M (part 2)

In proportion as the cuts a, of the first story E F, are thus filled up, the greater part of the timbering is withdrawn, and made use of elsewhere. The intermediate cuts b, c, b, are next mined in like manner, either beginning with the cuts c, or the cuts b, according to the localities. From fig. 729. it appears that the working may be so arranged, that in case of necessity, there may be always between two cuts in activity the distance of three cuts, either not made, or filled up with rubbish. Hence, all the portion of the bed of ore may be removed, which corresponds to a first story E F fig. 730., and this portion is replaced by rubbish.

The exploration of the upper stories E′ F′, E F, E F, is now prepared in a similar manner; with which view shafts h h, k k, are formed from below upwards in the wall m of the deposit, and from these shafts oblong galleries proceed, established successively on a level with the stories thus raised over one another. See fig. 730. The following objects may be specified in the figures:—

a a, the first cuts filled up with rubbish, upon the first story E F, fig. 729.

b b, other cuts subsequently filled up, upon the same story.

c, the cut actually working.

d, the front of the cut, or place of actual excavation of the mineral deposit.

e, masses of the barren rock, reserved in the cutting, as pillars of safety.

f, galleries, by means of which the workmen may turn round the mass e, in order to form, in the roof t, an excavation in the direction of the deposit.

g, rubbish behind the mass e.

k k, two shafts leading from the first story E F, to the upper stories of the workings, as already stated.

m, the wall, and t the roof of the mineral bed.

In the second story E′ F′, the gallery of prolongation F′, figs. 728. and 730., is not entirely perforated; but it is further advanced than that of the third story, which, in its turn, is more than the gallery of the fourth.

From this arrangement there is produced upon fig. 730. the general aspect of a working by reversed steps.

Whenever the workings of the cuts c in the first story are finished, those of the second, a′ a′, may be begun in the second; and thus by mounting from story to story, the whole deposit of ore may be taken out and replaced with rubbish. One great advantage of this method is, that nothing is lost; but it is not the only one. The facilities offered by the system of cross workings for disposing of the rubbish, most frequently a nuisance to the miner, and expensive to get rid of, the solidity which it procures by the banking up, the consequent economy of timbering, and saving of expense in the excavation of the rock, reckoning from the second story, are so many important circumstances which recommend this mode of mining. Sometimes, indeed, rubbish may be wanted to fill up, but this may always be procured by a few accessory perforations; it being easy to establish in the vicinity of the workings a vast excavation in the form of a vault, or kind of subterraneous quarry, which may be allowed to fall in with proper precautions, and where rubbish will thus accumulate in a short time, at little cost.

Fig. 731. represents a section of the celebrated lead mines of Bleyberg in Carinthia, not far from Villach.

b, c, is the ridge of the mountains of compact limestone, in whose bosom the workings are carried on.

e, is the metalliferous valley, running from east to west, between the two parallel valleys of the Gail and the Drave, but at a level considerably above the waters of these rivers.

f g, is the direction of a great many vertical beds of metalliferous limestone.

On considering the direction and dip of the marly schist, and metalliferous limestone, in the space w, w, to the west of the line 1, s, it would appear that a great portion of this system of mountains has suffered a slip between 1, s, and a parallel one towards the east; whereby, probably, that vertical position of the strata has been produced, which exists through a considerable extent. The metalliferous limestone is covered to a certain thickness with a marly schist, and other more recent rocks. It is in this schist that the fine marble known under the name of the lumachella of Bleyberg is quarried.

The galena occurs in the bosom of this rock in flattened masses, or blocks of a considerable volume, which are not separated from the rest of the calcareous beds by any seam. It is accompanied by zinc ore (calamine), especially in the upper parts of the mountain.

Several of the workable masses are indicated by r, r; each presents itself as a solid analogous to a very elongated ellipse, whose axis dips, not according to the inclination of the surrounding rock, but to an oblique or intermediate line between this inclination, and the direction of the beds of limestone; as shown by r w, r′ u. Every thing indicates the contemporaneous formation of the limestone, and the lying beds of the lead ore.

The accidents or faults called kluft (rent) at Bleyberg are visible on the surface of the ground. Experienced miners have remarked that the rich masses occur more frequently in the direction of these accidents than elsewhere.

It is in general by galleries cut horizontally in the body of the mountain, and at different levels, s, g, s f, that the miner advances towards the masses of ore r, r. Many of these galleries are 500 fathoms long before they reach a workable mass. The several galleries are placed in communication by a few shafts, such as t; but few of these are sunk deeper than the level of the valley e.

The total length of the mines of Bleyberg is about 10,000 yards, parallel to the valley e; in which space there are 500 concessions granted by the government to various individuals or joint stock societies, either by themselves or associated with the government.

The metalliferous valley contains 5000 inhabitants, all deriving subsistence from the mines; 300 of whom are occupied in the government works.

Each concession has a number and a name; as Antoni, Christoph, Matthæus, Oswaldi, 2, 8, 36, &c.

Fig.. 732 is a section in the quicksilver mine of Idria. 1. is the gray-limestone; 2. is a blackish slate; 5. is a grayish slate. Immediately above these transition rocks lies the bed containing the ores called corallenerz, which consist of an intimate mixture of sulphuret of mercury and argillaceous limestone; in which four men can cut out, in a month, 2⁄2 toises cube of rock.

Fig. 733. represents a section of part of the copper mine of Mansfeldt; containing the cellular limestone, called rauchwacke, always with the compact marl-limestone called zechstein; the cupreous schist, or kupferschiefer; the wall of grayish-white sandstone, called the weisse liegende; and the wall of red sandstone, or the rothe liegende. The thin dotted stratum at top is vegetable mould; the large dotted portion to the right of the figure is oolite; the vein at its side is sand; next is rauchwacke; and lastly, the main body of fetid limestone, or stinkstein.

Fig. 734. represents one of the Mansfeldt copper schist mines in the district called Burgoerner, or Preusshoheit.

1. Vegetable mould, with siliceous gravel.

2. Ferruginous clay or loam.

3. Sand, with fragments of quartz.

4. Red clay, a bed of variable thickness as well as the lower strata, according as the cupreous schist is nearer or farther from the surface.

5. Oolite (roogenstein).

6. Newer variegated sandstone, (bunter sandstein).

7. Newer gypsum; below which, there is

8. A bluish marly clay.

9. Stinkstone, or lucullite.

10. Friable grayish marl.

11. Older gypsum, a rock totally wanting in the other districts of the mines of Rothenberg; but abounding in Saxon Mansfeldt, where it includes vast caverns known among the miners by the name of schlotten, as indicated in the figure.

12. The calcareous rock called zechstein. The lower part of this stratum shows symptoms of the cupriferous schist that lies underneath. It presents three thin bands, differently modified, which the miner distinguishes as he descends by the names of the sterile or rotten (faüle) rock; the roof (dachklotz); and the main rock (oberberg.)

13. Is a bed of cupriferous schist (kupferschiefer), also called the bitumino-marly schist, in which may be noted, in going down, but not marked in the figure:—

• a, the lochberg, a seam 4 inches thick.
• b, the kammschale, ⁄4 of an inch thick.
• c, the kopfschale, one inch thick.

These seams are not worth smelting; the following, however, are:—

• d, the schiefer kopf, the main copper-schist, 2 inches thick.
• e, a layer called lochen, one inch thick.

14. The wall of sandstone, resting upon a porphyry.

Fig. 735. is a section of the mines of Kiegelsdorf in Hessia, presenting—

1. Vegetable mould.

2. Limestone distinctly stratified, frequently of a yellowish colour, called lagerhafter kalkstein.

3. Clay, sometimes red, sometimes blue, sometimes a mixture of red, blue, and yellow.

4. The cellular limestone (rauhkalk). This rock differs both in nature and position from the rock of the same name at Mansfeldt.

5. Clay, usually red, containing veins of white gypsum, and fine crystals of selenite.

6. Massive gypsum of recent formation.

7. Fetid limestone, compact and blackish gray, or cellular and yellowish gray.

8. Pulverulent limestone, with solid fragments interspersed.

9. Compact marl-limestone, or zechstein, which changes from a brownish colour above to a blackish schist below, as it comes nearer the cupreous schist, which seems to form a part of it.

10. Cupreous schist (kuperschiefer), of which the bottom portion, from 4 to 6 inches thick, is that selected for metallurgic operations. Beneath it, is found the usual wall or bed of sandstone. A vein of cobalt ore a, which is rich only in the grayish-white sandstone (weisse liegende), traverses and deranges all the beds wherever it comes.

Of working mines by fire.—The celebrated mine worked since the tenth century in the mountain called Rammelsberg, in the Hartz, to the south of Goslar, presents a stratified mass of ores, among the beds of the rock which constitute that mountain. The mineral deposit is situated in the earth, like an enormous inverted wedge, so that its thickness (power), inconsiderable near the surface of the ground, increases as it descends. At about 100 yards from its outcrop, reckoning in the direction of the slope of the deposit, it is divided into two portions or branches, which are separated from each other, throughout the whole known depth, by a mass of very hard clay slate, which passes into flinty slate. The substances composing the workable mass are copper and iron pyrites with sulphuret of lead (galena), accompanied by quartz, carbonate of lime, compact sulphate of baryta, and sometimes gray copper ore, sulphuret of zinc, and arsenical pyrites. The ores of lead and copper contain silver and gold, but in small proportion, particularly as to the last.

A mine so ancient as that of Rammelsberg, and which was formerly divided among several adventurous companies, cannot fail to present a great many shafts and excavations; but out of the 15 pits, only two are employed for the present workings; namely, those marked A B and E F, in fig. 736., by which the whole extraction and drainage are executed.—The general system of exploitation by fire, as practised in this mine, consists of the following operations:—

1. An advance is made towards the deposits of ore, successively at different levels, by transverse galleries which proceed from the shaft of extraction, and terminate at the wall of the stratiform mass.

2. There is formed in the level to be worked, large vaults in the heart of the ore, by means of fire, as we shall presently describe.

3. The floor of these vaults is raised up by means of terraces formed from the rubbish, in proportion as the roof is scooped out.

4. The ores detached by the fire from their bed, are picked and gathered; sometimes the larger blocks are blasted with gunpowder.

5. Lastly, the ores thus obtained are wheeled towards the shaft of extraction, and turned out to the day.

Let us now see how the excavation by fire is practised; and in that view, let us consider the state of the workings in the mines of Rammelsberg in 1809. We may remark in fig. 736. the regularity of the vaults previously scooped out above the level B C, and the other vaults which are in full activity of operation. It is, therefore, towards the lower levels that the new workings must be directed. For this purpose, the transverse gallery being already completed, there is prepared on the first of these floors a vault of exploitation at b, which eventually is to become similar to those of the superior levels. At the same time, there is commenced at the starting point below it, reached by a small well dug in the line of the mineral deposit, a transverse gallery in the rock, by means of blasting with gunpowder. The rock is also attacked at the starting-point by a similar cut, which advances to meet the first perforation. In this way, whenever the vaults of the level C are exhausted of ore and terraced up with rubbish, those of the level beneath it will be in full activity.

Others will then be prepared at a lower level; and the exploitation may afterwards be driven below this level by pursuing the same plan, by which the actual depth of excavation has been gained.

In workings by fire we must distinguish, 1. The case where it is necessary to open a vault immediately from the floor; 2. The case where the vault having already a certain elevation, it is necessary to heighten its roof. In the former case, the wall or floor of the mineral deposit is first penetrated by blasting with gunpowder. As soon as this penetration is effected over a certain length, parallel to the direction of the future vault, as happens at b, there is arranged on the bottom a horizontal layer of billets of firwood, over which other billets are piled in nearly a vertical position, which rest upon the ore, so that the flame in its expansion comes to play against the mineral mass to be detached. When after some similar operations, the flame of the pile can no longer reach the ore of the roof on account of its height, a small terrace of rubbish must be raised on the floor of the deposit; and over this terrace, a new pile of faggots is to be heaped up as above described. The ancient miners committed the fault of constantly placing such terraces close to the roof, and consequently arranging the faggots against this portion of the ore, so that the flame circulated from the roof down to the floor. The result of such procedure was the weakening of the roof, and the loss of much of the ore which could not be extracted from so unstable a fabric; and besides, much more wood was burned than at the present day, because the action of the flame was dissipated in part against the whole mass of the roof, instead of being concentred on the portion of the ore which it was desired to dislodge. Now, the flame is usually made to circulate from the floor to the roof, in commencing a new vault.

When the vault has already a certain height, care is always taken that between the roof of the vault and the rubbish on which the pile is arranged, no more than two yards of space should intervene, in order that the flame may embrace equally the whole concavity of the vault, and produce an uniform effect on all its parts. Here, the pile is formed of horizontal beds, disposed crosswise above one another, and presents four free vertical faces, whence it has been called a chest by the miners.

