Chapter 3
P. (part 2)
In Mr. Buddle’s system all these evils are guarded against, as far as human science and foresight can go. He makes the pillars very large, and the rooms or boards narrow; the pillars being in general 12 yards broad, and 24 yards long; the boards 4 yards wide, and the walls or thirlings cut through the pillars from one board to another, only 5 feet wide, for the purpose of ventilation. In the figure, the rooms are represented as proceeding from the dip to the crop, and the panel walls act as barriers thrown round the area of the panel, to prevent the weight of the superincumbent strata from overrunning the adjoining panels. Again, when the pillars of a panel are to be worked, one range of pillars, as at I (in H), is first attacked; and as the workmen cut away the furthest pillars, columns of prop-wood are erected betwixt the pavement and the roof, within a few feet of each other (as shown by the dots), till an area of above 100 square yards is cleared of pillars, presenting a body of-strata perhaps 130 fathoms thick, suspended clear and without support, except at the line of the surrounding pillars. This operation is termed working the goaff. The only use of the prop-wood is to prevent the seam, which forms the ceiling over the workmen’s heads, from falling down and killing them by its splintery fragments. Experience has proved, that before proceeding to take away another set of pillars, it is necessary to allow the last-made goaff to fall. The workmen then begin to draw out the props, which is a most hazardous employment. They begin at the more remote props, and knock them down one after another, retreating quickly under the protection of the remaining props. Meanwhile the roof-stratum begins to break by the sides of the pillars, and falls down in immense pieces; while the workmen still persevere, boldly drawing and retreating till every prop is removed. Nay, should any props be so firmly fixed by the top pressure, that they will not give way to the blows of heavy mauls, they are cut through with axes; the workmen making a point of honour to leave not a single prop in the goaff. The miners next proceed to cut away the pillars nearest to the sides of the goaff, setting prop-wood, then drawing it, and retiring as before, until every panel is removed, excepting small portions of pillars which require to be left under dangerous stones to protect the retreat of the workmen. While this operation is going forward, and the goaff extending, the superincumbent strata being exposed without support over a large area, break progressively higher up; and when strong beds of sandstone are thus giving way, the noise of the rending rocks is very peculiar and terrific; at one time loud and sharp, at another hollow and deep.
As the pillars of the panels are taken away, the panel walls are also worked progressively backwards to the pit bottom; so that only a very small proportion of coal is eventually lost. This method is undoubtedly the best for working such coals as those of Newcastle, considering their great depth beneath the surface, their comparative softness, and the profusion of inflammable air. It is evident that the larger the pillars and panel walls are, in the first working, the greater will be the security of the miners, and the greater the certainty of taking out, in the second stage, the largest proportion of coal. This system may be applied to many of the British collieries; and it will produce a vast quantity of coals beyond the post and stall methods, so generally persisted in.
In thus tearing to pieces the massive rocks over his head, the miner displays a determined and cool intrepidity; but his ingenuity is no less to be admired in contriving modes of carrying currents of pure atmospheric air through every turning of his gloomy labyrinth, so as to sweep away the explosive spirit of the mine.
The fourth system of working coal, is called the long way, the long-wall, and the Shropshire method. The plan must at first have been extremely hazardous; though now it is so improved as to be reckoned as safe, if not safer, to the workmen, than the other methods, with rooms and pillars.
The object of the Shropshire system, is to begin at the pit-bottom pillars, and to cut away at once every inch of coal progressively forward, and to allow the whole superincumbent strata to crush down behind and over the heads of the workmen. This plan is pursued chiefly with coals that are thin, and is very seldom adopted when the seam is 7 feet thick; from 4 to 5 feet being reckoned the most favourable thickness for proceeding with comfort, amidst ordinary circumstances, as to roof, pavement, &c. When a pit is opened on a coal to be treated by this method, the position of the coals above the lowest seam sunk to, must first be considered; if the coal beds be contiguous, it will be proper to work the upper one first, and the rest in succession downwards; but if they are 8 fathoms or more apart, with strata of strong texture betwixt them, the working of the lower coals in the first place will do no injury to that of the upper coals, except breaking them, perhaps, a little. In many instances, indeed, by this operation on a lower coal, upper coals are rendered more easily worked.
When the operation is commenced by working on the Shropshire plan, the dip-head levels are driven in the usual manner, and very large bottom pillars are formed, as represented in fig. 844. Along the rise side of the dip-head level, chains of wall, or long pillars, are also made, from 8 to 10 yards in breadth, and only mined through occasionally, for the sake of ventilation, or of forming new roads. In other cases no pillars are left upon the rise side of the level; but, instead of them, buildings of stone are reared, 4 feet broad at the base, and 9 or 10 feet from the dip side of the level. Though the roads are made 9 feet wide at first, they are reduced to half that width after the full pressure of the strata is upon them. Whenever these points are secured, the operation of cutting away the whole body of the coal begins. The place where the coal is removed, is named the gobb or waste; and gobbin, or gobb-stuff, is stones or rubbish taken away from the coal, pavement, or roof, to fill up that excavation as much as possible, in order to prevent the crush of superincumbent strata from causing heavy falls, or following the workmen too fast in their descent. Coals mined in this manner work most easily according to the way in which the widest backs and cutters are; and therefore, in the Shropshire mode, the walls stand sometimes in one direction, and sometimes in another; the mine always turning out the best coals when the open backs and cutters face the workmen. As roads must be maintained through the crushed strata, the miners in the first place cut away about 15 feet of coal round the pit-bottom pillars, and along the upper sides of the dip-head chain walls; and then, at the distance of 9 or 10 feet, carry regular buildings of stone 3 feet broad, with props set flush with the faces of these, if necessary. As the miners advance, they erect small pillars of roof or pavement stone in regular lines with the wall face, and sometimes with props intermediate.
There are two principal modifications of the Shropshire plan. The first, or the original system, was to open out the wall round the pit-bottom; and, as the wall face extended, to set off main roads and branches, very like the branches of a tree. These roads were so distributed, that between the ends of any two branches there should be a distance of 30 or 40 yards, as might be most convenient. (see fig. 844.) Each space of coal betwixt the roads is called a wall; and one half of the coals produced from each wall is carried to the one road, and the other half to the other road. This is a great convenience when the roof is bad; and hence a distance of only 20 yards betwixt the roads is in many instances preferred. In fig. 844. A represents the shaft; B B, the wall-face; a, the dip-head level; b, the roads, from 20 to 40 yards asunder; c, the gobb or waste, with buildings along the sides of the roads; and d, the pillars.
The other Shropshire system is represented in fig. 845., where A shows the pit, with the bottom pillars; b, the dip-head levels; c, the off-break from the level, where no pillars are left; d, the off-break, where pillars remain to secure the level. All roads are protected in the sides by stone buildings, if they can be had, laid off 9 feet wide. After the crush settles, the roads generally remain permanently good, and can, in many cases, be travelled through as easily 50 years after they have been made, as at the first. Should stones not be forthcoming, coals must be substituted, which are built about 20 inches in the base. In this method, the roads are likewise from 20 to 40 yards apart; but instead of ramifying, they are arranged parallel to each other. The miners secure the waste by gobbing; and three rows of props are carried forwards next the wall faces a, with pillars of stone or of coal reared betwixt them. This mode has a more regular appearance than the other; though it is not so generally practised.
In the post and stall system, each man has his own room, and performs all the labour of it; but in that of Shropshire, there is a division of labour among the workmen, who are generally divided into three companies. The first set curves or pools the coal along the whole line of walls, laying in or pooling at least 3 feet, and frequently 45 inches, or 5 quarters, as it is called. These men are named holers. As the crush is constantly following them, and impending over their heads, causing frequent falls of coal, they plant props of wood for their protection at regular distances in an oblique direction between the pavement and wall face. Indeed, as a further precaution, staples of coal, about 10 inches square, are left at every 6 or 8 yards, till the line of holing or curving is completed. The walls are then marked off into spaces of from 6 to 8 yards in length; and at each space a shearing or vertical cut is made, as deep as the holing; and when this is done, the holer’s work is finished. The set who succeed the holers, are called getters. These commence their operations at the centre of the wall divisions, and drive out the gibbs and staples. They next set wedges along the roof, and bring down progressively each division of coal; or, if the roof be hard-bound, the coal is blown down with gunpowder. When the roof has a good parting, the coals frequently fall down the moment the gibbs are struck; which makes the work very easy. The getters are relieved in their turn by the third set, named butty-men, who break down the coals into pieces of a proper size for sending up the shaft, and take charge of turning out the coal from the wall face to the ends of the roads. This being done, they build up the stone pillars, fill up the gobb, set the trees, clear the wall faces of all obstructions, set the gibbs, and make every thing clear and open for the holers to resume their work. If the roads are to be heightened by taking down the roof, or removing the pavement, these butty-men do this work also, building forwards the sides of the roads, and securing them with the requisite props. When a coal has a following or roof stone, which regularly separates with the coal, this facilitates the labour, and saves much of the coal; and should a soft bed of fire-clay occur a foot or two beneath the coal-seam, the holing is made in it, instead of into the coal, and the stone betwixt the holing and the coal benched down, which serves for pillars and gobbing. In this way all the vendible coal becomes available.
Another form of the Shropshire system is, for each miner to have from 6 to 12 feet of coal before him, with a leading-hand man; and for the several workmen to follow in succession, like the steps of a stair. When the coal has open backs and cutters, this work goes on very regularly, as represented in fig. 846., where the leading miner is at a, next to the outcrop, and b b, &c. are the wall faces of each workman; A being the shaft, and B the dip-head level. In this case the roads are carried either progressively through the gobb, or the gobb is entirely shut up; and the whole of the coals are brought down the wall-faces, either to the dip-head level or the road c, c. This method may be varied by making the walls broad enough to hold two, three, or four men when each set of miners performs the whole work of holing, getting, breaking down, and carrying off the coals.
It is estimated that from one-eighth to one-twelfth part only of the coals remains underground by the Shropshire plan; nay, in favourable circumstances, almost every inch of coal may be taken out, as its principle is to leave no solid pillars nor any coal below, except what may be indispensable for securing the gobb. Indeed this system might be applied to coal seams of almost any ordinary thickness, providing stuff to fill up the gobb could be conveniently procured.
In Great Britain, seams of coal are mined when they are only 18 inches thick; but if thinner, the working of fire-clay or ironstone immediately adjoining must be included. A few instances may be adduced, indeed, where caking coals of a fine quality for blacksmiths have been worked, though only in 12-inch seams.
Eighteen-inch seams are best worked by young lads and boys. The coal itself may be mined without lifting the pavement, or taking down the roof in the rooms; but roads must be cut either in the pavement or the roof, for removing the coals to the pit-bottom. All coals less than 2 feet 3 inches thick, are worked with the view of taking out all the coal, either on the Shropshire system, or with pillar-walls and rooms; with this peculiarity, that, on account of the thinness of the seam, the rooms are worked as wide as the roof will bear up; or if a following of the roof-stone, or fall of it, can be brought on, it proves advantageous, by not only giving head-room, but by filling up the waste, and rendering the roads easily kept for the working of the pillars. Where no following takes place, small temporary pillars, about 8 feet square, are left along the chain-wall side. The walls may vary in thickness from 4 to 16 yards, according to circumstances, and they are holed through only for ventilation.
Coals from 5 to 8 feet thick are the best suited in every point of view for the effective work of the miner, and for the general economy of underground operations. When they exceed that thickness, they require very excellent roofs and pavements, to render the working either safe or comfortable; or to enable those who superintend the field to get out a fair proportion of coal from a given area. In such powerful beds the Shropshire method is impracticable, from want of gobbin; and long props, unless of prodigious girth, would present an inadequate resistance to the pressure of the massive ceiling.
