Steam

At every temperature above freezing point water passes from the liquid into a gaseous state, the gas being termed steam. While water is below its boiling point its evaporation occurs at its surface only; but when its mass is heated to boiling point, and additional heat is imparted to it, evaporation occurs from the water lying against the surface from which it receives the heat, and an ebullition is caused by the vaporized water passing through the mass, the ebullition being what is known as boiling.

The temperature at which water boils depends upon the pressure acting upon its surface, the boiling point being at a lower temperature in proportion as the pressure is reduced; thus water at the top of a mountain, where the pressure of the atmosphere is less than at the sea level, would boil at a lower temperature than 212°, which is the boiling point when the atmospheric pressure is 14.7 lbs., which it is assumed to be at the sea level. Conversely, the boiling point is raised in proportion as the pressure upon its surface is raised, whether that pressure consists of air or of steam. As, however, the pressure is increased, the boiling point is at a higher temperature. So long as the steam is in contact with the water both are at the same temperature, as denoted by the thermometer (although they do not contain the same quantity of heat, as will be show presently), and the steam is termed saturated steam.

The pressure of saturated steam cannot be either increased or diminished without either increasing or diminishing its temperature, hence there is a definite relation of pressure to temperature, which enables the pressure to be known from the temperature, or conversely, the temperature to be known from the pressure. But if the steam be separated from the water and heated, it may be what is termed superheated, which is that it may be surcharged with heat or contain more heat than saturated steam at the same pressure. Such additional heat, however, is latent.

The pressure of steam is the lbs. of force it exerts upon a given area, as upon a square inch. In non-condensing engines the effective pressure of the steam is its pressure above that of the atmosphere, because the exhaust side of the piston being exposed to the atmosphere receives the atmospheric pressure, which must be overcome by a corresponding pressure of steam on the steam side of the piston, and this pressure is not, therefore, available for producing work or power in the engine.

In condensing engines, however, the exhaust side of the piston is (as nearly as practicable), relieved of the atmospheric pressure, and assuming a perfect vacuum to be formed, the whole of the steam pressure is exerted to propel the piston, in which case the steam pressure is termed the absolute pressure.

In considering the weight or density or the expansion of steam, its absolute and not its effective pressure must obviously be taken.

What is termed dry steam is saturated steam that does not contain what may be termed entrained water, which is water held in suspension in the steam, which may be caused by the surface of the water through which the steam is allowed to rise being too small in proportion to the volume of steam formed, in which case the rapid passage of the steam through the water causes it to carry up water with it and hold it in suspension, this action being termed foaming or priming.

Suppose, for example, that a boiler be filled with water up to the bottom of the steam dome, then all the steam formed would require to find exit from the water within the area of the dome, and the violence of the ebullition would cause foaming. Obviously, then, to obtain dry steam there must be provided a sufficient area of water surface for the steam to pass through.

But water so entrained is evaporated into steam, if the steam is wire drawn, that is, allowed to expand and reduce in pressure.