It is usually on Saturday that the fire is applied to all the piles of faggots distributed through the course of the week. Those in the upper floors of exploitation are first burned, in order that the inferior piles may not obstruct by their vitiated air, the combustion of the former. Thus, at 4 o’clock in the morning, the fires are kindled in the upper ranges; from pile to pile, the fireman and his assistant descend towards the lower floors, which occupies them till 3 o’clock in the afternoon. Vainly should we endeavour to describe the majestic and terrific spectacle which the fire presents, as it unfolds its wings under its metallic vaults, soon filled with vast volumes of smoke and flame. Let us mark the useful effect which it produces.

When the flame has beat for a few instants on the beds of ore, a strong odour of sulphur, and sometimes of arsenic is perceived; and soon thereafter loud detonations are heard in the vaults. Suddenly the flame is seen to assume a blue colour, or even a white; and at this period, after a slight explosion, flakes of the ore, of greater or less magnitude, usually fall down on the fire, but the chief portion of the heated mineral still remains fixed to the vault. The ores pass now into a shattered and divided condition, which allows them afterwards to be detached by long forks of iron. In this manner the fire, volatilizing entirely some principles, such as sulphur, zinc, arsenic, and water, changing the aggregation of the constituent parts of the ore, and causing fissures by their unequal expansibilities, facilitates the excavation of such materials as resist by their tenacity the action of gunpowder.

The combustion goes on without any person entering the mine from Saturday evening till Monday morning, on which day, the fireman and his assistants proceed to extinguish the remains of the bonfires. On Monday also some piles are constructed in the parts where the effect of the former ones has been incomplete; and they are kindled after the workmen have quitted the mine. On Tuesday all hands are employed in detaching the ores, in sorting them, taking them out, and preparing new piles against the next Saturday.

The labour of a week consists for every man of five posts during the day, each of 8 hours, and of one post of four hours for Saturday. Moreover, an extra allowance is made to such workmen as employ themselves some posts during the night.

The labour of one compartment or atelier of the mine consists therefore in arranging the faggots, in detaching the ore which has already experienced the action of the fire, in breaking the blocks obtained, in separating the ore from the débris of the pile, and whenever it may be practicable or useful, in boring holes for blasting with gunpowder. The heat is so great in this kind of mine, that the men are obliged to work in it without clothing.

We have already remarked, that besides the working by fire, which is chiefly used here, recourse is sometimes had to blasting by gunpowder. This is done in order either to recover the bottom part or ground of the vaults on which the fire can act but imperfectly, to clear away some projections which would interfere with the effect of the pile, or lastly to strip the surrounding rock from the mass of the ore, and thence to obtain schist proper for the construction of the rubbish-terraces.

The blasting process is employed when the foremen of the workshop or mine-chamber judge that a hole well placed may separate enough of ore to pay the time, the repair of tools, and the gunpowder expended. But this indemnification is rarely obtained. The following statement will give an idea of the tenacity which the mineral deposit often presents.

In 1808, in a portion of the Rammelsberg mine, the ore, consisting of extremely compact iron and copper pyrites, was attacked by a single man, who bored a mining hole. After 11 posts of obstinate labour, occupying altogether 88 hours, the workman, being vigilantly superintended, had been able to advance the hole to a depth of no more than 4 inches; in doing which he had rendered entirely unserviceable 126 punches or borers, besides 26 others which had been re-tipped with steel, and 201 which had been sharpened; 6⁄4 pounds of oil had been consumed in giving him light; and half a pound of gunpowder was required for blasting the bore. It was found from a calculation made upon these facts by the administration of mines, that every inch deep of this hole cost, at their low price of labour, nearly a florin, value two shillings and sixpence.

It is therefore evident that though the timber, of which the consumption is prodigiously great, were much less abundant and dearer than it still is at Rammelsberg, mining by fire would be preferable to every other mode of exploitation. It is even certain, that on any supposition, the employment of gunpowder would not be practicable for every part of the mine; and if fuel came to fail, it would be requisite to renounce the workings at Rammelsberg, although this mountain still contains a large quantity of metals.

If in all mines the free circulation of air be an object of the highest importance, we must perceive how indispensable it must be in every part of a mine where the mode of exploitation maintains the temperature of the air at 112° Fahr., when the workmen return into it after the combustion of the piles, and in which besides it is necessary that this combustion be effected with activity in their absence. But in consequence of the extent and mutual ramifications of the workings, the number of the shafts, galleries, and their differences of level, the ventilation of the mine is in a manner spontaneously maintained. The high temperature is peculiarly favourable to it. The aid of art consists merely in placing some doors judiciously, which may be opened or shut at pleasure, to carry on the circulation of the air.

In considering the Rammelsberg from its summit, which rises about 400 yards above the town of Goslar, we observe, first, beds of slaty sandstone, which become the more horizontal the nearer they approach to the surface. At about 160 yards below the top level there occurs, in the bosom of the slaty graywacke, a powerful stratum of shells impasted in a ferruginous sandstone. See D, fig. 730. In descending towards the face of the ore, the parallel stratification of the clay-slate which forms its walls and roof grows more and more manifest. Here the slate is black, compact, and thinly foliated. The inclination of the different beds of rock is indicated at B. The substance of the workable mass is copper and iron pyrites, along with sulphuret of lead, accompanied by quartz, carbonate of lime, compact sulphate of baryta, and occasionally gray copper (fahlerz), sulphuret of zinc, and arsenical pyrites.

The ores are argentiferous and auriferous, but very slightly so, especially as to the gold. It is the ores of lead and copper which contain the silver, and in the latter the gold is found, but without its being well ascertained in what mineral it is deposited. Sometimes the copper occurs in the native state, or as copper of cementation. Beautiful crystals of sulphate of lime are found in the old workings.

In figs. 736. 737., A B is the shaft of extraction, called the Kahnenkuhler; N is the ventilation shaft, called Breitlingerwetterschacht; P is the extraction shaft, called Innier-schacht.

E F, is a new extraction-shaft, called Neuer treibschacht, by which also the water is pumped up; by A B, and E F, the whole extraction and draining are carried on. The ores are raised in these shafts to the level of the waggon-gallery (galerie de roulage) i, by the whims l, q, provided with ropes and buckets. 1, 2, 3, 4, fig. 736., represent the positions of four water-wheels for working the whims; the first two being employed in extracting the ores, the last two in draining. The driving stream is led to the wheel 1, along the drift l; whence it falls in succession upon the wheels 2, 3, 4. The general system of working consists of the following operation;—

1. The bed of ore is got at by the transverse galleries, m, n, o, q, r, s, which branch off from the extraction shaft, and terminate at the wall of the main bed;

2. Great vaults are scooped out at the level of the workings, by means of fire;

3. The roofs of these vaults are progressively propped with mounds of rubbish;

4. The ores thus detached, or by blasting with gunpowder, are then collected;

5. Lastly, they are wheeled out to the day; and washed near Z.

Comparative Table of celebrated Mines in Europe and America. By F. Burr, Esq.
(Quarterly Mining Review for July, 1835, p. 60.)

Consolidated and United Mines. Veta Grande Mines. Mine of Valenciana. Mine of Himmelsfürst.

(At present the richest mines in Cornwall.) (At present the richest mines in Mexico.) (Richest of the Mexican mines at the beginning of the present century.) (Richest of the Saxon mines at the beginning of the present century.)

Situation Two miles east of Redruth. Four miles north of Zacatecas. One mile north of Guanaxuato. Two miles south-east of Freyberg.

Elevation Elevation of the surface above the level of the sea, from 200 to 300 ft.; depth of the bottom of the mine below the level of the sea, about 1,370 feet. Elevation of the surface above the level of the sea, supposed to be about 6000 feet. Elevation of the bottom of the mine above the level of the sea, probably near 5,000 feet. Elevation of the surface above the level of the sea, 7,617 feet. Elevation of the bottom of the mine above the level of the sea, 5,730 feet. Elevation of the surface above the level of the sea, 1,346 feet. Elevation of the bottom of the mine above the level of the sea, 263 feet.

Nature of the rock The Veta Madre of Guanaxuato, upon which this mine is worked, traverses both clay slate and porphyry, but it is most productive in the former rock. The clay slate is considered by Humboldt to belong to the transition class, but situate near the limits of primary formations. This rock in depth, passes into chlorite slate, and talc slate. It contains subordinate beds of syenite, hornblende slate, and serpentine. The porphyry rests upon the clay slate, and is conformable to it, both in direction and stratification. The rock prevailing in the neighbourhood of Freyberg, in which this and most of the other mines are situate, is a formation of primary gneiss. Primary clay slate resting immediately on granite, a short distance westward of the mines. The clay slate is intersected by numerous channels of porphyry, which have nearly the same direction as the mineral veins, and are often of considerable width. The porphyry sometimes appears also to form large irregular masses in the clay slate. Both rocks are traversed by veins of quartz and clay intersecting the metalliferous veins. Transition clay slate, alternating with dolomite, and occasionally with greywacke. This clay slate is sometimes decomposed; it rests on syenitic rocks, and is in some places covered with porphyry.

Nature of the metalliferous deposits In the consolidated mines, the eight following lodes are extensively worked:—Wheal Fortune lode, Cusvea lode, Deeble’s lode, Old lode, Taylor’s lode, Tregonning’s lode, Martin’s lode, and Glover’s lode. In the united mines, the principal workings are upon the Old lode, and about five or six others are more or less productive. Numerous smaller lodes or “branches” occur also in both mines. The principal lodes are from 2 or 3, to 7 or 8 feet wide; the “branches” are generally 12 or 18 inches wide. The direction of the lodes varies from nearly east and west to about 20 degrees north of east and south of west. The underlie of the principal lodes, is from 2 to 3 feet per fathom north, that of the smaller ones about the same south. One principal vein (the Veta Grande) which is generally separated into three branches, and sometimes into four. When ramified, the width extends to 60 or 70 feet; when united, it varies from 8 or 10 to 20 or 30 feet. The branches are generally about 10 or 12 feet wide, and the upper one is most productive. The direction of the Veta Grande, is from 30 to 40 degrees south of east, and north of west, and its underlie, from two to three feet per fathom south. Other veins of less size, occur in the neighbourhood of the Veta Grande, which cross it at an acute angle. One of these appears to heave the vein for about 700 feet, being the most remarkable derangement of the kind on record. One Veta (the Veta Madre) which is often separated into three branches, extending from 130 to 160 feet in width. When not ramified, its width varies from 20 or 30 to 60 or 70 feet, but is more commonly from 40 to 50 feet. The direction of the vein, is north-west and south-east; its underlie is south, and about five or six feet per fathom. There are five veins worked in this mine. The principal vein (Teichflache) is from one foot six inches, to three feet in width, the others are from six to 12 inches wide. The direction of this vein, is nearly north and south, its underlie is west, and about three feet per fathom. Some of the other veins intersect it.

Ores Chiefly copper ore, occasionally native copper, blue and green carbonate of copper. Tin, or oxide of tin, also occurs, but not in very great abundance. Chiefly red silver, native silver, sulphuret of silver, and argentiferous pyrites. Sulphuret of silver, native silver, prismatic black silver, red silver, native gold, argentiferous galena. Argentiferous sulphuret of lead, native silver, sulphuret of silver, red silver.

Produce of the ores 9⁄4 per cent. of fine copper; average produce in 100 parts of ore. 3⁄2 oz. per quintal. Four ounces of silver per quintal of 100 lbs., equivalent to 2⁄2 parts of metal in 1,000 of ore, or ⁄4 per cent. Six to seven ounces of silver per quintal of 100 lbs. Equivalent to from 3⁄4 to 4⁄2 parts of metal in 1,000 of ore, or from 3-8ths to nearly ⁄2 per cent.

Veinstone Chiefly quartz, of which many varieties occur. Chiefly quartz, occasionally amethyst, carbonate of lime, and sulphate of barytes. Quartz, amethyst, carbonate of lime, pearlspar, and hornstone. Quartz, pearlspar, and calcareous spar.

Mineral substances The ores are generally accompanied by “gossan” in the backs of the lodes, by blende, and by iron, and arsenical pyrites in depth. The ores are generally accompanied by blende, sulphuret of antimony, and iron pyrites. The ores are accompanied by blende, spathose iron, copper and iron pyrites. The ores are accompanied by blende, spathose iron, and a little iron and arsenical pyrites.

Depth of the principal shafts Woolf’s engine-shaft, 248 fathoms; Pearce’s engine-shaft, 275 fathoms. Some of the other engine shafts are scarcely inferior in depth. Tiro General, 182 fathoms; Gallega shaft, 138 fathoms. Tiro General, 310 fathoms. Frankenschacht, 180 fathoms.

Depth of adit at the principle shafts At Woolf’s engine-shaft, 13 fathoms. The average depth of the adit at the other engine-shafts is about 30 or 40 fathoms. There is no adit to this mine. There is no adit to this mine. The adit at the shaft called Frankenschacht is 47 fathoms in depth.

Quantity of water Varies from 2,000 to 3,000 gallons per minute. About 80 gallons per minute. The Valenciana was a dry mine from its commencement in 1760 to 1780, when it first became troubled with water, in consequence of some of the workings being inadvertently communicated with the adjoining mine of Tepeyac; which, although upon the same vein, was extremely wet. The quantity of water raised during the late working appears to have been about 110 gallons per minute, but the regular influx was much less. 50 gallons per minute.