When coals do not exceed 20 feet in thickness, and have good roofs, they are sometimes worked as one bed of coal; but if the coal be tender or free, it is worked as two beds. One-half of such thick coal, however, is in general lost in pillars; and it is very seldom that less than one-third can be left. When the coal is free and ready to crumble by the incumbent pressure, as well as by the action of the air, the upper portion of the coal is first worked, then a scaffolding of coal is left, 2 or 3 feet thick, according to the compactness of the coal; and the lower part of the coal is now worked, as shown in fig. 847. As soon as the workings are completed to the proposed extent, the coal scaffoldings are worked away, and as much of the pillars as can be removed with safety. As propwood is of no use in coal seams of such a height, and as falls from the roof would prove frequently fatal to the miners, it is customary with tender roofs to leave a ceiling of coal from 2 to 3 feet thick. This makes an excellent roof; and should it break, gives warning beforehand, by a peculiar crackling noise, very different from that of roof-stones crushing down.
One of the thickest coals in Great Britain, worked as one bed from roof to pavement, is the very remarkable seam near the town of Dudley, known by the name of the ten-yard coal, about 7 miles long, and 4 broad. No similar coal has been found in the island; and the mode of working it is quite peculiar, being a species of panel work totally different from the modern Newcastle system. A compartment, or pannel, formed in working the coal, is called a side of work; and as the whole operation is exhibited in one of these compartments, it will be proper to describe the mode of taking the coal from one of them, before describing the whole extent of the workings of a mine.
Let fig. 848. represent a side of work; A, the ribs or walls of coal left standing round, constituting the side of work; a, the pillars, 8 yards square; c, the stalls, 11 yards wide; d, the cross openings, or through puts, also 11 yards wide; e, the bolt-hole, cut through the rib from the main road, by which bolt-hole the side of work is opened up, and all the coals removed. Two, three, or even four bolt-holes open into a side of work, according to its extent; they are about 8 feet wide, and 9 feet high. The working is in a great measure regulated by the natural fissures and joints of the coal-seam; and though it is 30 feet thick, the lower band, of 2 feet 3 inches, is worked first; the miners choosing to confine themselves within this narrow opening, in order to gain the greater advantage afterwards, in working the superjacent coal. Whenever the bolt hole is cut through, the work is opened up by driving a gallery forward, 4 feet wide, as shown by the dotted lines. At the sides of this gallery next the bolt-hole, each miner breaks off in succession a breast of coal, two yards broad, as at f, f, by means of which the sides of the rib-walls A, are formed, and the area of the pillars. In this way each collier follows another, as in one of the systems of the Shropshire plan. When the side of work is laid open along the rib-walls, and the faces and sides of the pillars have been formed, the upper coals are then begun to be worked, next the rib-wall. This is done by shearing up to a bed next the bolt-hole, and on each side, whereby the head coals are brought regularly down in large cubical masses, of such thickness as suits with the free partings or subordinate divisions of the coals and bands. Props of wood, or even stone pillars, are placed at convenient distances for the security of the miners.
In working the ten-yard coal, a very large proportion of it is left underground, not merely in pillars and rib-walls, but in the state of small coal produced in breaking out the coal. Hence, from four-tenths to a half of the total amount is lost for ever.
Another method of working coal of uncommon thickness, is by scaffoldings or stages of coals, as practised in the great coal bed at Johnstone, near Paisley, of which a section has already been given. In one part of the field the coal is from 50 to 60 feet thick, and in another it amounts to 90 feet. The seams of stone interspersed through the coal are generally inconsiderable, and amount in only two cases to 27 inches in thickness. The roof of the coal is so unsound, and the height so prodigious, that it could not possibly be worked in one seam, like that of Staffordshire. About 3 feet of the upper coal is therefore left as a roof, under which a band of coal, from 6 to 7 feet thick, is worked on the post and stall plan, with square pillars of extra strength, which are thereafter penetrated. A platform about 3 feet high is left at the sole; under which the rooms and pillars are set off and worked in another portion of the coal, from 5 to 7 feet thick, great care being had to place pillar under pillar, and partition under partition, to prevent a crush. Where the coal is thickest, no less than 10 bands of it are worked in this way, as is shown in fig. 849. When any band of the coal is foul from sulphur or other causes, it is left for the next platform, so that a large proportion of it is lost, as in the Staffordshire mines. Much attention must here be paid to the vertical distribution of the pillars and apartments; the miner’s compass must be continually consulted, and bore-holes must be put down through the coal scaffoldings, to regulate correctly the position of the pillars under one another.
Edge coals, which are nearly perpendicular, are worked in a peculiar manner; for the collier stands upon the coal, having the roof on the one hand, and the floor on the other, like two vertical walls. The engine-pit is sunk in the most powerful stratum. In some instances the same stratum is so vertical as to be sunk through for the whole depth of the shaft.
Whenever the shaft has descended to the required depth, galleries are driven across the strata from its bottom, till the coals are intersected, as is shown in fig. 850., where we see the edge coals at a, a; A, the engine-pit; b, b, the transverse galleries from the bottom of the shaft; and c, c, upper transverse galleries, for the greater conveniency of working the coal. The principal edge coal works in Great Britain lie in the neighbourhood of Edinburgh, and the coals are carried on the backs of women from the wall-face to the bottom of the engine-pit.
The modes of carrying coals from the point where they are excavated to the pit bottom, are nearly as diversified as the systems of working.
One method employs hutches, or baskets, having slips or cradle feet shod with iron, containing from 2 to 3 hundred weight of coals. These baskets are dragged along the floor by ropes or leather harness attached to the shoulders of the workmen, who are either the colliers or persons hired on purpose. This method is used in several small collieries; but it is extremely injudicious, exercising the muscular action of a man in the most unprofitable manner. Instead of men, horses are sometimes yoked to these basket-hurdles, which are then made to contain from 4 to 6 hundred weight of coals; but from the magnitude of the friction, this plan cannot be commended.
An improvement on this system, where men draw the coals, is to place the basket or corve on a small four-wheeled carriage, called a tram, or to attach wheels to the corve itself. Thus much more work is performed, provided the floor be hard; but not on a soft pavement, unless some kind of wooden railway be laid.
The transport of coals from the wall-face to the bottom of the shaft, was greatly facilitated by the introduction of cast-iron railways, in place of wooden roads, first brought into practice by Mr. John Curr of Sheffield. The rails are called tram-rails, or plate-rails, consisting of a plate from 3 to 4 inches broad, with an edge at right angles to it about two inches and a half high. Each rail is from 3 to 4 feet long, and is fixed either to cross bearers of iron, called sleepers, or more usually to wooden bearers. In some collieries, the miners, after working out the coals, drag them along these railways to the pit bottom; but in others, two persons called trammers are employed to transport the coals; the one of whom, in front of the corve, draws with harness; and the other, called the patter, pushes behind. The instant each corve arrives, from the wall-face, at a central spot in the system of the railways, it is lifted from the tram by a crane placed there, and placed on a carriage called a rolley, which generally holds two corves. Whenever three or four rolleys are loaded, they are hooked together, and the rolley driver, with his horse, takes them to the bottom of the engine-shaft. The rolley horses have a peculiar kind of shafts, commonly made of iron, named limbers, the purpose of which is to prevent the carriage from overrunning them. One of these shafts is represented in fig. 851. The hole shown at a, passes over an iron peg or stud in front of the rolley, so that the horse may be quickly attached or disengaged. By these arrangements the work is carried on with surprising regularity and despatch.
The power of the engine for drawing the coals up the shaft, is made proportional to the depth of the pit and the quantity to be raised, the corves ascending at an average velocity of about 12 feet per second. So admirable is the modern arrangement of this operation, that the corves are transported from the wall-faces to the pit bottom, and moved up the shaft, as fast as the onsetters at the bottom, and the banksmen at the top, can hook the loaded and empty corves on and off the engine ropes. Thus 100 corves of coals have been raised every hour up a shaft 100 fathoms deep, constituting a lift of 27 tons per hour, or 324 tons in a day, or shift of 12 hours. Coals mined in large cubical masses cannot, however, be so rapidly raised as the smaller coal of the Newcastle district.
When coals have so great a rise from the pit bottom to the crop that horses cannot be used on the rolley ways, the corves descend along the tram-roads, by means of inclined-plane machines, which are moved either by vertical rope-barrels, or horizontal rope-sheaves. These inclined planes are frequently divided into successive stages, 200 or 300 yards long, at the end of each of which is an inclined-plane machine, whereby the coals are lowered from one level to another.
The wheels of the trams and rolleys vary in diameter from 8 to 16 inches, according to the thickness of the coal. In some, the axles not only revolve on their journals, but the wheels also revolve on their axles.
Various forms of machines have been employed for raising the coals out of the pits. The steam engine with fly-wheel and rope-barrels, is, however, now preferred in all considerable establishments. When of small power, they are usually constructed with a fly wheel, and short fly-wheel shaft, on which there is a small pinion working into the teeth of a large wheel, fixed upon the rope barrel. Thus the engine may move with great rapidity, while it imparts an equable slow motion to the corves ascending in the shaft. When the engines are of great power, however, they are directly connected with the rope-barrel; some of these being of such dimensions, that each revolution of the rope-barrel produces an elevation of 12 yards in the corve. A powerful brake is usually connected with the circumference of the fly-wheel or rope-barrel, whereby the brakeman, by applying his foot to the governing lever of the brake, and by shutting at the same time the steam valves with his hands, can arrest the corve, or pitch its arrival within a few inches of the required height of every delivery. An endless chain, suspended from the bottom to the top of the shaft, has, in a few pits of moderate depth, been worked by a steam engine, for raising corves in constant succession; but the practice has not been found hitherto applicable on the greater scale.
There is a kind of water engines for raising coals, strictly admissible only in level free pits, where the ascent of the loaded corve is produced by the descent of a cassoon filled with water. When the ascent and descent are through equal spaces, the rope barrels for the cassoon and the corves are of equal diameter; but when the point from which the coals have to be lifted is deeper than the point of discharge for the water into the dry level, the cassoon must be larger, and the rope barrel smaller; so that by the time the cassoon reaches to the half-depth, for example, the corve may have mounted through double the space. The cassoon is filled with water at the pit mouth, and is emptied by a self-acting valve whenever it gets to the bottom. The loaded corve is replaced by an empty one at the pit mouth, and its weight, with that of the descending rope, pull up the empty cassoon; the motions of the whole mechanism being regulated by a powerful brake.
Various plans have been devised to prevent collision between the ascending and descending corves, which sometimes pass each other with a joint velocity of 20 or 30 feet per second. One method is by dividing the pit from top to bottom, so that each corve moves in a separate compartment. Another mode was invented by Mr. Curr of Sheffield, in which wooden guides were attached from top to bottom of the pit; being spars of deal about 4 inches square, attached perpendicularly to the sides of the shaft, and to buntons in the middle of the pit. Betwixt these guides, friction-roller sliders are placed, attached to the gin-ropes, to which sliders the corves are suspended. In this way, the corves can be raised with great rapidity; but there is a considerable loss of time in banking the corve at the pit mouth, where shutters or sliding boards must be used. This plan is highly beneficial where the coals are in large lumps.
Both ropes and chains are used for lifting coals. The round ropes are shroud-laid; but the preferable rope is the flat band, made of four ropes placed horizontally together, the ropes being laid alternately right and left. In this way, the ropes counteract one another in the twist, hanging like a ribbon down the shaft; and are stitched strongly together by a small cord. Such rope bands are not only very pliable for their strength, which protects the heart of the rope from breaking, but as they lap upon themselves, a simple sheave serves as a rope-barrel. They possess the additional advantage, that by so lapping, they enlarge the diameter of the axle in which they coil, and thus make a compensation mechanically against the increasing length of rope descending with its corve. Thus the counterpoise chains, used in deep pits to regulate the descent, have been superseded. See Rope-spinning.
When chains are preferred to ropes, as in very deep pits, the short pudding-link chains are mostly used. See Cable.
The corves after being landed or banked at the pit mouth, are drawn to the bin or coal-hill, either upon slips by horses, or by trammers on a tram-road. But with small coals, like the Newcastle, the pit head is raised 8 or 9 feet above the common level of the ground, and the coal-heap slopes downwards from that height. As the bins increase, tram-roads are laid outwards upon them.
I shall now describe the ventilation of coal mines. Into their furthest recesses, an adequate supply of fresh air must be carried forwards, for the purposes of respiration, and the combustion of candles; as also for clearing off the carbonic acid and carburetted hydrogen gases, so destructive to the miners, who call these noxious airs, from their most obvious qualities, choke-damp and fire-damp.
