← Experimental Researches in Electricity, Volume 1
The electric spark or flash
1406. The spark is consequent upon a discharge or lowering of the polarized inductive state of many dielectric particles, by a particular action of a few of the particles occupying a very small and limited space; all the previously polarized particles returning to their first or normal condition in the inverse order in which they left it, and uniting their powers meanwhile to produce, or rather to continue, (1417.—1436.) the discharge effect in the place where the subversion of force first occurred. My impression is, that the few particles situated where discharge occurs are not merely pushed apart, but assume a peculiar state, a highly exulted condition for the time, i.e. have thrown upon them all the surrounding forces in succession, and rising up to a proportionate intensity of condition, perhaps equal to that of chemically combining atoms, discharge the powers, possibly in the same manner as they do theirs, by some operation at present unknown to us; and so the end of the whole. The ultimate effect is exactly as if a metallic wire had been put into the place of the discharging particles; and it does not seem impossible that the principles of action in both cases, may, hereafter, prove to be the same.
1407. The path of the spark, or of the discharge, depends on the degree of tension acquired by the particles in the line of discharge, circumstances, which in every common case are very evident and by the theory easy to understand, rendering it higher in them than in their neighbours, and, by exalting them first to the requisite condition, causing them to determine the course of the discharge. Hence the selection of the path, and the solution of the wonder which Harris has so well described as existing under the old theory. All is prepared amongst the molecules beforehand, by the prior induction, for the path either of the electric spark or of lightning itself.
1408. The same difficulty is expressed as a principle by Nobili for voltaic electricity, almost in Mr. Harris's words, namely, "electricity directs itself towards the point where it can most easily discharge itself," and the results of this as a principle he has well wrought out for the case of voltaic currents. But the solution of the difficulty, or the proximate cause of the effects, is the same; induction brings the particles up to or towards a certain degree of tension (1370.); and by those which first attain it, is the discharge first and most efficiently performed.
1409. The moment of discharge is probably determined by that molecule of the dielectric which, from the circumstances, has its tension most quickly raised up to the maximum intensity. In all cases where the discharge passes from conductor to conductor this molecule must be on the surface of one of them; but when it passes between a conductor and a nonconductor, it is, perhaps, not always so (1453.). When this particle has acquired its maximum tension, then the whole barrier of resistance is broken down in the line or lines of inductive action originating at it, and disruptive discharge occurs (1370.): and such an inference, drawn as it is from the theory, seems to me in accordance with Mr. Harris's facts and conclusions respecting the resistance of the atmosphere, namely, that it is not really greater at any one discharging distance than another.
1410. It seems probable, that the tension of a particle of the same dielectric, as air, which is requisite to produce discharge, is a constant quantity, whatever the shape of the part of the conductor with which it is in contact, whether ball or point; whatever the thickness or depth of dielectric throughout which induction is exerted; perhaps, even, whatever the state, as to rarefaction or condensation of the dielectric; and whatever the nature of the conductor, good or bad, with which the particle is for the moment associated. In saying so much, I do not mean to exclude small differences which may be caused by the reaction of neighbouring particles on the deciding particle, and indeed, it is evident that the intensity required in a particle must be related to the condition of those which are contiguous. But if the expectation should be found to approximate to truth, what a generality of character it presents! and, in the definiteness of the power possessed by a particular molecule, may we not hope to find an immediate relation to the force which, being electrical, is equally definite and constitutes chemical affinity?
1411. Theoretically it would seem that, at the moment of discharge by the spark in one line of inductive force, not merely would all the other lines throw their forces into this one (1406.), but the lateral effect, equivalent to a repulsion of these lines (1224. 1297.), would be relieved and, perhaps, followed by a contrary action, amounting to a collapse or attraction of these parts. Having long sought for some transverse force in statical electricity, which should be the equivalent to magnetism or the transverse force of current electricity, and conceiving that it might be connected with the transverse action of the lines of inductive force, already described (1297.), I was desirous, by various experiments, of bringing out the effect of such a force, and making it tell upon the phenomena of electro-magnetism and magneto-electricity.
1412. Amongst other results, I expected and sought for the mutual affection, or even the lateral coalition of two similar sparks, if they could be obtained simultaneously side by side, and sufficiently near to each other. For this purpose, two similar Leyden jars were supplied with rods of copper projecting from their balls in a horizontal direction, the rods being about 0.2 of an inch thick, and rounded at the ends. The jars were placed upon a sheet of tinfoil, and so adjusted that their rods, a and b, were near together, in the position represented in plan at fig. 116: c and d were two brass balls connected by a brass rod and insulated: e was also a brass ball connected, by a wire, with the ground and with the tinfoil upon which the Leyden jars were placed. By laying an insulated metal rod across from a to b, charging the jars, and removing the rod, both the jars could be brought up to the same intensity of charge (1370.). Then, making the ball e approach the ball d, at the moment the spark passed there, two sparks passed between the rods n, o, and the ball c; and as far as the eye could judge, or the conditions determine, they were simultaneous.
1413. Under these circumstances two modes of discharge took place; either each end had its own particular spark to the ball, or else one end only was associated by a spark with the ball, but was at the same time related to the other end by a spark between the two.
1414. When the ball c was about an inch in diameter, the ends n and o, about half an inch from it, and about 0.4 of an inch from each other, the two sparks to the ball could be obtained. When for the purpose of bringing the sparks nearer together, the ends, n and o, were brought closer to each other, then, unless very carefully adjusted, only one end had a spark with the ball, the other having a spark to it; and the least variation of position would cause either n or o to be the end which, giving the direct spark to the ball, was also the one through, or by means of which, the other discharged its electricity.