Height to which the water is raised About 230 fathoms at the consolidated mines, at the united mines, about 110 fathoms. On an average about 150 fathoms. 310 fathoms. 133 fathoms.

Power employed in drainage 9 steam-engines; 3 of 90-inch cylinder, 3 of 85, 1 of 80, and 2 of 65. A water wheel, 48 feet in diameter. Usually 10 malacates.[b] A steam-engine of 30-inch cylinder, and 7 malacates. Two water-wheels, each 42 feet in diameter.

Probable equivalent in actual horsepower 1,500 constantly at work, or a total number of above 4,500. 32 horses constantly working, or a total number of about 100 horses.[c] 65 horses constantly at work, or a total number of about 200. 16 horses constantly at work or a total number of about 50.[d]

Average annual expense in drainage 12,700l. taking the average of the last ten years.[a] 20,000l. per annum.[c] About 40,000l., per annum.[d] Cannot be ascertained, but evidently very small.[d]

Quantity of ore annually produced 16,400 tons of copper ore, a few tons of tin ore.[a] 21,380 tons of silver ore.[c] 32,500 tons of silver ore.[d] 630 tons of silver ore.[d]

Produce in metal 1,517 tons of fine copper, a little tin.[a] 153,000 lbs. troy of silver.[c] 221,900 lbs. troy silver.[d] 6,160 lbs. troy of silver.[d]

Total returns, or value of the above 119,800l.[a] 423,400l. per annum.[c] About 600,000l.[d] About 18,000l.[d]

Total costs of the mine 93,500l. exclusive of lord’s dues; 98,600l. including lord’s dues.[a] 252,170l. per annum.[c] 197,900l. per annum.[d] 9,500l. per annum.[d]

Clear profit to the proprietors 21,000l. per annum.[a] 171,240l. per annum.[c] 118,750l. per annum.[d] 3,560l. per annum.[d]

Amount of capital invested 75,000l.[a] 130,000l.[c] Cannot be ascertained, but known to have been very small.[d] Cannot be ascertained, but probably very small.[d]

Interest on capital invested 280 per cent. after paying back the original capital.[a] Nearly 700 per cent. after paying back the original capital.[c] Not known, but certainly many hundred per cent.[d] Not known, but probably very high.[d]

Proportion of costs to returns Costs exclusive of lord’s dues, 78 per cent.[a] About 59⁄2 per cent. Costs 60 per cent. In the nine years following, the proportion was 80 per cent., at the end of that time the working of the mine was stopped by the revolution, in the year 1809.[d] Costs 73 per cent.[d]

Number of men employed About 2,500 persons, of whom about 1,450 are employed under ground. About 900, of whom nearly 600 are employed under ground. 3,100 Indians and Mestizoes, of whom 1,800 are employed under ground. 700 miners of whom 550 are employed under ground.

Wages of the mines per day Probably about 3 shillings on an average. About 8 or 9 shillings per day. From 4 to 5 shillings. About 1s. 6d. per day.

Quantity and expense of powder 1,420 cwt.; value 15,830l. 240 cwt.; value 1,070l.

Manner in which the ores are disposed of Sold to the smelting companies, and smelted by them at Swansea, in South Wales. Chiefly reduced by the company at the hacienda of Sanceda, by smelting and amalgamation. Sold to the Rescatadores, and reduced by smelting and amalgamation at haciendas, in the neighbourhood of Guanaxuato. Delivered to the government reduction works in the neighbourhood of Freyberg, where they are partly smelted, and partly amalgamated.

[a] Average of the last Ten Years.
[b] Malacate; a horse whim.
[c] Average of the last Six Years.
[d] Average year at the end of the Eighteenth Century.

VENTILATION OF MINES.

When men penetrate by narrow passages into the interior of the earth, their respiration, joined to the combustion of candle and gunpowder, are not long of vitiating the air. The decomposition of wood contributes to the same effect, as also the mineral bed itself, especially in coal mines, by the carburetted hydrogen and carbonic acid evolved, and from the absorption of oxygen by pyrites. In many cases, arsenical and mercurial vapours are disengaged. Hence the necessity of maintaining in subterranean cavities a continual circulation of air, which may renew the atmosphere round the miners. The whole of the means employed to produce this effect, constitutes what is called the ventilation of mines.

These means are divided into natural and artificial. The natural means are the currents produced by the difference of density between the air of mines and the external air; the artificial are air-exhausters or condensers, fires, &c.

The temperature of the air of the subterranean workings surpasses the mean temperature of the place in which the mine is opened. Hence it is lighter in winter, but in summer often heavier than the air of the atmosphere. For this reason, when the mine presents two openings at different levels, the air naturally flows out by the most elevated in winter, and by the lowest in summer. We may take advantage of this circumstance, to lead the air into the bottom of even a very long gallery, opening into the side of the mountain, by piercing a shaft into its roof at some distance from the entrance, and dividing the gallery by a horizontal floor into two parts, which have no mutual communication, except at the furthest extremity—the upper part communicating with the shaft, and the under with the mouth of the gallery. If the two compartments have different dimensions, the air in the smaller sooner comes into an equilibrium of temperature with the rock; and the difference of temperature of the two compartments is sufficient to produce a current. If a streamlet of water flows through this gallery, it facilitates the flow of the air along the lower compartment. If a mine has several openings situated on the same level, it rarely happens but some peculiar circumstance destroys, during the colds of winter and the heats of summer, the equilibrium of the air. But in spring and autumn, when the external air is nearly of the same temperature with that of the mines, the above-named causes are almost always too feeble to excite an issuing current. This effect is, however, frequently obtained by raising over one of the shafts a chimney 20 or 30 yards high, which alone produces the effect of an opening at a different level. It has been remarked that stormy weather usually deranges every system of ventilation. See Pitcoal and Ventilation.

MINIUM. (Eng. and Fr., Red lead; Mennige, Germ.) This pigment is a peculiar oxide of lead, consisting of two atoms of the protoxide and one of the peroxide; but, as found in commerce, it always contains a little extra protoxide, or yellow massicot. It is prepared by calcining lead upon a reverberatory hearth with a slow fire, and frequent renewal of the surface with a rake, till it becomes an oxide, taking care not to fuse it. The calcined mass is triturated into a fine powder in a paint mill, where it is elutriated with a stream of water, to carry off the finely levigated particles, and to deposit them afterwards in tanks. The powder thus obtained being dried, is called massicot. It is converted into minium, by being put in quantities of about 50 pounds into iron trays, 1 foot square, and 4 or 5 inches deep. These are piled up upon the reverberatory hearth, and exposed during the night, for economy of fuel, to the residuary heat of the furnace, whereby the massicot absorbs more oxygen, and becomes partially red lead. This, after being stirred about, and subjected to a similar low calcining heat once and again, will be found to form a marketable red lead.

The best minium, however, called orange mine, is made by the slow calcination of good white lead (carbonate) in iron trays. If the lead contains either iron or copper, it affords a minium which cannot be employed with advantage in the manufacture of flint-glass, for pottery glazes, or for house-painting.

Dumas found several samples of red lead which he examined to consist of the chemical sesquioxide and the protoxide, in proportions varying from 50 of the former and 50 of the latter, to 95·3 of the former and 4·7 of the latter. The more oxygen gas it gives out when heated, the better it is, generally speaking. See Naples Yellow.

MINT. (Monnaie, Fr.; Münze, Germ.) The chief use of gold and silver is to serve for the medium of exchange in the sale and purchase of commodities, a function for which they are pre-eminently fitted by their scarcity, by being unalterable by common agents, and condensing a great value in a small volume. It would be very inconvenient in general to barter objects of consumption against each other, because their carriage would be expensive, and their qualities, in many cases, easily injured by external agents, &c. Gold is exempt from spontaneous change, and little costly in conveyance. Mankind at a very early period recognised how much easier it was to exchange a certain weight of gold or silver for objects of commerce, than to barter these objects themselves; and thenceforth all agreed to pay for their purchases in bars or ingots of these precious metals. But as their intrinsic value depends upon their purity, it became necessary to stamp on these bars their standard quality and their weight.

The inconvenience of using ingots in general trade, on account of the difficulty of defining fractional values, has determined governments to coin pieces of money, that is, quantities of metal whose weight and standard were made known and guaranteed by the effigies of the prince. It is true, indeed, that kings have become frequently coiners of base money, by altering the weight and purity of the pieces apparently guaranteed by their impress. By such reductions modern coins represent less of the precious metal than they did long ago. The ordonnance of 755, for the coining of sous in France, proves that there was then as much fine silver in a single sous, as there is now in a piece of 5 francs. During the last two centuries, indeed, silver coins have been diminished two thirds in weight.

But since knowledge has become more generally diffused, it has been shown that these frauds are equally injurious to the prince and to public faith. A sovereign may, it is true, declare by a decree that a shilling-piece is to be held worth five; but let us consider the consequences of this decree. All the individuals who have rents or capital sums to receive, will be ruined, by getting in metallic value only one-fifth of what is due to them; for although the nominal value should be the same as what they are entitled to, the intrinsic value would be but a fifth of the former; so that when they go to purchase the necessaries or comforts of life, the dealer who sells them will at once raise their price five-fold. Each article of merchandise would thus acquire a nominal price 5 times greater; and he who had received payment of a debt in that money, could not with it procure more than one-fifth of the goods he could have previously commanded. That fraudulent law would, therefore, favour the debtors at the expense of the creditors; and as the state is commonly a great debtor, especially when it has recourse to the depreciation of the currency, it is obvious, that however illicit the gain which it makes, it still does gain; and this is the reason why princes have so often tampered with the mint. But let us examine the other consequences of this decree.

If the sovereign is a debtor, he is also a creditor and consumer, and even the most considerable of any. The taxes which he imposes are paid him in this deteriorated money, returned to him at its nominal value; and the purveyors of his armies, his buildings, and his household, sell him their commodities only at the actual market price. We may infer from this simple development that the coin with which he pays for any object has the same intrinsic value as the object; and that the name given to the coin is of no consequence. The prince may call it a crown, a ducat, or a rix-dollar at his pleasure; and he may assign any value to it that his caprice may suggest, yet this will not affect its value; for this is fixed beyond his control by the general nature of things. The prince may, indeed, at the outset, have profited by defrauding his creditors, and by authorizing each debtor to imitate him, but he will soon lose whatever he may have gained; and he will thus learn to his cost that it was bad policy to sacrifice his character by giving an example of a fraud so truly unprofitable in the issue. Moreover, he will lose still as much in the following years, because his treasury will receive only one-fifth part of the taxes, unless he has quintupled the imposts. It may be said, indeed, that he might do the one thing along with the other. But every one knows that this power is neither generally permitted to princes, nor if it were, could it be safely exercised. Serious political crises would combine to endanger the stability of the government; which besides, as the main consumer in the nation, must lose always as much as it seems to gain.

It is therefore manifest that the alteration of the standard and weight of the coinage is at once a crime and a ruinous action for the sovereign power to commit; and hence such disastrous measures have been long abandoned in all well-regulated states. A gold sovereign is intrinsically worth 20 shillings minus the cost of coinage; for were it worth more, all our sovereign pieces would be exported or melted down, to obtain the difference of value, however trifling it might be; and were it worth less, it would be the source of loss similar to what the state occasions when it depreciates the coin.

To comprehend the true value of a coin, we must regard this piece as an article of merchandise, whose value depends, as that of every thing else, on its usefulness, the esteem in which it is held, and the demand for it in the market. Grain increases in value when there are few sellers and many buyers; gold and silver are in the same predicament. The value of these metals is much augmented, indeed, by the universal currency they obtain when struck into money; a value additional to what they possess as objects of the arts. This value of the precious metals changes with time and place, like that of every merchandise; their abundance, since the discovery of America, has greatly lowered their value; that is, with the same weight of metal, we cannot at the present day purchase the same quantity of corn, land, wool, &c. as formerly. In the countries where silver abounds, this metal has less value, or, in other terms, commodities are dearer. Hence the metal tends to resume its equilibrium in flowing into those places where it is rarer; which means, that the consumer prefers purchasing his commodities there rather than in another place, if he can easily transport them to where they are dearer.

It was formerly believed that a country is rich when it has a great deal of gold and silver; but this popular illusion has passed away. Spain has never been poorer than since the discovery of America, because its national industry has been ruined, and the capitals merely passed through its hands to spread over the rest of Europe, from which it was obliged to import every thing that its want of home manufactures made it necessary to procure from abroad. We may add to these, the prodigalities of the court, which, supposing its wealth inexhaustible, tried to corrupt all the ministers of the other powers, in furtherance of the chimera of universal dominion. The richest state is that in which there is most industry, whereby the inhabitants may procure every thing indispensable to the conveniences and comforts of life. Gold as a useful metal, and a medium of exchange, is undoubtedly very precious, and an adequate quantity for these exchanges must be had; but as it is good for very little besides, nay, as an excess is even hurtful, it soon begins to fly of itself towards the places where it is more needed or less common.