Before the steam engine was applied to the drainage of the mines, and the extraction of the coal, the excavations were of such limited extent, that when inflammable air accumulated in the foreheads, it was usual in many collieries to fire it every morning. This was done by fixing a lighted candle to the end of a long pole, which being extended towards the roof by a person lying flat on the floor, the gas was fired, and the blast passed safely over him. If the gas was abundant, the explosive miner put on a wet jacket, to prevent the fire from scorching him. In other situations, where the fire-damp was still more copious, the candle was drawn forwards into it, by a cord passing over a catch at the end of the gallery, while the operator stood at a distance. This very rude and dangerous mode of exploding the inflammable gas, is still practised in a few mines, under the name of the firing line.
The carbonic acid or choke-damp having a greater specific gravity than atmospheric air, in the proportion of about 3 to 2, occupies the lower part of the workings, and gives comparatively little annoyance. Its presence may moreover be always safely ascertained by the lighted candle. This cannot, however, be said of the fire-damp, which being lighter and more movable, diffuses readily through the atmospheric air, so as to form a most dangerous explosive mixture, even at a considerable distance from the blowers or sources of its extrication from the coal strata. Pure subcarburetted hydrogen has a specific gravity = 0·555, air being 1; and consists of a volume of vapour of carbon, and two volumes of hydrogen, condensed by mutual affinity into one volume. The choke-damp is a mixture of the above, with a little carbonic acid gas, and variable proportions of atmospheric air. As the pure subcarburetted hydrogen requires twice its bulk of oxygen to consume it completely, it will take for the same effect about 10 times its bulk of atmospheric air, since this volume of air contains about two volumes of oxygen. Ten volumes of air, therefore, mixed with one volume of subcarburetted hydrogen, form the most powerfully explosive mixture. If either less or more air be intermixed, the explosive force will be impaired; till 3 volumes of air below or above that ratio, constitute non-explosive mixtures; that is, 1 of the pure fire-damp mixed with either 7 or 13 of air, or any quantity below the first, or above the second number, will afford an unexplosive mixture. With the first proportion, a candle will not burn; with the second, it burns with a very elongated blue flame. The fire-damp should therefore be still further diluted with common air, considerably beyond the above proportion of 1 to 13, to render the working of the mine perfectly safe.
These noxious gases are disengaged from the cutters, fissures, and minute pores of the coal; and if the quantity be considerable, relative to the orifice, a hissing noise is heard.
Though the choke-damp, or carbonic acid gas, be invisible, yet its line of division from the common air is distinctly observable on approaching a lighted candle to the lower level, where it accumulates, which becomes extinguished the instant it comes within its sphere, as if it were plunged in water. The stratum of carbonic acid sometimes lies 1 or 2 feet thick on the floor, while the superincumbent air is perfectly good. When the coal has a considerable dip and rise, the choke-damp will be found occupying the lower parts of the mine, in a wedge form, as represented in fig. 852., where a shows the place of the carbonic acid gas, and b that of the common air.
When a gallery is driven in advance of the other workings, and a discharge of this gas takes place, it soon fills the whole mine, if its direction be in the line of level, and the mine is rendered unworkable until a supply of fresh air is introduced to dislodge it. As the flame of a candle indicates correctly the existence of the choke-damp, the miners may have sufficient warning of its presence, so as to avoid the place which it occupies, till adequate means be taken to drive it away.
The fire-damp is not an inmate of every mine, and is seldom found, indeed, where the carbonic acid prevails. It occurs in the greatest quantities in the coal mines of the counties of Northumberland, Durham, Cumberland, Staffordshire, and Shropshire. It is more abundant in coals of the caking kind, with a bright steel-grained fracture, than in cubic coals of an open-burning quality. Splint coals are still less liable to disengage this gas. In some extensive coal-fields it exists copiously on one range of the line of bearing, while on the other range, none of it is observed, but abundance of carbonic acid gas.
In the numerous collieries in the Lothians, south from the city of Edinburgh, the fire-damp is unknown; while in the coal-fields round the city of Glasgow, and along the coast of Ayrshire, it frequently appears.
The violent discharge of the gas from a crevice or cutter of the coal, is called a blower; and if this be ignited, it burns like an immense blowpipe, inflaming the coal at the opposite side of the gallery. The gas evidently exists in a highly compressed and elastic state; whence it seems to loosen the texture of the coals replete with it, and renders them more easily worked. The gas is often peculiarly abundant near a great dislocation or slip of the strata; so that the fissure of the dislocation will sometimes emit a copious stream of gas for many years. It has also happened, that from certain coals, newly worked, and let fall from a height into the hold of a vessel, so much inflammable gas has been extricated that, after the hatches were secured, and the ship ready to proceed to sea, the gas has ignited with the flame of a candle, so as to scorch the seamen, to blow up the decks, and otherwise damage the vessel. In like manner, when the pillars in a mine are crushed by sudden pressure, a great discharge of gas ensues. This gas being lighter than common air, always ascends to the roof or to the rise of the galleries; and, where the dip is considerable, occupies the forehead of the mine, in a wedge form, as shown in fig. 853., where a represents the fire-damp, and b the common air. In this case, a candle will burn without danger near the point c, close to the floor; but if it be advanced a few feet further towards the roof, an explosion will immediately ensue; since at the line where the two elastic fluids are in contact, they mix, and form an explosive body.
When this gas is largely diluted with air, the workmen do not seem to feel any inconvenience from breathing the mixture for a period of many years; but on inhaling pure carburetted hydrogen, the miner instantly drops down insensible, and, if not speedily removed into fresh air, he dies. The production of these noxious gases renders ventilation a primary object in the system of mining. The most easily managed is the carbonic acid. If an air-pipe has been carried down the engine pit for the purpose of ventilation in the sinking, other pipes are connected with it, and laid along the pavement, or are attached to an angle of the mine next the roof. These pipes are prolonged with the galleries, by which means the air at the forehead is drawn up the pipes and replaced by atmospheric air, which descends by the shaft in an equable current, regulated by the draught of the furnace at the pit mouth. This circulation is continued till the miners cut through upon the second shaft, when the air-pipes become superfluous; for it is well known that the instant such communication is made, as is represented in fig. 854., the air spontaneously descends in the engine pit A, and, passing along the gallery a, ascends in a steady current in the second pit B. The air, in sinking through A, has at first the atmospheric temperature, which in winter may be at or under the freezing point of water; but its temperature increases in passing down through the relatively warmer earth, and ascends in the shaft B, warmer than the atmosphere. When shafts are of unequal depths, as represented in the figure, the current of air flows pretty uniformly in one direction. If the second shaft has the same depth with the first, and the bottom and mouth of both be in the same horizontal plane, the air would sometimes remain at rest, as water would do in an inverted syphon, and at other times would circulate down one pit and up another, not always in the same direction, but sometimes up the one, and sometimes up the other, according to the variations of temperature at the surface, and the barometrical pressures, as modified by winds. There is in mines a proper heat, proportional to their depth, increasing about one degree of Fahrenheit’s scale for every 60 feet of descent.
There is a simple mode of conducting air from the pit bottom to the forehead of the mine, by cutting a ragglin, or trumpeting, as it is termed, in the side of the gallery, as represented in fig. 855., where A exhibits the gallery in the coal, and B the ragglin, which is from 15 to 18 inches square. The coal itself forms three sides of the air-pipe, and the fourth is composed of thin deals applied air-tight, and nailed to small props of wood fixed between the top and bottom of the lips of the ragglin. This mode is very generally adopted in running galleries of communication, and dip-head level galleries, where carbonic acid abounds, or when from the stagnation of the air the miners’ lights burn dimly.
When the ragglin or air-pipes are not made spontaneously active, the air is sometimes impelled through them by means of ventilating fanners, having their tube placed at the pit bottom, while the vanes are driven with great velocity by a wheel and pinion worked with the hand. In other cases, large bellows like those of the blacksmith, furnished with a wide nozzle, are made to act in a similar way with the fanners. But these are merely temporary expedients for small mines. A very slight circulation of air can be effected by propulsion, in comparison of what may be done by exhaustion; and hence it is better to attach the air-pipe to the valve of the bellows, than to their nozzle.
Ventilation of collieries has been likewise effected on a small scale, by attaching a horizontal funnel to the top of air-pipes elevated a considerable height above the pit mouth. The funnel revolves on a pivot, and by its tail-piece places its mouth so as to receive the wind. At other times, a circulation of air is produced by placing coal-fires in iron grates, either at the bottom of an upcast pit, or suspended by a chain a few fathoms down.
Such are some of the more common methods practised in collieries of moderate depth, where carbonic acid abounds, or where there is a total stagnation of air. But in all great coal mines the aërial circulation is regulated and directed by double doors, called main or bearing doors. These are true air-valves, which intercept a current of air moving in one direction from mixing with another moving in a different direction. Such valves are placed on the main roads and passages of the galleries, and are essential to a just ventilation. Their functions are represented in the annexed fig. 856., where A shows the downcast shaft, in which the aerial current is made to descend; B is the upcast shaft, sunk towards the rise of the coal; and C, the dip-head level. Were the mine here figured to be worked without any attention to the circulation, the air would flow down the pit A, and proceed in a direct line up the rise mine to the shaft B, in which it would ascend. The consequence would therefore be, that all the galleries and boards to the dip of the pit A, and those lying on each side of the pits, would have no circulation of air; or, in the language of the collier, would be laid dead. To obviate this result, double doors are placed in three of the galleries adjoining the pit; viz., at a and b, c and d, e and f; all of which open inwards to the shaft A. By this plan, as the air is not suffered to pass directly from the shaft A to the shaft B, through the doors a and b, it would have taken the next shortest direction by c d and e f; but the doors in these galleries prevent this course, and compel it to proceed downwards to the dip-head level C, where it will spread or divide, one portion pursuing a route to the right, another to the left. On arriving at the boards g and h, it would have naturally ascended by them; but this it cannot do, by reason of the building or stopping placed at g and h. By means of such stoppings placed in the boards next the dip-head level, the air can be transported to the right hand or to the left for many miles, if necessary, providing there be a train or circle of aerial communication from the pit A to the pit B. If the boards i and k are open, the air will ascend in them, as traced out by the arrows; and after being diffused through the workings, will again meet in a body at a, and mount the gallery to the pit B, sweeping away with it the deleterious air which it meets in its path. Without double doors on each main passage, the regular circulation of the air would be constantly liable to interruptions and derangements; thus, suppose the door c to be removed, and only d to remain in the left hand gallery, all the other doors being as represented, it is obvious, that whenever the door d is opened, the air, finding a more direct passage in that direction, would mount by the nearest channel l, to the shaft B, and lay dead all the other parts of the work, stopping all circulation. As the passages on which the doors are placed constitute the main roads by which the miners go to and from their work, and as the corves are also constantly wheeling along all the time, were a single door, such as d, so often opened, the ventilation would be rendered precarious or languid. But the double doors obviate this inconvenience; for both men and horses, with the corves, in going to or from the pit bottom A, no sooner enter the door d, than it shuts behind them, and encloses them in the still air contained between the doors d and c; c having prevented the air from changing its proper course while d was open. When d is again shut, the door c may be opened without inconvenience, to allow the men and horses to pass on to the pit bottom at A; the door d preventing any change in the aerial circulation while the door c is open. In returning from the pit, the same rule is observed, of shutting one of the double doors, before the other is opened.
If this mode of disjoining and insulating air-courses from each other be once fairly conceived, the continuance of the separation through a working of any extent, may be easily understood.
When carbonic acid gas abounds, or when the fire-damp is in very small quantity, the air may be conducted from the shaft to the dip-head level, and by placing stoppings of each room next the level, it may be carried to any distance along the dip-head levels; and the furthest room on each side being left open, the air is suffered to diffuse itself through the wastes, along the wall faces, and mount in the upcast pit, as is represented in fig. 842. But should the air become stagnant along the wall faces, stoppings are set up throughout the galleries, in such a way as to direct the main body of fresh air along the wall faces for the workmen, while a partial stream of air is allowed to pass through the stoppings, to prevent any accumulation of foul air in the wastes.