1415. On making the ball c smaller, I found that then it was needful to make the interval between the ends n and o larger in proportion to the distance between them and the ball c. On making c larger, I found I could diminish the interval, and so bring the two simultaneous separate sparks closer together, until, at last, the distance between them was not more at the widest part than 0.6 of their whole length.
1416. Numerous sparks were then passed and carefully observed. They were very rarely straight, but either curved or bent irregularly. In the average of cases they were, I think, decidedly convex towards each other; perhaps two-thirds presented more or less of this effect, the rest bulging more or less outwards. I was never able, however, to obtain sparks which, separately leaving the ends of the wires n and o, conjoined into one spark before they reached or communicated with the ball c. At present, therefore, though I think I saw a tendency in the sparks to unite, I cannot assert it as a fact.
1417. But there is one very interesting effect here, analogous to, and it may be in part the same with, that I was searching for: I mean the increased facility of discharge where the spark passes. For instance, in the cases where one end, as n, discharged the electricity of both ends to the ball c, fig. 116, the electricity of the other end o, had to pass through an interval of air 1.5 times as great as that which it might have taken, by its direct passage between the end and the ball itself. In such cases, the eye could not distinguish, even by the use of Wheatstone's means, that the spark from the end n, which contained both portions of electricity, was a double spark. It could not have consisted of two sparks taking separate courses, for such an effect would have been visible to the eye; but it is just possible, that the spark of the first end n and its jar, passing at the smallest interval of time before that of the other o had heated and expanded the air in its course, and made it so much more favourable to discharge, that the electricity of the end o preferred leaping across to it and taking a very circuitous route, rather than the more direct one to the ball. It must, however, be remarked, in answer to this supposition, that the one spark between d and e would, by its influence, tend to produce simultaneous discharges at n and o, and certainly did so, when no preponderance was given to one wire over the other, as to the previous inductive effect (1414.).
1418. The fact, however, is, that disruptive discharge is favourable to itself. It is at the outset a case of tottering equilibrium: and if time be an element in discharge, in however minute a proportion (1436.), then the commencement of the act at any point favours its continuance and increase there, and portions of power will be discharged by a course which they would not otherwise have taken.
1419. The mere heating and expansion of the air itself by the first portion of electricity which passes, must have a great influence in producing this result.
1420. As to the result itself, we see its effect in every electric spark; for it is not the whole quantity which passes that determines the discharge, but merely that small portion of force which brings the deciding molecule (1370.) up to its maximum tension; then, when its forces are subverted and discharge begins, all the rest passes by the same course, from the influence of the favouring circumstances just referred to; and whether it be the electricity on a square inch, or a thousand square inches of charged glass, the discharge is complete. Hereafter we shall find the influence of this effect in the formation of brushes (1435.); and it is not impossible that we may trace it producing the jagged spark and the forked lightning.
1421. The characters of the electric spark in different gases vary, and the variation may be due simply to the effect of the heat evolved at the moment. But it may also be due to that specific relation of the particles and the electric forces which I have assumed as the basis of a theory of induction; the facts do not oppose such a view; and in that view the variation strengthens the argument for molecular action, as it would seem to show the influence of the latter in every part of the electrical effect (1423. 1454.).
1422. The appearances of the sparks in different gases have often been observed and recorded, but I think it not out of place to notice briefly the following results; they were obtained with balls of brass, (platina surfaces would have been better,) and at common pressures. In air, the sparks have that intense light and bluish colour which are so well known, and often have faint or dark parts in their course, when the quantity of electricity passing is not great. In nitrogen, they are very beautiful, having the same general appearance as in air, but have decidedly more colour of a bluish or purple character, and I thought were remarkably sonorous. In oxygen, the sparks were whiter than in air or nitrogen, and I think not so brilliant. In hydrogen, they had a very fine crimson colour, not due to its rarity, for the character passed away as the atmosphere was rarefied (1459.). Very little sound was produced in this gas; but that is a consequence of its physical condition. In carbonic acid gas, the colour was similar to that of the spark in air, but with a little green in it: the sparks were remarkably irregular in form, more so than in common air: they could also, under similar circumstances as to size of ball, &c., be obtained much longer than in air, the gas showing a singular readiness to cause the discharge in the form of spark. In muriatic acid gas, the spark was nearly white: it was always bright throughout, never presenting those dark parts which happen in air, nitrogen, and some other gases. The gas was dry, and during the whole experiment the surface of the glass globe within remained quite dry and bright. In coal gas, the spark was sometimes green, sometimes red, and occasionally one part was green and another red: black parts also occur very suddenly in the line of the spark, i.e. they are not connected by any dull part with bright portions, but the two seem to join directly one with the other.
1423. These varieties of character impress my mind with a feeling, that they are due to a direct relation of the electric powers to the particles of the dielectric through which the discharge occurs, and are not the mere results of a casual ignition or a secondary kind of action of the electricity, upon the particles which it finds in its course and thrusts aside in its passage (1454.).
1424. The spark may be obtained in media which are far denser than air, as in oil of turpentine, olive oil, resin, glass, &c.: it may also be obtained in bodies which being denser likewise approximate to the condition of conductors, as spermaceti, water, &c. But in these cases, nothing occurs which, as far as I can perceive, is at all hostile to the general views I have endeavoured to advocate.