With regard to the relative value of gold and silver, several details have already been given in our view of the mineral wealth of the globe. Three centuries ago, an ounce of gold was worth at London or Paris 10 ounces of silver; now it may be exchanged for 15 ounces and a half.

The par of two coins results from the comparison of their weight and standard fineness. Let us take for an example the conversion of English gold sovereigns worth 20 shillings or a pound sterling, in relation to the French louis of 20 francs. The standard of the sovereign gold is 0·917, fine gold being 1000; its weight is 125·256 gr. English, or 7·980855 grammes; by multiplying this weight into its standard, we have a product of 7·318444035; this is, in grammes, the quantity of pure gold contained in the sovereign piece. The piece of 20 francs has a legal standard of 0·9; and multiplying this number by the weight of the louis, 6·45161 grammes, we find that it contains 5·806449 of pure metal. We then make this proportion:—

As 5·806449 : 20 francs ∷ 7·31844 : 25·2079 francs; or the value of the English sovereign is nearly 25·21 francs, in French gold coin. A similar calculation may be made for silver coins. The French rule for finding the par of a foreign gold coin, or its intrinsic value in francs, is to multiply its weight by its standard or titre, and that product by 3⁄9. The par of foreign silver money, or its intrinsic value in francs, is obtained by multiplying its weight in grammes by its standard in thousand parts, and by ⁄9. The French 5-franc piece has its standard or titre at 0·9, and weighs 25 grammes.

The assaying of gold for coin and trinkets requires very delicate management. The French take half a gramme at most (about 7⁄2 grains) of gold, and fuse it with thrice its weight of silver, as already described under Assay. The parting is the next operation. For this purpose the button of gold and silver alloy is first hammered flat on a piece of steel, and then made feebly red hot in burning charcoal or over a lamp flame. After being thus annealed, the metal is passed through the rolling press, till it be converted into a plate about ⁄70 of an inch thick. After annealing this riband, it is coiled into a spiral form, introduced immediately into a small matrass of a pear shape, an assay matrass, and about 500 grains of nitric acid, sp. grav. 1·185, are poured over it. Heat being now applied to the vessel, the solution of the silver and copper alloys ensues, and after 22 minutes of constant ebullition, the liquid is poured off and replaced by an equal quantity of nitric acid, likewise very pure, but of the density 1·28. This is made to boil for about 10 minutes, and is then poured off, when the matrass is filled up with distilled water to the brim. In conclusion, a small annealing crucible is inverted as a cup over the mouth of the matrass, which is now turned upside down with a steady hand; the slip of metal falls into the crucible through the water; which by sustaining a part of its weight, softens its descent and prevents its tearing. The matrass is then dexterously removed, without letting its water overflow the crucible. The water is gently decanted from the crucible, which is next covered, placed in the middle of burning charcoal, and withdrawn whenever it becomes red hot. After cooling, the metal slip is weighed very exactly, whence the weight of fine gold in the alloy is known. Stronger acid than that prescribed above would be apt to tear the metallic riband to pieces, and it would be difficult to gather the fine particles of gold together again. The metallic plate becomes at last merely a golden sieve, with very little cohesion. When copper is to be separated from gold by cupellation, a higher temperature is requisite than in cupelling silver coin.

The coining apparatus of the Royal Mint of London is justly esteemed a masterpiece of mechanical skill and workmanship. It was erected in 1811, under the direction of the inventor, Mr. Boulton; and has since been kept in almost constant employment.

The melting pots (fig. 738.) are made of cast iron, and hold conveniently 400 pounds of metal. They are furnished with a spout or lip for pouring out the metal, and with two ears, on which the tongs of the crane lay hold in lifting them out of the furnace. The pot rests on pedestals on the grate of the furnace, and has a ring cast on its edge to prevent the fuel falling into it. Whenever it becomes red hot, the metal properly prepared and mixed, so as to produce an alloy containing 0·915 parts of gold, is put in, and during the melting, which occupies some hours, it is occasionally stirred. The moulds are meanwhile prepared by warming them in a stove, and thereafter by rubbing their inside surfaces with a cloth dipped in oil, by which means the ingots cast in them get a better surface. Fig. 739. represents a side view of the carriage, charged with its moulds. When the proper number of moulds is introduced, the screws at the end, represented at t T, are screwed fast, to fix them all tight.

The pot of fused metal is lifted out of the furnace by the crane (fig. 740.), then swung round, and lowered down into the cradle l, m, n, o of the pouring machine, until the ring on the edge of it rests on the iron hoop n, which, being screwed tight up, holds it secure, and the crane-tongs are removed. One of the assistants now takes the winch handle s in one hand, and y in the other. By turning y he moves the carriage forward, so as to bring the first mould beneath the lip of the melting pot; and by turning s, he inclines the pot, and pours the metal into the mould. He then fills the other moulds in succession. The first portion of liquid metal is received in a small iron spoon, and is reserved for the assay-master; a second sample is taken from the centre of the pot, and a third from the bottom part. Each of these is examined as to its quality.

The ingots, which are about 10 inches long, 7 broad, and 6 tenths of an inch thick, are now carried to the rolling mill.

Fig. 741., where A represents a large spur wheel, fixed on the extremity of a long horizontal shaft B B, extending beneath the whole mill. This wheel and shaft are driven by a smaller wheel, fixed on the main or fly-wheel shaft of a steam engine of 36-horse power. The main shaft B of the rolling mill has wheels C, D, E fixed upon it, to give motion to the respective rollers, which are mounted at F and G, in strong iron frames, bolted to the iron sills a a, which extend through the whole length of the mill, and rest upon the masonry, in which the wheels are concealed. The two large wheels C and E give motion to the wheels H, I, which are supported on bearings between two standards b, b, bolted down to the ground sills. On the ends of the axes of these wheels are heads for the reception of coupling boxes d, d, which unite them to short connecting shafts K L; and these again, by means of coupling boxes, convey motion to the upper rollers e, e, of each pair, at F and G. The middle wheel D upon the-main shaft B gives motion to the lower rollers in a similar manner. Thus both the rollers e, f of each frame receive their motion from the main shaft with equal velocity, by means of wheels of large radius, which act with much more certainty than the small pinions usually employed in rolling mills to connect the upper and lower rollers, and cause them to move together.

The rolling mill contains four pairs of rollers, each driven by its train of wheel work; the mill, therefore, consists of two such sets of wheels and rollers as are represented in our figure. The two shafts are situated parallel to each other, and receive their motion from the same steam engine. This admirable rolling mill was erected by John Rennie, Esq.

The ingots are heated to redness in a furnace before they are rolled. The two furnaces for this purpose are situated before two pairs of rollers, which, from being used to consolidate the metal by rolling whilst hot, are termed breaking-down rollers. Two men are employed in this operation; one taking the metal from the furnace with a pair of tongs, introduces it between the rollers; and the other, catching it as it comes through, lifts it over the top roller, and returns it to his fellow, who puts it through again, having previously approximated the rollers a little by their adjusting screws. After having been rolled in this manner four or five times, they are reduced to nearly two-tenths of an inch thick, and increased lengthwise to about four times the breadth of the ingot. These plates, while still warm, are rubbed over with a dilute acid or pickle, to remove the colour produced by the heat, and are then cut up into narrow slips across the breadth of the plate, by means of the circular shears fig. 742.

This machine is worked by a spur-wheel at the extremity of the main shaft B of the rolling mill (fig. 741.) It consists of a framing of iron A A, supporting two shafts B B, which are parallel to each other, and move together by means of two equal spur-wheels C C, the lower one of which works with the teeth of the great wheel above mentioned, upon the main shaft of the rolling mill. At the extremities of the two shafts, wheels or circular cutters are fixed with their edges overlapping each other a little way. F represents a shelf on which the plate is laid, and advanced forward to present it to the cutter; and G is a ledge or guide, screwed down on it, to conduct the metal and to regulate the breadth of the piece to be cut off. Hence the screws which fasten down the ledge are fitted in oblong holes, which admit of adjustment. The workman holds the plate flat upon the surface F, and pushing it towards the shears, they will lay hold of it, and draw it through until they have cut the whole length. The divided parts are also prevented from curling up into scrolls, as they do when cut by a common pair of shears; because small shoulders on E and D, behind the cutting edge, keep them straight. Behind the standard, supporting the back pivots of the shafts B B of the cutter, is a frame l, with a screw m tapped through it. This is used to draw the axis of the upper cutter D endwise, and keep its edge in close contact with the edge of the other cutter E. The slips or ribands of plate are now carried to the other two pairs of rollers in the rolling mill, which are made of case-hardened iron, and better polished than the breaking-down rollers. The plates are passed cold between these, to bring them to exactly the same thickness; whence they are called adjusting or planishing rollers. The workman here tries every piece by a common gauge, as it comes through. This is a piece of steel having a notch in it; the inside lines of which are very straight, and inclined to one another at a very acute angle. They are divided by fine lines, so that the edge of the plate being pressed into the notch, will have its thickness truly determined by the depth to which it enters, the divisions showing the thickness in fractions of an inch.

In rolling the plate the second time, all the plates are successively passed through the rollers; then the rollers being adjusted, they are passed through another time. This is repeated thrice or even four times; after which they are all tried by the gauge, and thus sorted into as many parcels as there are different thicknesses. It is a curious circumstance, that though the rollers are no less than 14 inches in diameter, and their frame proportionally strong, they will yield in some degree, so as to reduce a thick plate in a less degree than a thin one; thus the plates which have all passed through the same rollers, may be of 3 or 4 different degrees of thickness, which being sorted by the gauge into as many parcels, are next reduced to the exact dimension, by adapting the rollers to each parcel. The first of the parcel which now comes through is tried, by cutting out a circular piece with a small hand machine, and weighing it. If it proves either too light or too heavy, the rollers are adjusted accordingly, till by a few such trials they are found to be correct, when all the parcel is rolled through. The trial plates which turn out to be too thin, are returned as waste to the melting-house. By these numerous precautions, the blanks or circular discs, when cut out by the next machine, will be very nearly of the same weight; which they would scarcely be, even if the gauge determined all the plates to the same thickness, because some being more condensed than others, they would weigh differently under the same volume.

A great improvement has been made on that mode of lamination, by the late Mr. Barton’s machine for equalizing the thickness of slips of metal for making coin, which has been for several years introduced into the British mint. A side elevation is shown in fig. 743., and a plan in fig. 744. It operates in the same way as wire-drawing mechanisms; namely, pulls the slips of metal forcibly through an oblong opening, left between two surfaces of hardened steel. The box or case which contains the steel dies, composed of two hardened cylinders, is represented at C in fig. 743. The pincers employed to hold the metal, and draw it through, are shown at s r.

The slips of metal to be operated on by the drawing machine, are first rendered thinner at one end, that they may be introduced between the dies, and also between the jaws of the pincers. This thinning of the ends is effected by another machine, consisting of a small pair of rollers, mounted in an iron frame, similar to a rolling-mill. The upper roller is cylindrical, but the lower is formed with 3 flat sides, leaving merely portions of the cylinder entire, between these flat sides. The distance between the centres of the rollers is regulated by screws, furnished with wheels on their upper ends, similar to what is seen in the drawing dies at C. The two rollers have pinions on their axes, which make them revolve together; they are set in motion by an endless strap passing round a drum, upon whose axis is a pinion working into the teeth of a wheel fixed upon the axis of the lower roller.

The end of a slip of metal is presented between the rollers while they are in motion, not on that side of the roller which would operate to draw in the slip between them, as in the rolling-press above described, but on the contrary side, so that when one of the flat sides of the under roller fronts horizontally the circumference of the upper roller, an opening is formed, through which the slip of metal is to be inserted until it bears against a fixed stop at the back of the rollers. As the rollers continue to turn round, the cylindrical portions come opposite to each other, and press the metal between them, forcing it outwards, and rendering the part which has been introduced between the rollers as thin as the space between their cylindrical surfaces. Thus the end of the slip of metal becomes attenuated enough to pass between the dies of the drawing machine, and to be seized by the pincers.

In using the drawing machine, a boy takes hold of the handle s of the pincers, their hook of connexion with the endless chain l, l, not shown in the present figure, being disengaged, and he moves them upon their wheels towards the die-box C. In this movement the jaws of the pincers get opened, and they are pushed up so close to the die-box that their jaws enter a hollow, which brings them near the dies, enabling them to seize the end of the slip of metal introduced between them by the action of the preparatory rollers. The boy now holds the handle s on the top of the pincers fast, and with his other hand draws the handle x backwards. Thus the jaws are closed, and the metal firmly griped. He now presses down the handle x till a hook on the under side of the pincers seizes the endless chain as it moves along, when it carries the pincers, and their slip of metal, onwards with it. Whenever the whole length of the metallic riband has passed through between the dies, the strain on the pincers is suddenly relieved, which causes the weight r to raise their hook out of the chain, and stop their motion. The machine in the mint has two sets of dies, and two endless chains, as represented in the plan, fig. 744. N N, are toothed wheels in the upper end of the die-box, furnished with pinions and levers, for turning them round, and adjusting the distance between the dies. A large spur-wheel G, is fixed upon the axis F, to give motion to the endless chains; see both figures. This spur-wheel is turned by a pinion H, fixed upon an axis m, extending across the top of the frame, and working in bearings at each end. A spur-wheel I, is fixed upon the axis m, and works into the teeth of a pinion K, upon a second axis across the frame, which carries likewise a drum wheel L, through which motion is communicated to the whole mechanism by an endless strap.