In very deep and extensive collieries more elaborate arrangements for ventilation are introduced. Here the circulation is made active by rarefying the air at the upcast shaft, by means of a very large furnace placed either at the bottom or top of the shaft. The former position is generally preferred. Fig. 834. exhibits a furnace placed at the top of the pit. When it surmounts a single pit, or a single division of the pit, the compartment intended for the upcast is made air-tight at top, by placing strong buntons or beams across it, at any suitable distance from the mouth. On these buntons a close scaffolding of plank is laid, which is well plastered or moated over with adhesive plastic clay. A little way below the scaffold, a passage is previously cut, either in a sloping direction, to connect the current of air with the furnace, or it is laid horizontally, and then communicates with the furnace by a vertical opening. If any obstacle prevent the scaffold from being erected within the pit, this can be made air-tight at top, and a brick flue carried thence along the surface to the furnace.
The furnace has a size proportional to the magnitude of the ventilation, and the chimneys are either round or square, being from 50 to 100 feet high, with an inside diameter of from 5 to 9 feet at bottom, tapering upwards to a diameter of from 2⁄2 feet to 5 feet. Such stalks are made 9 inches thick in the body of the building, and a little thicker at bottom, where they are lined with fire-bricks.
The plan of placing the furnace at the bottom of the pit is, however, more advantageous, because the shaft through which the air ascends to the furnace at the pit mouth, is always at the ordinary temperature; so that whenever the top furnace is neglected, the circulation of air throughout the mine becomes languid, and dangerous to the workmen; whereas, when the furnace is situated at the bottom of the shaft, its sides get heated, like those of a chimney, through its total length, so that though the heat of the furnace be accidentally allowed to decline or become extinct for a little, the circulation will still go on, the air of the upcast pit being rarefied by the heat remaining in the sides of the shaft.
To prevent the annoyance to the onsetters at the bottom, from the hot smoke, the following plan has been adopted, as shown in the wood-cut, fig. 857., where a represents the lower part of the upcast shaft; b, the furnace, built of brick, arched at top, with its sides insulated from the solid mass of coal which surrounds it. Between the furnace wall and the coal-beds, a current of air constantly passes towards the shaft, in order to prevent the coal catching fire. From the end of the furnace a gallery is cut in a rising direction at c, which communicates with the shaft at d, about 7 or 8 fathoms from the bottom of the pit. Thus the furnace and furnace-keeper are completely disjoined from the shaft; and the pit bottom is not only free from all encumbrances, but remains comfortably cool. To obviate the inconveniences from the smoke to the banksmen in landing the coals at the pit mouth, the following plan has been contrived for the Newcastle collieries. Fig. 858. represents the mouth of the pit; a is the upcast shaft, provided with a furnace at bottom; b, the downcast shaft, by which the supply of atmospheric air descends; and d, the brattice carried above the pit mouth. A little way below the settle-boards, a gallery c, is pushed, in communication with the surface from the downcast shaft, over which a brick tube or chimney is built from 60 to 80 feet high, 7 or 8 feet diameter at bottom, and 4 or 5 feet diameter at top. On the top of this chimney a deal funnel is suspended horizontally on a pivot, like a turn-cap. The vane f, made also of deal, keeps the mouth of the funnel always in the same direction with the wind. The same mechanism is mounted at the upcast shaft a, only here the funnel is made to present its mouth in the wind’s eye. It is obvious from the figure, that a high wind will rather aid than check the ventilation by this plan.
The principle of ventilation being thus established, the next object in opening up a colliery, and in driving all galleries whatever, is the double mine or double headways course; on the simple but very ingenious distribution of which, the circulation of air depends at the commencement of the excavations.
The double headways course is represented in fig. 859., where a is the one heading or gallery, and b the other; the former being immediately connected with the upcast side of the pit c, and the latter with the downcast side of the pit d. The pit itself is made completely air-tight by its division of deals from top to bottom, called the brattice wall; so that no air can pass through the brattice from d to c, and the intercourse betwixt the two currents of air is completely intercepted by a stopping betwixt the pit bottom and the end of the first pillar of coal; the pillars or walls of coal, marked e, are called stenting walls; and the openings betwixt them, walls or thirlings. The arrows show the direction of the air. The headings a and b are generally made about 9 feet wide, the stenting walls 6 or 8 yards thick, and are holed or thirled at such a distance as may be most suitable for the state of the air. The thirlings are 5 feet wide.
When the headings are set off from the pit bottom, an aperture is left in the brattice at the end of the pillar next the pit, through which the circulation betwixt the upcast and downcast pits is carried on; but whenever the workmen cut through the first thirling No. 1., the aperture in the brattice at the pit bottom is shut; in consequence of which the air is immediately drawn by the power of the upcast shaft through that thirling as represented by the dotted arrow. Thus a direct stream of fresh air is obviously brought close to the forehead where the mines are at work. The two headings a and b are then advanced, and as soon as the thirling No. 2. is cut through, a wall of brick and mortar, 4⁄2 inches thick, is built across the thirling No. 1. This wall is termed a stopping; and being air-tight, it forces the whole circulation through the thirling No. 2. In this manner the air is always led forward, and caused to circulate always by the last-made thirling next the forehead; care being had, that whenever a new thirling is made, the last thirling through which the air was circulated, be secured with an air-tight stopping. In the woodcut, the stoppings are placed in the thirlings numbered 1, 2, 3, 4, 5, 6, and of consequence the whole circulation passes through the thirling No. 7., which lies nearest the foreheads of the headings a, b. By inspecting the figure, we observe, that on this very simple plan, a stream of air may be circulated to any required distance, and in any direction, however tortuous. Thus, for example, if while the double headways course a, b, is pushed forward, other double headways courses are required to be carried on at the same time on both sides of the first headway, the same general principles have only to be attended to as shown in fig. 860., where a is the upcast, and b the downcast shaft. The air advances along the heading c, but cannot proceed further in that direction than the pillar d, being obstructed by the double doors at e. It therefore advances in the direction of the arrows to the foreheads at f, and passing through the last thirling made there, returns to the opposite side of the double doors, ascends now the heading g to the foreheads at h, passes through the last-made thirling at that point, and descends, in the heading i, till it is interrupted by the double doors at k. The aerial current now moves along the heading l, to the foreheads at m, returns by the last-made thirling there, along the heading n, and finally goes down the heading o, and mounts by the upcast shaft a, carrying with it all the noxious gases which it encountered during its circuitous journey. This wood-cut is a faithful representation of the system by which collieries of the greatest extent are worked and ventilated. In some of these, the air courses are from 30 to 40 miles long. Thus the air conducted by the medium of a shaft divided by a brattice wall only a few inches thick, after descending in the downcast in one compartment of the pit at 6 o’clock in the morning, must thence travel through a circuit of nearly 30 miles, and cannot arrive at its reascending compartment on the other side of the brattice, or pit partition, till 6 o’clock in the evening, supposing it to move all the time at the rate of 2⁄2 miles per hour. Hence we see that the primum mobile of this mighty circulation, the furnace, must be carefully looked after, since its irregularities may affect the comfort, or even the existence of hundreds of miners spread over these vast subterraneous labyrinths. On the principles just laid down, it appears, that if any number of boards be set off from any side of these galleries, either in a level, dip, or rise direction, the circulation of air may be advanced to each forehead, by an ingoing and returning current.
Yet while the circulation of fresh air is thus advanced to the last-made thirling next the foreheads f, h, and m, fig. 860., and moves through the thirling which is nearest to the face of every board and room, the emission of fire-damp is frequently so abundant from the coaly strata, that the miners dare not proceed forwards more than a few feet from that aerial circulation, without hazard of being burned by the combustion of the gas at their candles. To guard against this accident, temporary shifting brattices are employed. These are formed of deal, about ⁄4 of an inch thick, 3 or 4 feet broad, and 10 feet long; and are furnished with cross-bars for binding the deals together, and a few finger loops cut through them, for lifting them more expeditiously, in order to place them in a proper position. Where inflammable air abounds, a store of such brattice deals should be kept ready for emergencies.
The mode of applying these temporary brattices, or deal partitions, is shown in the accompanying figure (fig. 861.), which shows how the air circulates freely through the thirling d, d before the brattices are placed. At b and c, we see two heading boards or rooms, which are so full of inflammable air as to be unworkable. Props are now erected near the upper end of the pillar e, betwixt the roof and pavement, about two feet clear of the sides of the next pillar, leaving room for the miner to pass along between the pillar side and the brattice. The brattices are then fastened with nails to the props, the lower edge of the under brattice resting on the pavement, while the upper edge of the upper is in contact with the roof. By this means any variation of the height in the bed of coal is compensated by the overlap of the brattice boards; and as these are advanced, shifting brattices are laid close to, and alongside of, the first set. The miner next sets up additional props in the same parallel line with the former, and slides the brattices forwards, to make the air circulate close to the forehead where he is working; and he regulates the distance betwixt the brattice and the forehead by the disengagement of fire-damp and the velocity of the aerial circulation. The props are shown at d d, and the brattices at f, f. By this arrangement the air is prevented from passing directly through the thirling a, and is forced along the right-hand side of the brattice, and, sweeping over the wall face or forehead, returns by the back of the brattice, and passes through the thirling a. It is prevented, however, from returning in its former direction by the brattice planted in the forehead c, whereby it mounts up and accomplishes its return close to that forehead. Thus headways and boards are ventilated till another thirling is made at the upper part of the pillar. The thirling a is then closed by a brick stopping, and the brattice boards removed forward for a similar operation.
When blowers occur in the roof, and force the strata down, so as to produce a large vaulted excavation, the accumulated gas must be swept away; because, after filling that space, it would descend in an unmixed state under the common roof of the coal. The manner of removing it is represented in fig. 862., where a is the bed of coal, b the blower, c the excavation left by the downfall of the roof, d is a passing door, and e a brattice. By this arrangement the aerial current is carried close to the roof, and constantly sweeps off or dilutes the inflammable gas of the blower, as fast as it issues. The arrows show the direction of the current; but for which, the accumulating gas would be mixed in explosive proportions with the atmospheric air, and destroy the miners.
There is another modification of the ventilating system, where the air-courses are traversed across; that is, when one air-course is advanced at right angles to another, and must pass it in order to ventilate the workings on the further side. This is accomplished on the plan shown in fig. 863., where a is a main road with an air-course, over which the other air-course b, has to pass. The sides of this air channel are built of bricks arched over so as to be air-tight, and a gallery is driven in the roof strata as shown in the figure. If an air-course, as a, be laid over with planks made air-tight, crossing and recrossing may be effected with facility. The general velocity of the air in these ventilating channels is from 3 to 4 feet per second, or about 2⁄2 miles per hour, and their internal dimensions vary from 5 to 6 feet square, affording an area of from 25 to 36 square feet.
Mr. Taylor’s hydraulic air-pump, formerly described, p. 839., deserves to be noticed among the various ingenious contrivances for ventilating mines, particularly when they are of moderate extent. a is a large wooden tub, nearly filled with water, through whose bottom the ventilating pipe b passes down into the recesses of the mine. Upon the top of b, there is a valve e, opening upwards. Over b, the gasometer vessel is inverted in a, having a valve also opening outwards at d. When this vessel is depressed by any moving force, the air contained within it is expelled through d; and when it is raised, it diminishes the atmospherical pressure in the pipe b, and thus draws air out of the mine into the gasometer; which cannot return on account of the valve at e, but is thrown out into the atmosphere through d at the next descent.
The general plan of distributing the air, in all cases, is to send the first of the current that descends in the downcast shaft among the horses in the stables, next among the workmen in the foreheads, after which the air, loaded with whatever mixtures it may have received, is made to traverse the old wastes. It then passes through the furnace with all the inflammable gas it has collected, ascends the upcast shaft, and is dispersed into the atmosphere. This system, styled coursing the air, was invented by Mr. Spedding of Cumberland. According to the quantity of the fire-damp, the coursing is conducted either up one room, and returned by the next alternately, through the whole extent of the works, or it passes along 2 or 3 connected rooms, and returns by the same number.