The cutting-out machine is exhibited in fig. 745. A A is a basement of stone to support an iron plate B B, on which stand the columns C C, that bear the upper part D of the frame. The iron frame of the machine E, F, E, is fixed down upon the iron plate B, B. The punch d is fixed in the lower part of the inner frame, and is moved up and down by the screw a, which is worked by wipers turned by a steam engine, impelling the lever H, and turning backwards and forwards the axis G, through a sufficient space for cutting the thickness of the metallic lamina. A boy manages this machine. There are twelve of them mounted on the same basement frame in a circular range contained in an elegant room, lighted from the roof. The whole are moved by a steam engine of 16-horse power.

The blanks or planchets thus cut out, were formerly adjusted by filing the edges, to bring them to the exact weight; a step which Mr. Barton’s ingenious mechanism has rendered in a great measure unnecessary. The edge is then milled, by a process which Mr. Boulton desires to keep secret, and which is therefore not shown in our mint.

But the French mint employs a very elegant machine for the purpose of lettering or milling the edges, called the cordon des monnaies, invented by M. Gengembre, which has entirely superseded the older milling machine of M. Castaing, described in the Encyclopedias. The Napoleon coins of France bear on the edge, in sunk letters, the legend, Dieu protège la France; and those of the king, Domine salvum fac regem. This is marked before striking the blank or flan. One machine imprints this legend, and its service is so prompt and easy, that a single man marks in a day 20,000 pieces of 5 francs, or 100,000 francs.

Each of the two arc dies E, D, (fig. 746.) carries one half of the legend, engraved in relief on the curved face; these arcs are pieces of steel tempered very hard, and fixed with two screws, one immoveably at E, on the sill which bears the apparatus; the other at D, at the extremity of the lever P, D, which turns round the axis C. The letters of these demi-legends are exactly parallel, and inscribed in an inverse order on the dies. An alternating circular motion is communicated to the handle P. The curvatures of the two dies are arcs of circles described from the centre C; and the interval which separates them, or the difference of the radii, is precisely the diameter of the piece to be milled.

As the centre C sustains the whole strain of the milling, and produces, of consequence, a hard friction, this axis must possess a considerable size. It is composed of a squat truncated cone of tempered steel, which enters into an eye of the moveable piece P, D. This cone is kept on the plate of the metal N N, which bears the whole machine, by a nut, whose screw, by being tightened or slackened, gives as much freedom as is requisite for the movement of rotation, or removes the shake which hard service gives to the cone in its eye. The middle thickness of the hole of the moveable piece P, D, and the axis of the lever P, which terminates it, are exactly on a level with the engraved letters of the die, so that no strain can derange the movable piece, or disturb the centre by its oscillations.

At a is a vertical tube, containing a pile of blanks for milling. It is kept constantly full; the tube being open at both ends, a little elevated above the circular space a, K, b, which separates the dies, and fixed by a tail m with a screw to the motionless piece A, B. The branch I, c, movable with the piece P, D, passes under the tube, and pushes before it the blank at the bottom of the column, which is received into a small excavation in the form of a circular step, and carried forwards. Matters are thus so arranged as to regulate the issue of the blanks, one by one, on the small step, called the posoir (bed.)

As soon as the blank is pushed forwards into contact with the lower edge of the engraved grooves, it is seized by them, and carried on by the strain of milling, without exposing the upper or under surfaces of the blank to any action which may obstruct the printing on its edge.

The blank is observed to revolve between the two dies according as the lever P completes its course, and this blank passing from a to K, then to b, meets a circular aperture b, through which it falls into a drawer placed under the sill.

The range of the movable lever P is regulated by four pieces, F, F, F, F, solidly sunk in the plate N, N, which bears the whole apparatus. A stud placed on this lever towards D, makes the arm of the posoir I c retire no farther than is necessary for the little blank to issue from the column; and a spring fixed to the centre c, and supported on a peg, brings back the posoir; so that when a screw I comes to strike against the column, the posoir stops, and the movable die D, which continues its progress, finds the blank in a fit position for pressing, seizing, and carrying it on, by reaction of the fixed die E. Thus the edge of the blank is lettered in half a second. A hundred may easily be marked in about three minutes.

The coining press is the most beautiful part of the whole mechanism in the British mint; but the limits of this volume will not allow of its being figured upon an adequate scale. An engraving of it may be seen in the Encyclopedia Britannica.

The only attention which this noble machine requires is that of a little boy, who stands in a sunk place before the press, and always keeps the tube full of blanks. He has two strings, one of which, when pulled, will put the press in motion by the concealed mechanism in the apartment above; and the other string, when snatched, stops the press. This coining operation goes on at the rate of 60 or 70 strokes per minute; and with very few interruptions during the whole day. The press-room at the Royal Mint contains eight machines, all supported on the same stone base; and the iron beams between the columns serve equally for the presses on each side. The whole has therefore a magnificent appearance. The eight presses will strike more than 19,000 coins in an hour, with only a child to supply each. The grand improvement in these presses, consists; 1. in the precision with which they operate to strike every coin with equal force, which could not be ensured by the old press impelled by manual labour; 2. The rising collar or steel ring in which they are struck, keeps them all of one size, and makes a fair edge, which was not the case with the old coins, as they were often rounded and defaced by the expansion of the metal under the blow; 3. The twisting motion of the upper die is thought to produce a better surface on the flat parts of the coin; but this is somewhat doubtful; 4. The feeding mechanism is very complete, and enables the machine to work much quicker than the old press did, where the workman, being in constant danger of having his fingers caught, was obliged to proceed cautiously, as well as to place the coin true on the die, which was seldom perfectly done. The feeding mechanism of the above press is a French invention; but Mr. Boulton is supposed to have improved upon it.

MIRRORS. See Copper and Glass.

MISPICKEL, is arsenical pyrites.

MOHAIR, is the hair of a goat which inhabits the mountains in the vicinity of Angora, in Asia Minor.

MOIRÉE METALLIQUE, called in this country crystallized tin-plate, is a variegated primrose appearance, produced upon the surface of tin-plate, by applying to it in a heated state some dilute nitro-muriatic acid for a few seconds, then washing it with water, drying, and coating it with lacquer. The figures are more or less beautiful and diversified, according to the degree of heat, and relative dilution of the acid. This mode of ornamenting tin-plate is much less in vogue now than it was a few years ago.

MOLASSE, is a sandstone belonging to the tertiary strata, employed under that name by the Swiss for building.

MOLASSES, is the brown viscid uncrystallizable liquor, which drains from cane sugar in the colonies. See Sugar.

MOLYBDENUM (Molybdène, Fr.; Molybdan, Germ.); is a rare metal which occurs in nature sometimes as a sulphuret, sometimes as molybdic acid, and at others as molybdate of lead. Its reduction from the acid state by charcoal requires a very high heat, and affords not very satisfactory results. When reduced by passing hydrogen over the ignited acid, it appears as an ash-gray powder, susceptible of acquiring metallic lustre by being rubbed with a steel burnisher; when reduced and fused with charcoal, it possesses a silver white colour, is very brilliant, hard, brittle, of specific gravity 8·6; it melts in a powerful air-furnace, oxidizes with heat and air, burns at an intense heat into molybdic acid, dissolves in neither dilute sulphuric, muriatic, nor fluoric acids, but in the concentrated sulphuric and nitric.

The protoxide consists of 85·69 of metal, and 14·31 of oxygen; the deutoxide consists of 75 of metal, and 25 of oxygen; and the peroxide, or molybdic acid, of 66·6 of metal, and 33·4 of oxygen. These substances are too rare at present to be used in any manufacture.

MORDANT, in dyeing and calico-printing, denotes a body which, having a twofold attraction for organic fibres and colouring particles, serves as a bond of union between them, and thus gives fixity to dyes; or it signifies a substance which, by combining with colouring particles in the pores of textile filaments, renders them insoluble in hot soapy and weak alkaline solutions. In order properly to appreciate the utility and the true functions of mordants, we must bear in mind that colouring matters are peculiar compounds possessed of certain affinities, their distinctive characters being not to be either acid or alkaline, and yet to be capable of combining with many bodies, and especially with salifiable bases, and of receiving from each of them modifications in their colour, solubility, and alterability. Organic colouring substances, when pure, have a very energetic attraction for certain bodies, feeble for others, and none at all for some. Among these immediate products of animal or vegetable life, some are soluble in pure water, and others become so only through peculiar agents. We may thus readily conceive, that whenever a dye-stuff possesses a certain affinity for the organic fibre, it will be able to become fixed on it, or to dye it without the intervention of mordants, if it be insoluble by itself in water, which, in fact, is the case with the colouring matters of safflower, annotto, and indigo. The first two are soluble in alkalis; hence, in order to use them, they need only be dissolved in a weak alkaline lye, be thus applied to the stuffs, and then have their tinctorial substance precipitated within their pores, by abstracting their solvent alkali with an acid. The colouring matter, at the instant of ceasing to be liquid, is in an extremely divided state, and is in contact with the organic fibres for which it has a certain affinity. It therefore unites with them, and, being naturally insoluble in water, that is, having no affinity for this vehicle, the subsequent washings have no effect upon the dye. The same thing may be said of indigo, although its solubility in the dye-bath does not depend upon a similar cause, but is due to a modification of its constituent elements, in consequence of which it becomes soluble in alkalis. Stuffs plunged into this indigo bath get impregnated with the solution, so that when again exposed to the air, the dyeing substance resumes at once its primitive colour and insolubility, and washing can carry off only the portions in excess above the intimate combination, or which are merely deposited upon the surface of the stuff.

Such is the result with insoluble colouring matters; but for those which are soluble it should be quite the reverse, since they do not possess an affinity for the organic fibres which can counterbalance their affinity for water. In such circumstances, the dyer must have recourse to intermediate bodies, which add their affinity for the colouring matter to that possessed by the particles of the stuff, and increase by this twofold action the intimacy and the stability of the combination. These intermediate bodies are the true mordants.

Mordants are in general found among the metallic bases or oxides; whence they might be supposed to be very numerous, like the metals; but as they must unite the twofold condition of possessing a strong affinity for both the colouring matter and the organic fibre, and as the insoluble bases are almost the only ones fit to form insoluble combinations, we may thus perceive that their number may be very limited. It is well known, that although lime and magnesia, for example, have a considerable affinity for colouring particles, and form insoluble compounds with them, yet they cannot be employed as mordants, because they possess no affinity for the textile fibres.

Experience has proved, that of all the bases, those which succeed best as mordants are alumina, tin, and oxide of iron; the first two of which, being naturally white, are the only ones which can be employed for preserving to the colour its original tint, at least without much variation. But whenever the mordant is itself coloured, it will cause the dye to take a compound colour quite different from its own. If, as is usually said, the mordant enters into a real chemical union with the stuff to be dyed, the application of the mordant should obviously be made in such circumstances as are known to be most favourable to the combination taking place; and this is the principle of every day’s practice in the dyehouse.

In order that a combination may result between two bodies, they must not only be in contact, but they must be reduced to their ultimate molecules. The mordants that are to be united with stuffs are, as we have seen, insoluble of themselves, for which reason their particles must be divided by solution in an appropriate vehicle. Now this solvent or menstruum will exert in its own favour an affinity for the mordant, which will prove to that extent an obstacle to its attraction for the stuff. Hence we must select such solvents as have a weaker affinity for the mordants than the mordants have for the stuffs. Of all the acids which can be employed to dissolve alumina, for example, vinegar is the one which will retain it with least energy, for which reason the acetate of alumina is now generally substituted for alum, because the acetic acid gives up the alumina with such readiness, that mere elevation of temperature is sufficient to effect the separation of these two substances. Before this substitution of the acetate, alum alone was employed; but without knowing the true reason, all the French dyers preferred the alum of Rome, simply regarding it to be the purest; it is only within these few years that they have understood the real grounds of this preference. This alum has not, in fact, the same composition as the alums of France, England, and Germany, but it consists chiefly of cubic alum having a larger proportion of base. Now this extra portion of base is held by the sulphuric acid more feebly than the rest, and hence is more readily detached in the form of a mordant. Nay, when a solution of cubic alum is heated, this redundant alumina falls down in the state of a subsulphate, long before it reaches the boiling point. This difference had not, however, been recognised, because Roman alum, being usually soiled with ochre on the surface, gives a turbid solution, whereby the precipitate of subsulphate of alumina escaped observation. When the liquid was filtered, and crystallized afresh, common octahedral alum alone was obtained; whence it was most erroneously concluded, that the preference given to Roman alum was unjustifiable, and that its only superiority was in being freer from iron.