This admirable system has received the greatest improvements from the mining engineers of the Newcastle district, and especially from Mr. Buddle of Wallsend. His plan being a most complete scale of ventilation, where the aerial current is made to sweep every corner of the workings, is shown in fig. 865.; in which a represents the downcast, and b the upcast shaft. By pursuing the track of the arrows, we may observe that the air passes first along the two rooms c, d, having free access to each through the walls, but is hindered from entering into the adjoining rooms by the stoppings which form the air-courses. It sweeps along the wall faces of the rooms c, d, and makes a return down the rooms e, f, but is not allowed to proceed further in that direction by the stoppings g, h. It then proceeds to the foreheads i, k, and single courses all the rooms to the foreheads l, m; from this point it would go directly to the upcast pit b, were it not prevented by the stopping n, which throws it again into double coursing the rooms, till it arrives at o, whence it goes directly to the furnace, and ascends the shaft b. The lines across each other represent the passing doors; and these may be substituted in any place for a passage where there is a stopping. The stopping p, near the bottom of the downcast shaft, is termed a main stopping; because if it were removed, the whole circulation would instantly cease, and the air, instead of traversing in the direction of the arrows, would go directly from the downcast pit a, to the upcast pit b, along the gallery q. Hence every gallery and room of the workings would be laid dead, as it is termed, and be immediately filled with fire-damp, which might take fire either at the workmen’s candles, or at the furnace next the upcast shaft b. Thus also a partial stagnation in one district of the colliery, would be produced by any of the common stoppings being accidentally removed or destroyed, since the air would thereby always pursue the nearest route to the upcast pit. Main stoppings are made particularly secure, by strong additional stone buildings, and they are set up at different places, to maintain the main air courses entire in the event of an explosion; by which precautions great security is given to human life. This system of ventilation may be extended to almost any distance from the pit-bottom, provided the volume of fresh air introduced be adequate to dilute sufficiently the fire-damp, so that the mixture shall not reach the explosive point. The air, by this management, ventilates first one panel of work, and then other panels in succession, passing onwards through the barriers or panel walls, by means of galleries, as in fig. 843., by the principle either of single, double, or triple coursing, according to the quantity of gas in the mine.
In ventilating the very thick coal of Staffordshire, though there is much inflammable air, less care is needed than in the north of England collieries, as the workings are very roomy, and the air courses of comparatively small extent. The air is conducted down one shaft, carried along the main roads, and distributed into the sides of work, as shown in fig. 848. A narrow gallery, termed the air-head, is carried in the upper part of the coal, in the rib walls, along one or more of the sides. In the example here figured, it is carried all round, and the air enters at the bolt-hole e. Lateral openings, named spouts, are led from the air-head gallery into the side of work; and the circulating stream mixed with the gas in the workings, enters by these spouts, as represented by the arrows, and returns by the air-head at g, to the upcast pit.
When the fire-damp comes off suddenly in any case, rendering the air foul and explosive at the foreheads, if no other remedy be found effectual, the working of the coal must be suspended, and a current of air sent directly from the fresh in-going stream, in order to dilute the explosive mixture, before it reaches the furnace. This is termed skailing the air; for otherwise the gas would kindle at the furnace, and flame backwards, like a train of gunpowder, through all the windings of the work, carrying devastation and death in its track. By skailing the air, however, time is given for running forward with water, and drowning the furnace. A cascade of water from the steam engine pumps is then allowed to fall down the pit, the power of which through a fall of 500 or 600 feet, is so great in carrying down a body of air, that it impels a sufficient current through every part of the workings. The ventilation is afterwards put into its usual train at leisure.
In collieries which have been worked for a considerable time, and particularly in such as have goaves, creeps, or crushed wastes, the disengagement of the fire-damp from these recesses is much influenced by the state of atmospheric pressure. Should this be suddenly diminished, as shown by the fall of the barometer, the fire-damp suddenly expands and comes forth from its retirement, polluting the galleries of the mine with its noxious presence. But an increase of barometric pressure condenses the gases of the mine, and restrains them within their sequestered limits. It is therefore requisite that the coal-viewer should consult the barometer before inspecting the subterraneous workings of an old mine, on the Monday mornings, in order to know what precautions must be observed in his personal survey.
The catastrophe of an explosion in an extensive coal-mine is horrible in the extreme. Let us imagine a mine upwards of 100 fathoms deep, with the workings extended to a great distance under the surrounding country, with machinery complete in all its parts, the mining operations under regular discipline, and railways conducted through all its ramifications; the stoppings, passing doors, brattices, and the entire economy of the mine, so arranged that every thing moves like a well regulated machine. A mine of this magnitude at full work is a scene of cheering animation, and happy industry; the sound of the hammer resounds in every quarter, and the numerous carriages, loaded or empty, passing swiftly to and fro from the wall faces to the pit bottom, enliven the gloomiest recesses. At each door a little boy, called a trapper, is stationed, to open, and shut it. Every person is at his post, displaying an alacrity and happiness pleasingly contrasted with the surrounding gloom. While things are in this merry train, it has but too frequently happened that from some unforeseen cause, the ventilation has partially stagnated, allowing a quantity of the fire-damp to accumulate in one space to the explosive pitch; or a blower has suddenly sprung forth, and the unsuspecting miner entering this fatal region with his candle, sets the whole in a blaze of burning air, which immediately suffocates and scorches to death every living creature within its sphere, while multitudes beyond the reach of the flame are dashed to pieces by the force of the explosion, rolling like thunder along the winding galleries. Sometimes the explosive flame seems to linger in one district for a few moments; then gathering strength for a giant effort, it rushes forth from its cell with the violence of a hurricane, and the speed of lightning, destroying every obstacle in its way to the upcast shaft. Its power seems to be irresistible. The stoppings are burst through, the doors are shivered into a thousand pieces; while the unfortunate miners, men, women, and boys, are swept along with an inconceivable velocity, in one body, with the horses, carriages, corves, and coals. Should a massive pillar obstruct the direct course of the aerial torrent, all these objects are dashed against it, and there prostrated or heaped up in a mass of common ruin, mutilation, and death. Others are carried directly to the shaft, and are either buried there amid the wreck, or are blown up and ejected from the pit mouth. Even at this distance from the explosive den, the blast is often so powerful, that it frequently tears the brattice walls of the shaft to pieces, and blows the corves suspended in the shaft as high up into the open air as the ropes will permit. Not unfrequently, indeed, the ponderous pulley-wheels are blown from the pit-head frame, and carried to a considerable distance in the bosom of a thick cloud of coals and coal-dust brought up from the mine by the fire-damp, whose explosion shakes absolutely the superincumbent solid earth itself with a mimic earthquake. The dust of the ruins is sometimes thrown to such a height above the pit as to obscure the light of the sun. The silence which succeeds to this awful turmoil is no less formidable; for the atmospheric back-draught, rushing down the shaft, denotes the consumption of vital air in the mine, and the production of the deleterious choke-damp and azote.
Though many of the miners may have escaped by their distance in the workings from the destructive blast and the fire, yet their fate may perhaps be more deplorable. They hear the explosion, and are well aware of its certain consequences. Every one anxious to secure his personal safety, strains every faculty to reach the pit-bottom. As the lights are usually extinguished by the explosion, they have to grope their way in utter darkness. Some have made most marvellous escapes, after clambering over the rubbish of fallen roofs, under which their companions are entombed; but others wandering into uncertain alleys, tremble lest they should encounter the pestilential airs. At last they feel their power, and aware that their fate is sealed, they cease to struggle with their inevitable doom; they deliberately assume the posture of repose, and fall asleep in death. Such has been too often the fate of the hardy and intelligent miners who immure themselves deep beneath the ground, and venture their lives for the comfort of their fellow-men; and such frequently is the ruinous issue of the best ordered and most prosperous mining concerns.
In such circumstances the mining engineers or coal viewers have a dangerous and difficult duty to perform. The pit into which they must descend as soon as possible, is rendered unsafe by many causes; by the wrecks of loose timber torn away by the eruption, or by the unrespirable gases; by the ignition perhaps of a portion of the coal itself, or by the flame of a blower of fire-damp; either of which would produce violent and repeated explosions whenever the gas may again accumulate to the proper degree. Such a predicament is not uncommon, and it is one against which no human skill can guard. Yet even here, the sense of duty, and the hope of saving some workmen from a lingering death by wounds or suffocation, lead this intrepid class of men to descend amid the very demons of the mine.
As soon as the ventilation is restored by temporary brattices, the stoppings and doors are rebuilt in a substantial manner, and the workings are resumed with the wonted activity. From an inspection of fig. 864., p. 1029, it is obvious that the stability of the main stopping p, is an important point; for which reason it is counterforted by strong walls of stone, to resist the explosive force of fire-damp.
When it is known that fire exists in the wastes, either by the burning of the small coal-dust along the roads, or from the ignition of the solid coal by a blower of gas, the inspection of the mine is incomparably more hazardous, as safety cannot be insured for an instant; for if the extrication of gas be great, it rapidly accumulates, and whenever it reaches the place where the fire exists, a new explosion takes place. There have been examples of the most furious detonations occurring regularly after the interval of about an hour, and being thus repeated 36 times in less than two days, each eruption appearing at the pit mouth like the blast of a volcano. It would be madness for any one to attempt a descent in such circumstances. The only resource is to moat up the pit, and check the combustion by exclusion of atmospheric air, or to drown the workings by letting the water accumulate below ground.
When fire exists in the wastes, with less apparent risk of life, water is driven upon it by portable fire-extinguishing engines, or small cannon are discharged near the burning coal, and the concussion thus produced in the air sometimes helps to extinguish the flame.
Since the primary cause of these tremendous catastrophes is the accension of the explosive gases by the candle of the miner, it has been long a desideratum to procure light of such a nature as may not possess the power of kindling the fire-damp. The train of light producible from the friction of flint and steel, by a mechanism called a steel mill, has been long known, and afforded a tolerable gleam, with which the miners were obliged to content themselves in hazardous atmospheres.
It consists of a small frame of iron, mounted with a wheel and pinion, which give rapid rotation to a disk of hard steel placed upright, to whose edge a piece of flint is applied. The use of this machine entailed on the miner the expense of an attendant, called the miller, who gave him light. Nor was the light altogether safe, for occasionally the ignited shower of steel particles attained to a sufficient heat to set fire to the fire-damp.
At length the attention of the scientific world was powerfully attracted to the means of lighting the miner with safety, by an awful catastrophe which happened at Felling Colliery, near Newcastle, on the 25th May, 1812. This mine was working with great vigour, under a well-regulated system of ventilation, set in action by a furnace and air-tube, placed over a rise pit in elevated ground. The depth of winning was above 100 fathoms; 25 acres of coal had been excavated, and one pit was yielding at the rate of 1700 tons per week. At 11 o’clock in the forenoon the night shift of miners was relieved by the day shift; 121 persons were in the mine, at their several stations, when, at half-past 11, the gas fired, with a most awful explosion, which alarmed all the neighbouring villages. The subterraneous fire broke forth with two heavy discharges from the dip-pit, and these were instantly followed by one from the rise-pit. A slight trembling, as from an earthquake, was felt for about half a mile round the colliery, and the noise of the explosion, though dull, was heard at from 3 to 4 miles’ distance. Immense quantities of dust and small coal accompanied these blasts, and rose high into the air, in the form of an inverted cone. The heaviest part of the ejected matter, such as corves, wood, and small coal, fell near the pits; but the dust borne away by a strong west wind fell in a continuous shower a mile and a half from the pit. In the adjoining village of Heworth it caused a darkness like that of early twilight, covering the roads where it fell so thickly that the footsteps of passengers were imprinted in it. The heads of both shaft-frames were blown off, their sides set on fire, and their pulleys shattered to pieces. The coal-dust ejected from the rise-pit into the horizontal part of the ventilating tube, was about 3 inches thick, and speedily burnt to a cinder; pieces of burning coal, driven off the solid stratum of the mine, were also blown out of this shaft. Of the 121 persons in the mine at the time of the explosion, only 32 were drawn up the pit alive, 3 of whom died a few hours after the accident. Thus no less than 92 valuable lives were instantaneously destroyed by this pestilential fire-damp. The scene of distress among the relatives at the pit mouth was indescribably sorrowful.
Dr. W. Reid Clanny, of Sunderland, was the first to contrive a lamp which might burn among explosive air without communicating flame to the gas in which it was plunged. This he effected, in 1813, by means of an air-tight lamp, with a glass front, the flame of which was supported by blowing fresh air from a small pair of bellows through a stratum of water in the bottom of the lamp, while the heated air passed out through water by a recurved tube at top. By this means the air within the lamp was completely insulated from the surrounding atmosphere. This lamp was the first ever taken into a body of inflammable air in a coal-mine, at the exploding point, without setting fire to the gas around it. Dr. Clanny made another lamp upon an improved plan, by introducing into it the steam of water generated in a small vessel at the top of the lamp, heated by the flame. The chief objection to these lamps is their inconvenience in use.
Various other schemes of safe-lamps were offered to the miner by ingenious mechanicians, but they have been all superseded by the admirable invention of Sir H. Davy, founded on his fine researches upon flame. The lamp of Davy was instantly tried and approved of by Mr. Buddle and the principal mining engineers of the Newcastle district. A perfect security of accident is therefore afforded to the miner in the use of a lamp which transmits its light, and is fed with air, through a cylinder of wire gauze; and this invention has the advantage of requiring no machinery, no philosophical knowledge to direct its use, and is made at a very cheap rate.
In the course of a long and laborious investigation on the properties of the fire-damp, and the nature and communication of flame, Sir H. Davy ascertained that the explosions of inflammable gases were incapable of being passed through long narrow metallic tubes; and that this principle of security was still obtained by diminishing their length and diameter at the same time, and likewise diminishing their length, and increasing their number, so that a great number of small apertures would not pass an explosion, when their depth was equal to their diameter. This fact led him to trials upon sieves made of wire-gauze, or metallic plates perforated with numerous small holes; and he found it was impossible to pass explosions through them.
The apertures in the gauze should never be more than 1-20th of an inch square. In the working models sent by Sir H. to the mines, there were 748 apertures in the square inch, and the wire was about the 40th of an inch diameter. The cage or cylinder of wire gauze should be made by double joinings, the gauze being folded over in such a manner as to leave no apertures. It should not be more than two inches in diameter; or in large cylinders the combustion of the fire-damp renders the top inconveniently hot; and a double top is always a proper precaution, fixed at a distance of about half an inch above the first top. The gauze cylinder should be fastened to the lamp by a screw of 4 or 5 turns. All joinings in the lamp should be made with hard solder; and the security depends upon the condition, that no aperture exists in the apparatus larger than in the wire gauze.
The forms of the lamp and cage, and the mode of burning the wick, may be greatly diversified; but the principle which ensures their safety must be strictly attended to. See Lamp of Davy, Safety Lamp, and Ventilation.
The state of the air in coal mines, from very early periods till the discovery of the safe-lamp, was judged of by the appearances exhibited by the flame of a candle; and this test must in many circumstances be still had recourse to. When there is merely a defect of atmospheric oxygen, the air being also partially vitiated by a little carbonic acid, either from choke-damp or the lungs and candles of the miners, the lights burn with a very dull flame, the tallow ceases to melt in the cup formed round the wick, till the flame flickers and expires. In this case the candle may be kept burning by slanting it more or less towards a horizontal position, which causes the tallow to melt with the edge of the flame. The candle is thus rapidly wasted, however; and therefore an oil lamp is preferable, as it continues to burn where a candle would be extinguished. The candles of the collier are generally small, with a very small wick; such being found to produce a more distinct flame than candles of a large size with a thick wick.
In trying the quality of the air by the flame of a candle, the wick must be trimmed by taking off the snuff, so as to produce a clear, distinct, and steady-burning flame. When a candle thus trimmed is looked at in common air, a distinct and well-defined cone of flame is seen, of a fine sky-blue at the bottom next the wick, and thence of a bright yellow to the apex of the cone. Besides this appearance, there is another, surrounding the cone, which the brightness of the flame prevents the eye from discerning. This may be seen by placing one of the hands expanded as a screen betwixt the eyes and the candle, and at the distance of about an inch, so that the least point of the apex of the yellow flame may be seen, and no more. By this method, a top, as the miners term it, will be distinctly observed close to the apex of the yellow flame, from an eighth to a quarter of an inch in length. This top is of a yellowish-brown colour, and like a misty haze. This haze is seen not only on the top, but it extends downwards and surrounds the flame fully half way, about a twentieth of an inch in thickness; here it assumes a violet colour, which passes into a beautiful blue at the bottom next the wick. The test of the state of the air in mines, or “trying the candle,” as practised by miners, depends entirely on the appearance which this haze assumes in shape and colour at the top of the flame. In fact, this top has distinct appearances when burning in atmospheric air, carbonated air, azotized air, or fire-damp air; displaying many modifications, according to the proportions of the various admixtures.
When azote or carbonic acid abounds, the top is frequently an inch or two in length, of a decided brown colour, and the flame is short and dim. When they are still more copious, the flame goes out, and the miners immediately retire.
When inflammable air is imagined to exist in considerable quantity, the miner trims his candle, and advances with cautious step, holding the candle with the left hand, and screening the flame with the right; and as the fire-damp floats in the upper part of the gallery next the roof, he holds the candle as low as he can, and keeping his eye fixed on the tip, he moves forwards. If the gas be small in quantity, he may reach the forehead without observing any material change in his light. But if in his advance he perceives the tip to elongate, and take a bluish-gray colour, he is put on his guard, and steps on with much caution; and if the tip begins to spire, he drops down on one knee, and holding the candle near the pavement, gradually raises it up, and watches the change it undergoes as it approaches the roof. If the gas be copious, the flame elongates into a sharp spire, as well as the top. It is in general reckoned dangerous when the tip changes from the bluish-gray to a fine blue colour, accompanied with minute luminous points, which pass rapidly upwards through the flame and top. When the symptoms are manifestly dangerous, a sudden movement of the hands or body is liable to produce ignition by agitation of the fire-damp. The experienced miner therefore slowly and cautiously lowers his candle to the pavement, and then turning round, effects his retreat slowly, or slips up his right hand and extinguishes the flame with his finger and thumb. Should he venture too far, and approach the body of gas in an explosive condition, the tip of the candle rapidly elongates, and the whole rises in a sharp spire several inches in length; and then the whole surrounding atmosphere is in a blaze, an explosion ensues, and destructive ravage is the consequence, to an extent proportioned to the quantity of fire-damp. See Safety Lamp, and Ventilation.
This trying the candle is a delicate operation, requiring much practical sagacity, where the lives of so many men, and the welfare of the whole establishment, are at stake. Almost every colliery, after having been worked for some time, gives a peculiar top to the candle; so that while in one mine liable to fire-damp an explosion will take place with a top less than an inch long, in another mine the top may be two inches high, and yet the air be considerably under the point of accension. These differences depend on several particulars. If the gas has not passed through a long course of ventilation, and is little mixed with air, it will ignite with a very short top; while on the other hand, a gas which has run through a ventilation of 20 or 30 miles may cause the production of a long top without hazard. It is hence obvious, that skilful experience, and thorough practical knowledge, are the only sure guides in these cases.
We shall now describe briefly the modern modes of working coals a-dipping of, and deeper than, the engine-pit bottom. One of these consists in laying a working pump barrel with a long wind-bore at the bottom of the downset mine, furnished with a smooth rod working through a collar at the top of the working barrel. At one side of this, near the top, a kneed pipe is attached, and from it pipes are carried to the point of delivery, either at the engine-pit bottom or day level, as represented in fig. 866. The spears are worked sometimes by rods connected with the machinery at the surface; in which case the spears, if very long, are either suspended from swing or pendulum rods, or move on friction rollers. But since the action of the spears, running with great velocity the total length of the engine stroke, very soon tears every thing to pieces, the motion of the spears underground has been reduced from 6 or 8 feet, the length of the engine stroke, to about 15 inches; and the due speed in the pump is effected by the centering of a beam, and the attachment of the spears to it, as represented in fig. 867., where a is the working barrel, b the beam centered at c, having an arc-head and martingale sinking-chain. The spears d are fastened by a strong bolt, which passes through the beam; and there are several holes, by means of which the stroke in the pumps can be lengthened or shortened at convenience. The movement of the spears is regulated by a strong iron quadrant or wheel at the bottom.
In level-free coals, these pumps may be worked by a water-wheel, stationed near the bottom of the pit, impelled by water falling down the shaft, to be discharged by the level to the day (day-level).
But the preferable plan of working under-dip coal, is that recently adopted by the Newcastle engineers; and consists in running a mine a-dipping of the engine-pit, in such direction of the dip as is most convenient; and both coals and water are brought up the rise of the coal by means of high-pressure engines, working with a power of from 30 to 50 pounds on the square inch. These machines are quite under command, and, producing much power in little space, they are the most applicable for underground work. An excavation is made for them in the strata above the coal, and the air used for the furnace under the boiler, is the returned air of the mine ventilation. In the dip-mine a double tram-road is laid; so that while a number of loaded corves are ascending, an equal number of empty ones are going down. Although this improved method has been introduced only a few years back, under-dip workings have been already executed more than an English mile under-dip of the engine-pit bottom, by means of three of these high-pressure engines, placed at equal distances in the under-dip mine. It may hence be inferred, that this mode of working is susceptible of most extensive application; and in place of sinking pits of excessive depth upon the dip of the coal, at an almost ruinous expense, much of the under-dip coal will in future be worked by means of the actual engine-pits. In the Newcastle district, coals are now working in an engine-pit 115 fathoms deep under-dip of the engine-pit bottom, above 1600 yards, and fully 80 fathoms of perpendicular depth more than the bottom of the pit.
If an engine-pit be sunk to a given coal at a certain depth, all the other coals of the coal-field, both above and below the coal sunk to, can be drained and worked to the same depth, by driving a level cross-cut mine, both to the dip and rise, till all the coals are intersected, as represented in fig. 868., where A is the engine-pit bottom reaching to the coal a; and b, c, d, e, f, coals lying above the coal a; the coals which lie below it, g, h, i; k is the forehead of the cross-cut mine, intersecting all the lower coals; and l, the other forehead of the mine, intersecting all the upper coals.
In the “Report from the select committee of the House of Lords, appointed to take into consideration the state of the coal trade in the United Kingdom,” printed in June, 1829, under the head of Mr. Buddle’s evidence we have an excellent description of the nature and progress of creeps, which we have adverted to in the preceding account. The annexed fig. 869. exhibits the creep in all its progressive stages, from its commencement until it has completely closed all the workings, and crushed the pillars of coal. The section of the figures supposes us standing on the level of the different galleries which are opened in the seam. The black is the coal pillars between each gallery; when these are weakened too much, or, in other words, when their bases become too narrow for the pavement below, by the pressure of the incumbent stratification they sink down into the pavement, and the first appearance is a little curvature in the bottom of each gallery: that is the first symptom obvious to sight; but it may generally be heard before it is seen. The next stage is when the pavement begins to open with a crack longitudinally. The next stage is when that crack is completed, and it assumes the shape of a metal ridge. The next is when the metal ridge reaches the roof. The next stage is when the peak of the metal ridge becomes flattened by pressure, and forced into a horizontal direction, and becomes quite close; just at this moment the coal pillars begin to sustain part of the pressure. The next is when the coal pillars take part of the pressure. The last stage is when it is dead and settled; that is, when the metal or factitious ridge, formed by the sinking of the pillar into the pavement, bears, in common with the pillars of coal on each side, the full pressure, and the coal becomes crushed or cracked, and can be no longer worked, except by a very expensive and dangerous process. Fig. 869.
The quantity of coals, cinders, and culm shipped coastways, and exported from the several ports of the United Kingdom in the year 1837, was 8,204,301 tons; in 1836, the quantity was 7,389,272 tons, being an increase of 815,029 tons, or 11·03 per cent. in favour of 1837.
The following Table shows the separate proportions of this quantity supplied by England and Wales, Scotland, and Ireland:—
1836. 1837. Increase.
Tons. Tons. Tons.
England and Wales 6,757,937 7,570,254 812,317 or 12·02 per cent.
Scotland 624,308 626,532 2,204 0·36
Ireland 7,027 7,515 488 6·94
Total 7,389,272 8,204,301 815,029 or 11·03 per cent.
PITCOAL, COKING OF. See also Charcoal.