Here a remarkable anecdote illustrates the necessity of extreme caution, before we venture to condemn from theory a practice found to be useful in the arts, or set about changing it. When the French were masters in Rome, one of their ablest chemists was sent thither to inspect the different manufactures, and to place them upon a level with the state of chemical knowledge. One of the fabrics, which seemed to him furthest behindhand, was precisely that of alum, and he was particularly hostile to the construction of the furnaces, in which vast boilers received heat merely at their bottoms, and could not be made to boil. He strenuously advised them to be new modelled upon a plan of his own; but, notwithstanding his advice, which was no doubt very scientific, the old routine kept its ground, supported by utility and reputation, and very fortunately, too, for the manufacture; for had the higher heat been given to the boilers, no more genuine cubical alum would have been made, since it is decomposed at a temperature of about 120° F., and common octahedral alum would alone have been produced. The addition of a little alkali to common alum brings it into the same basic state as the alum of Rome.

The two principal conditions, namely, extreme tenuity of particles, and liberty of action, being found in a mordant, its operation is certain. But as the combination to be effected is merely the result of a play of affinity between the solvent and the stuff to be dyed, a sort of partition must take place, proportioned to the mass of the solvent, as well as to its attractive force. Hence the stuff will retain more of the mordant when its solution is more concentrated, that is, when the base diffused through it is not so much protected by a large mass of menstruum; a fact applied to very valuable uses by the practical man. On impregnating in calico printing, for example, different spots of the same web with the same mordant in different degrees of concentration, there is obtained in the dye-bath a depth of colour upon these spots intense in proportion to the strength of their various mordants. Thus, with solution of acetate of alumina in different grades of density, and with madder, every shade can be produced, from the fullest red to the lightest pink; and, with acetate of iron and madder, every shade from black to pale violet.

We hereby perceive that recourse must indispensably be had to mordants at different stages of concentration; a circumstance readily realized by varying the proportions of the watery vehicle. See Calico-printing and Madder. When these mordants are to be topically applied, to produce partial dyes upon cloth, they must be thickened with starch or gum, to prevent their spreading, and to permit a sufficient body of them to become attached to the stuff. Starch answers best for the more neutral mordants, and gum for the acidulous; but so much of them should never be used, as to impede the attraction of the mordant for the cloth. Nor should the thickened mordants be of too desiccative a nature, lest they become hard, and imprison the chemical agent before it has had an opportunity of combining with the cloth, during the slow evaporation of its water and acid. Hence the mordanted goods, in such a case, should be hung up to dry in a gradual manner, and when oxygen is necessary to the fixation of the base, they should be largely exposed to the atmosphere. The foreman of the factory ought, therefore, to be thoroughly conversant with all the minutiæ of chemical reaction. In cold and damp weather he must raise the temperature of his drying-house, in order to command a more decided evaporation; and when the atmosphere is unusually dry and warm, he should add deliquescent correctives to his thickening, as I have particularized in treating of some styles of calico-printing. But, supposing the application of the mordant and its desiccation to have been properly managed, the operation is by no means complete; nay, what remains to be done is not the least important to success, nor the least delicate of execution. Let us bear in mind that the mordant is intended to combine not only with the organic fibre, but afterwards also with the colouring matter, and that, consequently, it must be laid entirely bare, or scraped clean, so to speak, that is, completely disengaged from all foreign substances which might invest it, and obstruct its intimate contact with the colouring matters. This is the principle and the object of two operations, to which the names of dunging and clearing have been given.

If the mordant applied to the surface of the cloth were completely decomposed, and the whole of its base brought into chemical union with it, a mere rinsing or scouring in water would suffice for removing the viscid substances added to it, but this never happens, whatsoever precautions may be taken; one portion of the mordant remains untouched, and besides, one part of the base of the portion decomposed does not enter into combination with the stuff, but continues loose and superfluous. All these particles, therefore, must be removed without causing any injury to the dyes. If in this predicament the stuff were merely immersed in water, the free portion of the mordant would dissolve, and would combine indiscriminately with all the parts of the cloth not mordanted, and which should be carefully protected from such combination, as well as the action of the dye. We must therefore add to the scouring water some substance that is capable of seizing the mordant as soon as it is separated from the cloth, and of forming with it an insoluble compound; by which means we shall withdraw it from the sphere of action, and prevent its affecting the rest of the stuff, or interfering with the other dyes. This result is obtained by the addition of cow-dung to the scouring bath; a substance which contains a sufficiently great proportion of soluble animal matters, and of colouring particles, for absorbing the aluminous and ferruginous salts. The heat given to the dung-bath accelerates this combination, and determines an insoluble and perfectly inert coagulum.

Thus the dung-bath produces at once the solution of the thickening paste; a more intimate union between the alumina or iron and the stuff, in proportion to its elevation of temperature, which promotes that union; an effectual subtraction of the undecomposed and superfluous part of the mordant, and perhaps a commencement of mechanical separation of the particles of alumina, which are merely dispersed among the fibres; a separation, however, which can be completed only by the proper scouring, which is done by the dash-wheel with such agitation and pressure (see Bleaching and Dunging) as vastly facilitate the expulsion of foreign particles. See also Bran.

Before concluding this article, we may say a word or two about astringents, and especially gall-nuts, which have been ranked by some writers among mordants. It is rather difficult to account for the part which they play. Of course we do not allude to their operation in the black dye, where they give the well known purple-black colour with salts of iron; but to the circumstance of their employment for madder dyes, and especially the Adrianople red. All that seems to be clearly established is, that the astringent principle or tannin, whose peculiar nature in this respect is unknown, combines like mordants with the stuffs and the colouring substance, so as to fix it; but as this tannin has itself a brown tint, it will not suit for white grounds, though it answers quite well for pink grounds. When white spots are desired upon a cloth prepared with oil and galls, they are produced by an oxygenous discharge, effected either through chlorine or chromic acid.

MORDANT, is also the name sometimes given to the adhesive matter by which gold-leaf is made to adhere to surfaces of wood and metal in gilding. Paper, vellum, taffety, &c., are easily gilt by the aid of different mordants, such as the following: 1. beer in which some honey and gum arabic have been dissolved; 2. gum arabic, sugar, and water; 3. the viscid juice of onion or hyacinth, strengthened with a little gum arabic. When too much gum is employed, the silver or gold leaf is apt to crack in the drying of the mordant. A little carmine should be mixed with the above colourless liquids, to mark the places where they are applied. The foil is applied by means of a dossil of cotton wool, and when the mordant has become hard, the foil is polished with the same.

The best medium for sticking gold and silver leaf to wood, is the following, called mixtion by the French artists:—1 pound of amber is to be fused, with 4 ounces of mastic in tears, and 1 ounce of Jewish pitch, and the whole dissolved in 1 pound of linseed oil rendered drying by litharge.

Painters in distemper sometimes increase the effect of their work, by patches of gold leaf, which they place in favourable positions; they employ the above mordant. The manufacturers of paper hangings of the finer kinds attach gold and silver leaf to them by the same varnish.

MOROCCO. See Leather.

MORPHIA (Morphine, Fr.; Morphin, Germ.), is a vegeto-alkali which exists associated with opian, codeïne, narcotine, meconine, meconic acid, resin, gum, bassorine, lignine, fat oil, caoutchouc, extractive, &c., in opium. Morphia is prepared as follows: Opium in powder is to be repeatedly digested with dilute muriatic acid, slightly heated, and sea-salt is to be added, to precipitate the opian. The filtered liquid is to be supersaturated with ammonia, which throws down the morphia, along with the meconine, resin, and extractive. The precipitate is to be washed with water, heated, and dissolved in dilute muriatic acid; the solution is to be filtered, whereby the foreign matters are separated from the salt of morphia, which concretes upon cooling, while the meconine remains in the acid liquid. The muriate of morphia having been squeezed between folds of blotting paper, is to be sprinkled with water, again squeezed, next dissolved in water, and decomposed by water of ammonia. The precipitate, when washed, dried, dissolved in alcohol, and crystallized, is morphia.

These crystals, which contain 6·32 per cent. of combined water, are transparent, colourless, four-sided prisms, without smell, and nearly void of taste, fusible at a moderate heat, and then concrete into a radiated translucent mass, but at a higher temperature they grow purple-red. Morphia consists of 72·34 of carbon; 6·366 of hydrogen; 5 of azote; and 16·3 of oxygen. It burns with a red and very smoky flame, is stained red by nitric acid, is soluble in 30 parts of boiling anhydrous alcohol, in 500 parts of boiling water, but hardly if at all in cold water, and is insoluble in ether and oils. The solutions have a strong bitter taste, and an alkaline reaction upon litmus paper. The saline compounds have a bitter taste, are mostly crystallizable, are soluble in water and alcohol (but not in ether), and give a blue colour to the peroxide salts of iron. It is a very poisonous substance. Acetate of morphia is sometimes prescribed, instead of opium, in medicine.

MORTAR, HYDRAULIC, called also Roman Cement, is the kind of mortar used for building piers, or walls under or exposed to water, such as those of harbours, docks, &c. The poorer sorts of limestone are best adapted for this purpose, such as contain from 8 to 25 per cent. of foreign matter, in silica, alumina, magnesia, &c. These, though calcined, do not slake when moistened; but if pulverized they absorb water without swelling up or heating, like fat lime, and afford a paste which hardens in a few days under water, but in the air they never acquire much solidity. Smeaton first discovered these remarkable facts, and described them in 1759.

The following analyses of different hydraulic limestones, by Berthier, merit confidence:—

No. 1. No. 2. No. 3. No. 4. No. 5.

A. Analyses of limestones.

Carbonate of lime 97·0 98·5 74·5 76·5 80·0

Carbonate of magnesia 2·0 — 23·0 3·0 1·5

Carbonate of protoxide of iron — — — 3·0 —

Carbonate of manganese — — — 1·5 —

Silica and alumina - 15·2 - 18·0

Oxide of iron 1·0 1·5 1·2

100·0 100·0 100·0 100·0 100·0

B. Analyses of the burnt lime.

Lime 96·4 97·2 78·0 68·3 70·0

Magnesia 1·8 — 20·0 2·0 1·0

Alumina 1·8 2·8 2·0 24·0 29·0

Oxide of iron — — — 5·7 —

100·0 100·0 100·0 100·0 100·0

No. 1. is from the fresh-water lime formation of Château-Landon, near Nemours; No. 2. the large-grained limestone of Paris; both of these afford a fat lime when burnt. Dolomite affords a pretty fat lime, though it contains 42 per cent. of carbonate of magnesia; No. 3. is a limestone from the neighbourhood of Paris, which yields a poor lime, possessing no hydraulic property; No. 4. is the secondary limestone of Metz; No. 5. is the lime marl of Senonches, near Dreux; both the latter have the property of hardening under water, particularly the last, which is much used at Paris on this account.

All good hydraulic mortars must contain alumina and silica; the oxides of iron and manganese, at one time considered essential, are rather prejudicial ingredients. By adding silica and alumina, or merely the former, in certain circumstances, to fat lime, a water-cement may be artificially formed; as also by adding to lime any of the following native productions, which contain silicates; puzzolana, trass or tarras, pumice-stone, basalt-tuff, slate-clay. Puzzolana is a volcanic product, which forms hills of considerable extent to the south-west of the Appenines, in the district of Rome, the Pontine marshes, Viterbo, Bolsena, and in the Neapolitan region of Puzzuoli, whence the name. A similar volcanic tufa is found in many other parts of the world. According to Berthier, the Italian puzzolana consists of 44·5 silica; 15·0 alumina; 8·8 lime; 4·7 magnesia; 1·4 potash; 4·1 soda; 12 oxides of iron and titanium; 9·2 water; in 100 parts.

The tufa stone, which when ground forms trass, is composed of 57·0 silica, 16·0 clay, 2·6 lime, 1·0 magnesia, 7·0 potash, 1·0 soda, 5 oxides of iron and titanium, 9·6 water. This tuff is found abundantly filling up valleys in beds of 10 or 20 feet deep, in the north of Ireland, among the schistose formations upon the banks of the Rhine, and at Monheim in Bavaria.

The fatter the lime, the less of it must be added to the ground puzzolana or trass, to form a hydraulic mortar; the mixture should be made extemporaneously, and must at any rate be kept dry till about to be applied. Sometimes a proportion of common sand mortar instead of lime is mixed with the trass. When the hydraulic cement hardens too soon, as in 12 hours, it is apt to crack; it is better when it takes 8 days to concrete. Through the agency of the water, silicates of lime, alumina, (magnesia), and oxide of iron are formed, which assume a stony hardness.

Besides the above two volcanic products, other native earthy compounds are used in making water cements. To this head belong all limestones which contain from 20 to 30 per cent. of clay and silica. By gentle calcination, a portion of the carbonic acid is expelled, and a little lime is combined with the clay, while a silicate of clay and lime results, associated with lime in a subcarbonated state. A lime-marl containing less clay will bear a stronger calcining heat without prejudice to its qualities as a hydraulic cement; but much also depends upon the proportion of silica present, and the physical structure of all the constituents.

The mineral substance most used in England for making such mortar, is vulgarly called cement-stone. It is a reniform limestone, which occurs distributed in single nodules or rather lenticular cakes, in beds of clay. They are mostly found in those argillaceous strata which alternate with the limestone beds of the oolite formation, as also in the clay strata above the chalk, and sometimes in the London clay. On the coasts of Kent, in the isles of Sheppey and Thanet, on the coasts of Yorkshire, Somersetshire, and the Isle of Wight, &c., these nodular concretions are found in considerable quantities, having been laid bare by the action of the sea and weather. They were called by the older mineralogists Septaria and Ludus Helmontii (Van Helmont’s coits). When sawn across, they show veins of calc-spar traversing the siliceous clay, and are then sometimes placed in the cabinets of virtuosi. They are found also in several places on the Continent, as at Neustadt-Eberswalde, near Antwerp, near Altdorf in Bavaria; as also at Boulogne-sur-mer, where they are called Boulogne-pebbles (galets). These nodules vary in size from that of a fist to a man’s head, they are of a yellow-gray or brown colour, interspersed with veins of calc-spar, and sometimes contain cavities bestudded with crystals. Their specific gravity is 2·59.

Analyses of several cement-stones, and of the cement made with them:—

No. 1. No. 2. No. 3. No. 4. No. 5.

A. Constituents of the cement-stones.

Carbonate of lime 65·7 61·6 82·9 63·8

Carb——e ofmagnesia 0·5 1·5

Carb——e ofprotoxide of iron 6·0 6·0 - 4·3 11·6

Carb——e ofmanganese 1·6

Silica 18·0 15·0 13·0 14·0

Alumina or clay 6·6 4·8 trace 5·7

Oxide of iron 3·0

Water 1·2 6·6 3·4

B. Constituents of the cement.

Lime 55·4 54·0 55·0 56·6

Magnesia 1·1

Alumina or clay 36·0 31·0 38·0 21·0

Oxide of iron 8·6 15·0 13·0 13·7

No. 1. English cement-stone, analyzed by Berthier; No. 2. Boulogne stone, by Drapiez; No. 3. English ditto, by Davy; No. 4. reniform limestone nodules from Arkona, by Hühnefeld; No. 5. cement-stone of Avallon, by Dumas.

In England the stones are calcined in shaft-kilns, or sometimes in mound-kilns, then ground, sifted, and packed in casks. The colour of the powder is dark-brown-red. When made into a thick paste with water, it absorbs little of it, evolves hardly any heat, and soon indurates. It is mixed with sharp sand in various proportions, immediately before using it; and is employed in all marine and river embankments, for securing the seams of stone or brick floors or arches from the percolation of moisture, and also for facing walls to protect them from damp.

The cement of Pouilly is prepared from a Jurassic (secondary) limestone, which contains 39 per cent. of silica, with alumina, magnesia, and iron oxide. Vicat forms a factitious Roman cement by making bricks with a pasty mixture of 4 parts of chalk, and 1 part of dry clay, drying, burning, and grinding them. River sand must be added to this powder; and even with this addition, its efficacy is somewhat doubtful; though it has, for want of a better substitute, been much employed at Paris.

The cement of Dihl consists of porcelain or salt-glaze potsherds ground fine, and mixed with boiled linseed oil.

Hamelin’s mastic or lithic paint to cover the façades of brick buildings, &c., is composed of 50 measures of siliceous sand, 50 of lime-marl, and 9 of litharge or red-lead ground up with linseed oil.

MOSAIC GOLD. For the composition of this peculiar alloy of copper and zinc, called also Or-molu, Messrs. Parker and Hamilton obtained a patent in November, 1825. Equal quantities of copper and zinc are to be “melted at the lowest temperature that copper will fuse,” which being stirred together so as to produce a perfect admixture of the metals, a further quantity of zinc is added in small portions, until the alloy in the melting pot becomes of the colour required. If the temperature of the copper be too high, a portion of the zinc will fly off in vapour, and the result will be merely spelter or hard solder; but if the operation be carried on at as low a heat as possible, the alloy will assume first a brassy yellow colour; then, by the introduction of small portions of zinc, it will take a purple or violet hue, and will ultimately become perfectly white; which is the appearance of the proper compound in its fused state. This alloy may be poured into ingots; but as it is difficult to preserve its character when re-melted, it should be cast directly into the figured moulds. The patentees claim the exclusive right of compounding a metal consisting of from 52 to 55 parts of zinc out of 100.

Mosaic gold, the aurum musivum of the old chemists, is a sulphuret of tin.

MOSAIC. (Mosaïque, Fr.; Mosaisch, Germ.) There are several kinds of mosaic, but all of them consist in imbedding fragments of different coloured substances, usually glass or stones, in a cement, so as to produce the effect of a picture. The beautiful chapel of Saint Lawrence in Florence, which contains the tombs of the Medici, has been greatly admired by artists, on account of the vast multitude of precious marbles, jaspers, agates, avanturines, malachites, &c., applied in mosaic upon its walls. The detailed discussion of this subject belongs to a treatise upon the fine arts.

MOTHER OF PEARL (Nacre de Perles, Fr.; Perlen mutter, Germ.); is the hard, silvery, brilliant internal layer of several kinds of shells, particularly oysters, which is often variegated with changing purple and azure colours. The large oysters of the Indian seas alone secrete this coat of sufficient thickness to render their shells available to the purposes of manufactures. The genus of shell fish called pentadinæ furnishes the finest pearls, as well as mother of pearl; it is found in greatest perfection round the coasts of Ceylon, near Ormus in the Persian Gulf, at Cape Comorin, and among some of the Australian seas. The brilliant hues of mother of pearl, do not depend upon the nature of the substance, but upon its structure. The microscopic wrinkles or furrows which run across the surface of every slice, act upon the reflected light in such a way as to produce the chromatic effect; for Sir David Brewster has shown, that if we take, with very fine black wax, or with the fusible alloy of D’Arcet, an impression of mother of pearl, it will possess the iridescent appearance. Mother of pearl is very delicate to work, but it may be fashioned by saws, files, and drills, with the aid sometimes of a corrosive acid, such as the dilute sulphuric or muriatic; and it is polished by colcothar of vitriol.

MOTHER-WATER, is the name of the liquid which remains after all the salts that will regularly crystallize have been extracted, by evaporation and cooling, from any saline solution.

MOUNTAIN SOAP (Savon de montagne, Fr.; Bergseife, Germ.); is a tender mineral, soft to the touch, which assumes a greasy lustre when rubbed, and falls to pieces in water. It consists of silica 44, alumina 26·5, water 20·5, oxide of iron 8, lime 0·5. It occurs in beds, alternating with different sorts of clay, in the Isle of Skye, at Billin in Bohemia, &c. It has been often, but improperly, confounded with steatite.

MUCIC ACID (Acid mucique, Fr.; Schleimsaüre, Germ.); is the same as the saclactic acid of Scheele, and may be obtained by digesting one part of gum arabic, sugar of milk, or pectic acid, with twice or thrice their weight of nitric acid. It forms white granular crystals, and has not been applied to any use in the arts.

MUCILAGE, is a solution in water of gummy matter of any kind.

MUFFLE, is the earthenware case or box, in the assay furnaces, for receiving the cupels, and protecting them from being disturbed by the fuel. See Assay and Furnace.

MUNDIC, is the name of copper pyrites among English miners.

MUNJEET, is a kind of madder grown in several parts of India.

MURIATIC or HYDROCHLORIC ACID; anciently marine acid, and spirit of salt. (Acide hydrochlorique, and Chlorhydrique, Fr.; Salzsaüre, Germ.) This acid is now extracted from sea-salt, by the action of sulphuric acid and a moderate heat; but it was originally obtained from the salt by exposing a mixture of it and of common clay to ignition in an earthen retort. The acid gas which exhales, is rapidly condensed by water. 100 cubic inches of water are capable of absorbing no less than 48,000 cubic inches of the acid gas, whereby the liquid acquires a specific gravity of 1·2109; and a volume of 142 cubic inches. This vast condensation is accompanied with a great production of heat, whence it becomes necessary to apply artificial refrigeration, especially if so strong an acid as the above is to be prepared. In general, the muriatic acid of commerce has a specific gravity varying from 1·15 to 1·20; and contains, for the most part, considerably less than 40 parts by weight of acid gas in the hundred. The above stronger acid contains 42·68 per cent. by weight; for since a cubic inch of water, which weighs 252·5 grains, has absorbed 480 cubic inches = 188 grains of gas; and 252·5 + 188 = 440·5; then 440·5 : 188 ∷ 100 : 42·68. In general a very good approximation may be found to the percentage of real muriatic acid, in any liquid sample, by multiplying the decimal figures of the specific gravity by 200. Thus for example, at 1·162 we shall have by this rule 0·162 × 200 = 32·4, for the quantity of gas in 100 parts of the liquid. Muriatic acid gas consists of chlorine and hydrogen combined, without condensation, in equal volumes. Its specific gravity is 1·247, air = 1·000.

By sealing up muriate of ammonia and sulphuric acid, apart, in a strong glass tube recurved, and then causing them to act on each other, Sir H. Davy procured liquid muriatic acid. He justly observes, that the generation of elastic substances in close vessels, either with or without heat, offers much more powerful means of approximating their molecules than those dependent on the application of cold, whether natural or artificial; for as gases diminish only ⁄480 in volume for every degree of Fahrenheit’s scale, beginning at ordinary temperatures, a very slight condensation only can be produced by the most powerful freezing mixtures, not half as much as would result from the application of a strong flame to one part of a glass tube, the other part being of ordinary temperature: and when attempts are made to condense gases into liquids by sudden mechanical compression, the heat instantly generated presents a formidable obstacle to the success of the experiment; whereas in the compression resulting from their slow generation in close vessels, if the process be conducted with common precautions, there is no source of difficulty or danger; and it may be easily assisted by artificial cold, in cases where gases approach near to that point of compression and temperature at which they become vapours.—Phil. Trans. 1823.

The muriatic acid of commerce has usually a yellowish tinge, but when chemically pure it is colourless. It fumes strongly in the air, emitting a corrosive vapour of a peculiar smell. The characteristic test of muriatic acid in the most dilute state, is nitrate of silver, which causes a curdy precipitate of chloride of silver.

The preparation of this acid upon the great scale is frequently effected in this country by acting upon sea-salt in hemispherical iron pots, or in cast-iron cylinders, with concentrated sulphuric acid; taking 6 parts of the salt to 5 of the acid. The mouth of the pot may be covered with a slab of siliceous freestone, perforated with two holes of about two inches diameter each, into the one of which the acid is poured by a funnel in successive portions, and into the other, a bent glass, or stone-ware tube, is fixed, for conducting the disengaged muriatic gas into a series of large globes of bottle glass, one-third filled with water, and laid on a sloping sand-bed. A week is commonly employed for working off each pot; no heat being applied to it till the second day.

The decomposition of sea-salt by sulphuric acid, was at one time carried on by some French manufacturers in large leaden pans, 10 feet long, 5 feet broad, and a foot deep, covered with sheets of lead, and luted. The disengaged acid gas was made to circulate in a conduit of glazed bricks, nearly 650 yards long, where it was condensed by a sheet of water exceedingly thin, which flowed slowly in the opposite direction of the gas down a slope of 1 in 200. At the end of this canal nearest the apparatus, the muriatic acid was as strong as possible, and pretty pure; but towards the other end, the water was hardly acidulous. The condensing part of this apparatus was therefore tolerably complete; but as the decomposition of the salt could not be finished in the leaden pans, the acid mixture had to be drawn out of them, in order to be completely decomposed in a reverberatory furnace; in this way nearly 50 per cent. of the muriatic acid was lost. And besides, the great quantity of gas given off during the emptying of the lead-chambers was apt to suffocate the workmen, or seriously injured their lungs, causing severe hemoptysis. The employment of muriatic acid is so inconsiderable, and the loss of it incurred in the preceding process is of so little consequence, that subsequently, both in France and in England, sulphate of soda, for the soda manufacture, has been procured with the dissipation of the muriatic acid in the air. In the method more lately resorted to, the gaseous products are discharged into extensive vaults, where currents of water condense them and carry them off into the river. The surrounding vegetation is thereby saved in some measure from being burned up, an accident which was previously sure to happen when fogs precipitated the floating gases upon the ground. At Newcastle, Liverpool, and Marseilles, where the consumption of muriatic acid bears no proportion to the manufacture of soda, this process is now practised upon a vast scale.

The apparatus for condensing muriatic acid gas has been modified and changed, of late years, in many different ways.