Fig. 870. represents a schachtofen, or pit-kiln, for coking coals in Germany. a is the lining (chemise), made of fire-bricks; the enclosing walls are built of the same material; b, b, is a cast-iron ring covered with a cast-iron plate c. The floor of the kiln is massive. The coals are introduced, and the coke taken out, through a hole in the side d; during the process it is bricked up, and closed with an iron door. In the surrounding walls are 4 horizontal rows of flues e, e, e, e, which are usually iron pipes; the lowest row is upon a level with the floor of the kiln; and the others are each respectively one foot and a half higher than the preceding. Near the top of the shaft there is an iron pipe f, of from 8 to 10 inches in diameter, which allows the incoercible vapours generated in the coking to escape into the condenser, which consists either of wood or brick chambers. For kindling the coal, a layer of wood is first placed on the bottom of the kiln.
The coking of small coal is performed upon vaulted hearths, somewhat like bakers’ ovens, but with still flatter roofs. Of such kilns, several are placed alongside one another each being an ellipse deviating little from a circle, so that the mouth may project but a small space. The dimensions are such, that from 10 to 12 cubic feet of coal-culm may be spread in a layer 6 inches deep upon the sole of the furnace. The top of the flat arch of fire brick should be covered with a stratum of loam and sand.
Figs. 871. and 872. represent such a kiln as is mounted at Zabrze, in Upper Silesia, for coking small coal. Fig. 871. is the ground plan; fig. 872. the vertical section in the line of the long axis of fig. 871. a, is the sand-bed of the hearth, under the brick sole; b, is the roof of large fire-bricks; c, the covering of loam; d, the top surface of sand; e, the orifice in the front wall, for admission of the culm, and removal of the coke, over the sloping stone f. The flame and vapours pass off above this orifice, through the chimney marked g, or through the aperture h, into a lateral chimney. i, is a bar of iron laid across the front of the door as a fulcrum to work the iron rake upon. A layer of coals is first kindled upon the hearth, and when this is in brisk ignition, it is covered with the culm in successive sprinklings. When the coal is sufficiently coked, it is raked out, and quenched with water.
Fig. 873. represents a simple coking meiler or mound, constructed in a circular form round a central chimney of loose bricks, towards which small horizontal flues are laid among the lumps of coals. The sides and top are covered with culm or slack, and the heap is kindled from certain openings towards the circumference. Fig. 874. represents an oblong meiler, sometimes made 100 or 150 feet in length, and from 10 to 12 in breadth. The section in the middle of the figure shows how the lumps are piled up; the wooden stakes are lifted out when the heap is finished, in order to introduce kindlings at various points; and the rest of the meiler is then covered with slack and clay, to protect it from the rains. A jet of smoke and flame is seen issuing from its left end.
An excellent range of furnaces for making a superior article of coke, for the service of the locomotive engines of the London and Birmingham Railway Company, has been recently erected at the Camden Town station; consisting of 18 ovens in two lines, the whole discharging their products of combustion into a horizontal flue, which terminates in a chimney-stalk, 115 feet high. Fig. 875. is a ground plan of the elliptical ovens, each being 12 feet by 11 internally, and having 3 feet thickness of walls. a, a, is the mouth, 3⁄2 feet wide outside, and about 2⁄4 feet within. b, b, are the entrances into the flue; they may be shut more or less completely by horizontal slabs of fire-brick, resting on iron frames, pushed in from behind, to modify the draught of air. The grooves of these damper-slabs admit a small stream of air to complete the combustion of the volatilized particles of soot. By this means the smoke is well consumed. The flue c, c, is 2⁄2 feet high, by 21 inches wide. The chimney d, at the level of the flue, is 11 feet in diameter inside, and 17 outside; being built from an elegant design of Robert Stephenson, Esq. (See Chimney.) d, d, are the keys of the iron hoops, which bind the brickwork of the oven. Fig. 876. is a vertical section in the line A, B, of fig. 875. showing, at b, b, and e, e, the entrances of the different ovens into the horizontal flue; the direction of the draught being indicated by the arrows. f, f, is a bed of concrete, upon which the whole furnace-range is built, the level of the ground being in the middle of that bed. g, is a stauncheon on which the crane is mounted: (see fig. 877.) h is a section of the chimney wall, with part of the interior to the left of the strong line. Fig. 877. is a front elevation of two of these elegant coke-ovens; in which the bracing hoops i, i, i, are shown; k, k, are the cast-iron doors, strengthened outside with diagonal ridges; each door being 5⁄2 feet high, by 4 feet wide, and lined internally with fire-bricks. They are raised and lowered by means of chains and counterweights, moved by the crane l.
Each alternate oven is charged, between 8 and 10 o’clock every morning, with 3⁄2 tons of good coals. A wisp of straw is thrown in on the top of the heap, which takes fire by the radiation from the dome (which is in a state of dull ignition from the preceding operation), and inflames the smoke then rising from the surface, by the re-action of the hot sides and bottom upon the body of the fuel. In this way the smoke is consumed at the very commencement of the process, when it would otherwise be most abundant. A neighbour of the above coking ovens, having lately indicted them as a nuisance, procured, secundum artem, a parcel of affidavits from sundry chemical and medical men. Two of the former, who had not entered the premises, but had espied the outside of the furnaces’ range at some distance, declared that “the coking process, as performed at the ovens, is a species of distillation of coal”! How rashly do unpractical theorists affirm what is utterly unfounded, and mislead an unscientific judge! That the said coking process is in no respect a species of distillation, but a complete combustion of the volatile principles of the coal, will be manifest from the following description of its actual progress. The mass of coals is first kindled at the surface, as above stated, where it is supplied with abundance of atmospheric oxygen; because the doors of the ovens in front, and the throat-vents behind, are then left open. The consequence is, that no more smoke is discharged from the top of the chimney, at this the most sooty period of the process, than is produced by an ordinary kitchen fire. In these circumstances, the coal gas, or other gas, supposed to be generated in the slightly heated mass beneath, cannot escape destruction in passing up through the bright open flame of the oven. As the coking of the coal advances most slowly and regularly from the top of the heap to the bottom, only one layer is affected at a time, and in succession downwards, while the surface is always covered with a stratum of redhot cinders, ready to consume every particle of carburetted or sulphuretted hydrogen gases which may escape from below. The greatest mass, when calcined in this downward order, cannot emit into the atmosphere any more of the above-mentioned gases than the smallest heap; and therefore the argument raised on account of the magnitude of the operations, is altogether fallacious.
The coke being perfectly freed from all fuliginous and volatile matters by a calcination of upwards of 40 hours, is cooled down to moderate ignition by sliding in the dampers, and sliding up the doors, which had been partially closed during the latter part of the process. It is now observed to form prismatic concretions, somewhat like a columnar mass of basalt. These are loosened by iron bars, lifted out upon shovels furnished with long iron shanks, which are poised upon swing chains with hooked ends, and the lumps are thrown upon the pavement, to be extinguished by sprinkling water upon them from the rose of a watering-can; or, they might be transferred into a large chest of sheet-iron set on wheels, and then covered up. Good coals thus treated, yield 80 per cent. of an excellent compact glistening coke; weighing about 14 cwt. per chaldron.
The loss of weight in coking in the ordinary ovens is usually reckoned at 25 per cent.; and coal, which thus loses one-fourth in weight, gains one-fourth in bulk.
Labourers who have been long employed at rightly-constructed coke ovens, seem to enjoy remarkably good health.
PITTACALL, is one of the 6 curious principles detected in wood-tar by Reichenbach. It is a dark-blue solid substance, somewhat like indigo, assumes a metallic fiery lustre on friction, and varies in tint from copper to golden. It is void of taste and smell, not volatile; carbonizes at a high heat without emitting an ammoniacal smell; is soluble or rather very diffusible in water; gives a green solution with a cast of crimson, in sulphuric acid, with a cast of red blue, in muriatic acid, and with a cast of aurora red, in acetic acid. It is insoluble in alkalis. It dyes a fast blue upon linen and cotton goods, with tin and aluminous mordants.
PLASTER; see Mortar.
PLASTER OF PARIS; see Gypsum.
PLATED MANUFACTURE. (Fabrique de plaqué, Fr.; Silber plattirung, Germ.) The silver in this case is not applied to ingots of pure copper, but to an alloy consisting of copper and brass, which possesses the requisite stiffness for the various articles.
The furnace used for melting that alloy, in blacklead crucibles, is a common air-furnace, like that for making brass.
The ingot-moulds are made of cast iron, in two pieces, fastened together; the cavity being of a rectangular shape, 3 inches broad, 1⁄2 thick, and 18 or 20 long. There is an elevated mouth-piece or gate, to give pressure to the liquid metal, and secure solidity to the ingot. The mould is heated, till the grease with which its cavity is besmeared, merely begins to smoke, but does not burn. The proper heat of the melted metal for casting, is when it assumes a bluish colour, and is quite liquid. Whenever the metal has solidified in the mould, the wedges that tighten its rings are driven out, lest the shrinkage of the ingot should cause the mould to crack. See Brass.
The ingot is now dressed carefully with the file on one or two faces, according as it is to be single or double plated. The thickness of the silver plate is such as to constitute one fortieth of the thickness of the ingot; or when this is an inch and a quarter thick, the silver plate applied is one thirty-second of an inch, being by weight a pound troy of the former, to form 8 to 10 pennyweights of the latter. The silver, which is slightly less in size than the copper, is tied to it truly with iron wire, and a little of a saturated solution of borax is then insinuated at the edges. This salt melts at a low heat, and excludes the atmosphere, which might oxidize the copper, and obstruct the union of the metals. The ingot thus prepared is brought to the plating furnace.
The furnace has an iron door with a small hole to look through; it is fed with cokes, laid upon a grate at a level with the bottom of the door. The ingot is placed immediately upon the cokes, the door is shut, and the plater watches at the peep-hole the instant when the proper soldering temperature is attained. During the union of the silver and copper, the surface of the former is seen to be drawn into intimate contact with the latter, and this species of riveting is the signal for removing the compound bar instantly from the furnace. Were it to remain a very little longer, the silver would become alloyed with the copper, and the plating be thus completely spoiled. The adhesion is, in fact, accomplished here by the formation of a film of true silver-solder at the surfaces of contact.
The ingot is next cleaned, and rolled to the proper thinness between cylinders as described under Mint; being in its progress of lamination frequently annealed on a small reverberatory hearth. After the last annealing, the sheets are immersed in hot dilute sulphuric acid, and scoured with fine Calais sand; they are then ready to be fashioned into various articles.
In plating copper wire, the silver is first formed into a tubular shape, with one edge projecting slightly over the other; through which a redhot copper cylinder being somewhat loosely run, the silver edges are closely pressed together with a steel burnisher, whereby they get firmly united. The tube thus completed, is cleaned inside, and put on the proper copper rod, which it exactly fits. The copper is left a little longer than its coating tube, and is grooved at the extremities of the latter, so that the silver edges, being worked into the copper groove, may exclude the air from the surface of the rod. The compound cylinder is now heated redhot, and rubbed briskly over with the steel burnisher in a longitudinal direction, whereby the two metals get firmly united, and form a solid rod, ready to be drawn into wire of any requisite fineness and form; as flat, half-round, fluted, or with mouldings, according to the figure of the hole in the draw-plate. Such wire is much used for making bread-baskets, toast-racks, snuffers, and articles combining elegance with lightness and economy. The wire must be annealed from time to time during the drawing, and finally cleaned, like the plates, with dilute acid.
Formerly the different shaped vessels of plated metal were all fashioned by the hammer; but every one of simple form is now made in dies struck with a drop-hammer or stamp. Some manufacturers employ 8 or 10 drop machines.