The Bastringue apparatus. At the end of a reverberatory furnace, (see Copper, smelting of, and Soda, manufacture of,) a rectangular lead trough or pan, about 1 foot deep, of a width equal to that of the interior of the furnace, that is about 5 feet wide, and 6⁄2 feet long, is encased in masonry, having its upper edges covered with cast-iron plates or fire tiles, and placed upon a level with the passage of the flame, as it escapes from the reverberatory. The arch which covers that pan forms a continuation of the roof of the reverberatory, and is of the same height. The flame which proceeds from the furnace containing the mixture of salt and sulphuric acid is made to escape between the vault and the surface of the iron plates or fire tiles, through a passage only 4 inches in height. When the burned air and vapours reach the extremity of the pan, they are reflected downwards, and made to return beneath the bottom of the pan, in a flue, which is afterwards divided so as to lead the smoke into two lateral flues, which terminate in the chimney. The pan is thus surrounded as it were with the heat and flame discharged from the reverberatory furnace. See Evaporation. A door is opened near the end of the pan, for introducing the charge of sea-salt, amounting to 12 bags of 2 cwt. each, or 24 cwt. This door is then luted on as tightly as possible, and for every 100 parts of salt, 110 of sulphuric acid are poured in, of specific gravity 1·594, containing 57 per cent. of dry acid. This acid is introduced through a funnel inserted in the roof of the furnace. Decomposition ensues, muriatic acid gas mingled with steam is disengaged, and is conducted through 4 stone-ware tubes into the refrigerators, where it is finally condensed. These refrigerators consist of large stone-ware carboys, called dame-jeans in France, to the number of 7 or 8 for each pipe, and arranged so that the neck of the one communicates with the body of the other; thus the gas must traverse the whole series, and gets in a good measure condensed by the water in them, before reaching the last.

When the operation is finished, the door opposite the pan is opened, and the residuum in it, is discharged, in the form of a fluid magma, upon a square bed of bricks, exterior to the furnace. This paste speedily concretes on cooling, and is then broken into fragments and carried to the soda manufactory. The immense quantity of gas exhaled in discharging the pan, renders this part of the operation very painful to the workmen; and wasteful in reference to the production of muriatic acid. The difficulty of luting securely the cast-iron plates or fire tiles which cover the pan, the impossibility of completing the decomposition of the salt, since the residuum must be run off in a liquid state, finally, the damage sustained by the melting and corrosion of the lead, &c., are among the causes why no more than 80 or 90 parts of muriatic acid at 1·170 are collected, equivalent to 25 per cent. of real acid for every 100 of salt employed, instead of much more than double that quantity, which it may be made to yield by a well conducted chemical process.

The cylinder apparatus is now much esteemed by many manufacturers. Fig. 747. represents, in transverse section, a bench of iron cylinder retorts, as built up in a proper furnace for producing muriatic acid; and fig. 748. a longitudinal section of one retort with one of its carboys of condensation. a is the grate; b, a fireplace, in which two iron cylinders, c c, are set alongside of each other. They are 5⁄2 feet long, 20 inches in diameter, about ⁄4 of an inch thick, and take 1·6 cwts. of salt for a charge; d is the ash-pit; e, e, are cast-iron lids, for closing both ends of the cylinders; f is a tube in the posterior lid, for pouring in the sulphuric acid; g is another tube, in the anterior lid, for the insertion of the bent pipe of hard glazed stone-ware h; i is a three-necked stone-ware carboy; k is a tube of safety; l, a tube of communication with the second carboy; m m, m m, are the flues leading to the chimney n.

After the salt has been introduced, and the fire kindled, 83⁄4 per cent. of its weight of sulphuric acid, of spec. grav. 1·80, should be slowly poured into the cylinder through a lead funnel, with a syphon-formed pipe. The three-necked carboys may be either placed in a series for each retort, like a range of Woulfe’s bottles, or all the carboys of the front range may be placed in communication with one another, while the last carboy at one end is joined to the first of the second range; and thus in succession. They must be half filled with cold water; and when convenient, those of the front row at least, should be plunged in an oblong trough of running water. The acid which condenses in the carboys of that row is apt to be somewhat contaminated with sulphuric acid, muriate of iron, or even sulphate of soda; but that in the second and third will be found to be pure. In this way 100 parts of sea-salt will yield 130 parts of muriatic acid, of spec. grav. 1·19; while the sulphate of soda in the retort will afford from 208 to 210 of that salt in crystals.

It is proper to heat all the parts of the cylinders equably, to insure the simultaneous decomposition of the salt, and to protect it from the acid; for the hotter the iron, and the stronger the acid, the less erosion ensues.

Some manufacturers, with the view of saving fuel by the construction of their furnaces oppose to the flame as many obstacles as they can, and make it perform numerous circulations round the cylinders; but this system is bad, and does not even effect the desired economy, because the passages, being narrow, impair the draught, and become speedily choked up with the soot, which would be burned profitably in a freer space; the decomposition also, being unequally performed, is less perfect, and the cylinders are more injured. It is better to make the flame envelope at once the body of the cylinder; after which it may circulate beneath the vault, in order to give out a portion of its caloric before it escapes at the chimney.

The fire should be briskly kindled, but lowered as soon as the distillation commences; and then continued moderate till the evolution of gas diminishes, when it must be heated somewhat strongly to finish the decomposition. The iron door is now removed, to extract the sulphate of soda, and to recommence another operation. This sulphate ought to be white and uniform, exhibiting in its fracture no undecomposed sea-salt.

Liquid muriatic acid has a very sour corrosive taste, a pungent suffocating smell, and acts very powerfully upon a vast number of mineral, vegetable, and animal substances. It is much employed for making many metallic solutions; and in combination with nitric acid, it forms the aqua regia of the alchemists, so called from its property of dissolving gold.

Table of Muriatic Acid, by Dr. Ure.

Acid
of 120
in 100. Specific
gravity. Chlorine. Muriatic
Gas.

100 1·2000 39·675 40·777

99 1·1982 39·278 40·369

98 1·1964 38·882 39·961

97 1·1946 38·485 39·554

96 1·1928 38·089 39·146

95 1·1910 37·692 38·738

94 1·1893 37·296 38·330

93 1·1875 36·900 37·923

92 1·1857 36·503 37·516

91 1·1846 36·107 37·108

90 1·1822 35·707 36·700

89 1·1802 35·310 36·292

88 1·1782 34·913 35·884

87 1·1762 34·517 35·476

86 1·1741 34·121 35·068

85 1·1721 33·724 34·660

84 1·1701 33·328 34·252

83 1·1681 32·931 33·845

82 1·1661 32·535 33·437

81 1·1641 32·136 33·029

80 1·1620 31·746 32·621

79 1·1599 31·343 32·213

78 1·1578 30·946 31·805

77 1·1557 30·550 31·398

76 1·1536 30·153 30·990

75 1·1515 29·757 30·582

74 1·1494 29·361 30·174

73 1·1473 28·964 29·767

72 1·1452 28·567 29·359

71 1·1431 28·171 28·951

70 1·1410 27·772 28·544

69 1·1389 27·376 28·136

68 1·1369 26·979 27·728

67 1·1349 26·583 27·321

66 1·1328 26·186 26·913

65 1·1308 25·789 26·505

64 1·1287 25·392 26·098

63 1·1267 24·996 25·690

62 1·1247 24·599 25·282

61 1·1226 24·202 24·874

60 1·1206 23·805 24·466

59 1·1185 23·408 24·058

58 1·1164 23·012 23·050

57 1·1143 22·615 23·242

56 1·1123 22·218 22·834

55 1·1102 21·822 22·426

54 1·1082 21·425 22·019

53 1·1061 21·028 21·611

52 1·1041 20·632 21·203

51 1·1020 20·235 20·796

50 1·1000 19·837 20·388

49 1·0980 19·440 19·980

48 1·0960 19·044 19·572

47 1·0939 18·647 19·165

46 1·0919 18·250 18·757

45 1·0899 17·854 18·349

44 1·0879 17·457 17·941

43 1·0859 17·060 17·534

42 1·0838 16·664 17·126

41 1·0818 16·267 16·718

40 1·0798 15·870 16·310

39 1·0778 15·474 15·902

38 1·0758 15·077 15·494

37 1·0738 14·680 15·087

36 1·0718 14·284 14·679

35 1·0697 13·887 14·271

34 1·0677 13·490 13·863

33 1·0657 13·094 13·456

32 1·0637 12·697 13·049

31 1·0617 12·300 12·641

30 1·0597 11·903 12·233

29 1·0577 11·506 11·825

28 1·0557 11·109 11·418

27 1·0537 10·712 11·010

26 1·0517 10·316 10·602

25 1·0497 9·919 10·194

24 1·0477 9·522 9·786

23 1·0457 9·126 9·379

22 1·0437 8·729 8·971

21 1·0417 8·332 8·563

20 1·0397 7·935 8·155

19 1·0377 7·538 7·747

18 1·0357 7·141 7·340

17 1·0337 6·745 6·932

16 1·0318 6·348 6·524

15 1·0298 5·951 6·116

14 1·0279 5·554 5·709

13 1·0259 5·158 5·301

12 1·0239 4·762 4·893

11 1·0220 4·365 4·486

10 1·0200 3·968 4·078

9 1·0180 3·571 3·670

8 1·0160 3·174 3·262

7 1·0140 2·778 2·854

6 1·0120 2·381 2·447

5 1·0100 1·984 2·039

4 1·0080 1·588 1·631

3 1·0060 1·191 1·224

2 1·0040 0·795 0·816

1 1·0020 0·397 0·408

MURIATES were, till the great chemical era of Sir H. Davy’s researches upon chlorine, considered to be compounds of an undecompounded acid, the muriatic, with the different bases; but he proved them to be in reality compounds of chlorine with the metals. They are all, however, still known in commerce by their former appellation. The only muriates much used in the manufactures are, Muriate of ammonia, or Sal ammoniac; muriated peroxide of mercury, Mercury, bichloride of; muriate of soda, or chloride of sodium, see Salt; muriate of tin, see Calico-printing and Tin.

MUSK (Musc, Fr.; Moschus, Germ.), is a peculiar aromatic substance, found in a sac between the navel and the parts of generation of a small male quadruped of the deer kind, called by Linnæus, Moschus moschiferus, which inhabits Tonquin and Thibet. The colour of musk is blackish-brown; it is lumpy or granular, somewhat like dried blood, with which substance, indeed, it is often adulterated. The intensity of its smell is almost the only criterion of its genuineness. When thoroughly dried it becomes nearly scentless; but it recovers its odour when slightly moistened with water of ammonia. The Tonquin musk is most esteemed. It comes to us in small bags covered with a reddish-brown hair; the bag of the Thibet musk is covered with a silver-gray hair. All the analyses of musk hitherto made, teach little or nothing concerning its active or essential constituent. It is used in medicines, and is an ingredient in a great many perfumes.

MUSLIN, is a fine cotton fabric, used for ladies’ robes; which is worn either white, dyed, or printed.

MUST, is the sweet juice of the grape.

MUSTARD (Moutarde, Fr.; Senf, Germ.); is a plant which yields the well-known seed used as a condiment to food. M. Lenormand gives the following prescription for preparing mustard for the table.

With 2 pounds of very fine flour of mustard, mix half an ounce of each of the following fresh plants; parsley, chervil, celery, and tarragon, along with a clove of garlic, and twelve salt anchovies, all well minced. The whole is to be triturated with the flour of mustard till the mixture becomes uniform. A little grape-must or sugar is to be added, to give the requisite sweetness; then one ounce of salt, with sufficient water to form a thinnish paste by rubbing in a mortar. With this paste the mustard pots being nearly filled, a redhot poker is to be thrust down into the contents of each, which removes (it is said) some of the acrimony of the mustard, and evaporates a little water, so as to make room for pouring a little vinegar upon the surface of the paste. Such table mustard not only keeps perfectly well, but improves with age.

The mode of preparing table mustard patented by M. Soyés, consisted in steeping mustard seed in twice its bulk of weak wood vinegar for eight days, then grinding the whole into paste in a mill, putting it into pots, and thrusting a redhot poker into each of them.

MUTAGE, is a process used in the south of France to arrest the progress of fermentation in the must of the grape. It consists either in diffusing sulphurous acid, from burning sulphur matches in the cask containing the must, or in adding a little sulphite (not sulphate) of lime to it. The last is the best process. See Fermentation.

MYRICINE, is a vegetable principle which constitutes from 20 to 30 per cent. of the weight of bees-wax, being the residuum from the solvent action of alcohol upon that substance. It is a grayish-white solid, which may be vaporized almost without alteration.

MYRRH, is a gum-resin, which occurs in tears of different sizes; they are reddish-brown, semi-transparent, brittle, of a shining fracture, appear as if greasy under the pestle, they have a very acrid and bitter taste, and a strong, not disagreeable, smell. Myrrh flows from the incisions of a tree not well known, which grows in Arabia and Abyssinia, supposed to be a species of amyris or mimosa. It consists of resin and gum in proportions stated by Pelletier at 31 of the former and 66 of the latter; but by Braconnot, at 23 and 77. It is used only in medicine.