Fig. 878. and 879. are two views of the stamp. A is a large stone, the more massy the better; b, the anvil on which the die e is secured by four screws, as shown in the ground plan, fig. 880. In fig. 878., a a are two upright square prisms, set diagonally with the angles opposed to each other; between which the hammer or drop d slides truly, by means of nicely fitted angular grooves or recesses in its sides. The hammer is raised by pulling the rope f, which passes over the pulley c, and is let fall from different heights, according to the impulse required. Vessels which are less in diameter at the top and bottom than in the middle, must either be raised by the stamp in two pieces, or raised with a hand hammer. The die is usually made of cast steel. When it is placed upon the anvil, and the plated metal is cut into pieces of proper size, the top of the die is then surrounded with a lute made of oil and clay, for an inch or two above its surface; and the cavity is filled with melted lead. The under face of the stamp-hammer has a plate of iron called the licker-up fitted into it, about the area of the die. Whenever the lead has become solid, the hammer is raised to a certain height, and dropped down upon it; and as the under face of the licker-up is made rough like a rasp, it firmly adheres to the lead, so as to lift it afterwards with the hammer. The plated metal is now placed over the die, and the hammer mounted with its lead is let fall repeatedly upon it, till the impression on the metal is complete. If the vessel to be struck, be of any considerable depth, two or three dies may be used, of progressive sizes in succession. But it occasionally happens that when the vessel has a long conical neck, recourse must be had to an auxiliary operation, called punching. See the embossing punches, fig. 881. These are made of cast steel, with their hollows turned out in the lathe. The pieces a, b are of lead. The punching is performed by a series of these tools, of different sizes, beginning with the largest, and ending with the least. By this means a hollow cone, 3 or 4 inches deep, and an inch diameter, may be raised out of a flat plate. These punches are struck with a hand hammer also, for small articles, of too great delicacy for the drop. Indeed it frequently happens that one part of an article is executed by the stamp, and another by the hand.
Cylindrical and conical vessels are mostly formed by bending and soldering. The bending is performed on blocks of wood, with wooden mallets; but the machine so much used by the tin-smiths, to form their tubes and cylindric vessels (see the end section, figs. 882. and 883.), might be employed with advantage. This consists of 3 iron rollers fixed in an iron frame. A, B, C, are the three cylinders, and a, b, c, d, the riband or sheet of metal passed through them to receive the cylindrical or conical curvature. The upper roller A can be raised or lowered at pleasure, in order to modify the diameter of the tube; and when one end of the roller is higher than the other, the conical curvature is given. The edges of the plated cylinders or cones are soldered with an alloy composed of silver and brass. An alloy of silver and copper is somewhat more fusible; but that of brass and silver answers best for plated metal, the brass being in very small proportion, lest the colour of the plate be affected. Calcined borax mixed with sandiver (the salt skimmed from the pots of crown glass) is used along with the alloy, in the act of soldering. The seam of the plated metal being smeared with that saline mixture made into a pap with water, and the bits of laminated solder, cut small with scissors, laid on, the seam is exposed to the flame of an oil blowpipe, or to that of charcoal urged by bellows in a little forge-hearth, till the solder melts and flows evenly along the junction. The use of the sandiver seems to be, to prevent the iron wire that binds the plated metal tube from being soldered to it.
Mouldings are sometimes formed upon the edges of vessels, which are not merely ornamental, but give strength and stiffness. These are fashioned by an instrument called a swage, represented in figs. 884. and 885. The part A lifts up by a joint, and the metal to be swaged is placed between the dies, as shown in the figures; the tail b being held in the jaws of a vice, while the shear-shaped hammer rests upon it. By striking on the head A, while the metal plate is shifted successively forwards, the beading is formed. In fig. 884. the tooth a is a guide to regulate the distance between the bead and the edge. A similar effect is produced of late years in a neater and more expeditious manner by the rollers, figs. 886. 887. Fig. 888. is a section to show the form of the bead. The two wheels a, a, fig. 886., are placed upon axes, two of which are furnished with toothed pinions in their middle; the lower one being turned by the handle, gives motion to the upper. The groove in the upper wheel corresponds with the bead in the lower, so that the slip of metal passed through between them assumes the same figure.
The greatest improvement made in this branch of manufacture, is the introduction of silver edges, beads and mouldings, instead of the plated ones, which from their prominence had their silver surface speedily worn off, and thus assumed a brassy look. The silver destined to form the ornamental edgings is laminated exceedingly thin; a square inch sometimes weighing no more than 10 or 12 grains. This is too fragile to bear the action of the opposite steel dies of the swage above described. It is necessary, therefore, that the sunk part of the die should be steel, and the opposite side lead, as was observed in the stamping; and this is the method now generally employed to form these silver ornaments. The inside shell of this silver moulding is filled with soft solder, and then bent into the requisite form.
The base of candlesticks is generally made in a die by the stamp, as well as the neck, the dish part of the nozzle or socket, and the tubular stem or pillar. The different parts are united, some with soft and others with hard solder. The branches of candlesticks are formed in two semi-cylindrical halves, like the feet of tea-urns. When an article is to be engraved on, an extra plate of silver is applied at the proper part, while the plate is still flat, and fixed by burnishing with great pressure over a hot anvil. This is a species of welding.
The last finish of plated goods is given by burnishing-tools of bloodstone, fixed in sheet-iron cases, or hardened steel, finely polished.
The ingots for lamination might probably be plated with advantage by the delicate pressure process employed for silvering copper wire.
The total value of the plate, plated ware, jewellery, and watches, exported in the year 1836, was 338,889l.; but the value of the plated goods is not given in the tables of revenue. M. Parquin, the greatest manufacturer of plated goods in Paris (or France, for this business is monopolized by the capital), who makes to the value of 700,000 francs per annum, out of the 1,500,000 which, he says, is the whole internal consumption of the kingdom, states that the internal consumption of the United Kingdom amounts 30,000,000, or 20 times, that of France! He adds, that our common laminated copper costs 26 sous the pound, while theirs costs 34. Their plated goods are fashioned, not in general with stamps, but by the pressure of tools upon wood moulds in the turning-lathe, which is a great economy of capital to the manufacturer. There are factories at Birmingham which possess a heavy stock of 300,000 different die-moulds. See Stamping of Metals.
PLATINA-MOHR. The following easy method of preparing igniferous black platinum, proposed thirty years ago by Descotils, has been recently recommended by M. Dobereiner:—
Melt platina ore with double its weight of zinc, reduce the alloy to powder, and treat it first with dilute sulphuric acid, and next with dilute nitric acid, to oxidize and dissolve out all the zinc, which, contrary to one’s expectations, is somewhat difficult to do, even at a boiling heat. The insoluble black-gray powder contains some osmiuret of iridium, united with the crude platinum. This compound acts like simple platina-black, after it has been purified by digestion in potash lye, and washing with water. Its oxidizing power is so great, as to transform not only the formic acid into the carbonic, and alcohol into vinegar, but even some osmic acid, from the metallic osmium. The above powder explodes by heat like gunpowder.
When the platina-mohr prepared by means of zinc is moistened with alcohol, it becomes incandescent, and emits osmic acid; but if it be mixed with alcohol into a paste, and spread upon a watch-glass, nothing but acetic acid will be disengaged; affording an elegant means of diffusing the odour of vinegar in an apartment.
PLATINUM, is a metal of a grayish-white colour, resembling in a good measure polished steel. It is harder than silver, and of about double its density, being of specific gravity 21. It is so infusible, that no considerable portion of it can be melted by the strongest heats of our furnaces. It is unchangeable in the air and water; nor does a white heat impair its polish. The only acid which dissolves it, is the nitro-muriatic; the muriate or chloride thus formed, affords, with pure ammonia or sal ammoniac, a triple salt in a yellow powder, convertible into the pure metal by a red heat. This character distinguishes platinum from every other metal.
Native Platinum.—In the natural state it is never pure, being alloyed with several other metals. It occurs only under the form of grains, which are usually flattened, and resemble in shape the gold pepitas. Their size is in general less than linseed, although in some cases they equal hempseed, and, occasionally, peas. One piece brought from Choco, in Peru, and presented to the Cabinet of Berlin, by M. Humboldt, weighs 55 grammes = 850 grains, or nearly 2 oz. avoirdupois. The greatest lump of native platinum known, till of late years, was one in the Royal Museum of Madrid, which was found in 1814 in the gold mine of Condoto, province of Novita, at Choco. Its size is greater than a Turkey’s egg, (about 2 inches one diameter, and 4 inches the other,) and its weight 760 grammes, = 24 oz. or fully 2 lbs. troy. See infrà.
The colour of the grains of native platinum is generally a grayish white, like tarnished steel. The cavities of the rough grains are often filled with earthy and ferruginous matters, or sometimes with small grains of black oxide of iron, adhering to the surface of the platinum grains. Their specific gravity is also much lower than that of forged pure platinum; varying from 15 in the small particles, to 18·94 in M. Humboldt’s large specimen. This relative lightness is owing to the presence of iron, copper, lead, and chrome; besides its other more lately discovered metallic constituents, palladium, osmium, rhodium, and iridium.
Its main localities in the New Continent, are in the three following districts:—
1. At Choco, in the neighbourhood of Barbacoas, and generally on the coasts of the South Sea, or on the western slopes of the Cordillera of the Andes, between the 2nd and the 6th degrees of north latitude. The gold-washings that furnish most platinum, are those of Condoto, in the province of Novita; those of Santa Rita, or Viroviro, of Santa Lucia, of the ravine of Iro, and Apoto, between Novita and Taddo. The deposit of gold and platinum grains is found in alluvial ground, at a depth of about 20 feet. The gold is separated from the platinum by picking with the hand, and also by amalgamation; formerly, when it was imagined that platinum might be used to debase gold, the grains of the former metal were thrown into the rivers, through which mistaken opinion an immense quantity of it was lost.
2. Platinum grains are found in Brazil, but always in the alluvial lands that contain gold, particularly in those of Matto-Grosso. The ore of this country is somewhat different from that of Choco. It is in grains, which seem to be fragments of a spongy substance. The whole of the particles are nearly globular, exhibiting a surface formed of small spheroidal protuberances strongly cohering together, whose interstices are clean, and even brilliant.
This platinum includes many small particles of gold, but none of the magnetic iron-sand or of the small zircons which accompany the Peruvian ore. It is mixed with small grains of native palladium, which may be recognised by their fibrous or radiated structure, and particularly by their chemical characters.
3. Platinum grains are found in Hayti, or Saint Domingo, in the sand of the river Jacky, near the mountains of Sibao. Like those of Choco, they are in small brilliant grains, as if polished by friction. The sand containing them is quartzose and ferruginous. This native platinum contains, like that of Choco, chromium, copper, osmium, iridium, rhodium, palladium, and probably titanium. Vauquelin could find no gold among the grains.
Platinum has been discovered lately in the Russian territories, in the auriferous sands of Kuschwa, 250 wersts from Ekaterinebourg, and consequently in a geological position which seems to be analogous with that of South America.
These auriferous sands are, indeed, almost all superficial; they cover an argillaceous soil; and include, along with gold and platinum, debris of dolerite (a kind of greenstone), protoxide of iron, grains of corundum, &c. The platinum grains are not so flat as those from Choco, but they are thicker; they have less brilliancy, and more of a leaden hue. This platinum, by M. Laugier’s analysis, is similar in purity to that of Choco; but the leaden-gray grains, which were taken for a mixture of osmium and iridium, are merely an alloy of platinum, containing 25 per cent. of these metals.
The mines of Brazil, Columbia, and Saint Domingo furnish altogether only about 400 kilos. of platinum ore per annum; but those of Russia produce above 1800 kilos. The latter were discovered in 1822, and were first worked in 1824. They are all situated in the Ural mountains. The ore is disseminated in an argillaceous sand, of a greenish-gray colour, resulting from the disintegration of the surrounding rocks, and constitutes from 1 to 3 parts in 4000 of the sand. Occasionally it has been found in lumps weighing 8 kilogrammes (16 lbs.!), but it generally occurs in blackish angular grains, which contain 70 per cent. of platinum, and 3 to 5 of iridium. The ore of Goroblagodat is in small flattened grains, which contain 88 per cent. of this precious metal. The osmiure of iridium is found upon a great many points of the Urals, throughout a space of 140 leagues, being a product accessory to the gold washings. 32 kilogrammes of osmiure are collected there annually, which contain upon an average 2 per cent. of platinum.
M. Vauquelin found nearly ten per cent. of platinum in an ore of argentiferous copper, which was transmitted to him as coming from Guadalcanal in Spain. This would be the only example of platinum existing in a rock, and in a vein. As the same thing has not again been met with, even in other specimens from Guadalcanal, we must delay drawing geological inferences, till a new example has confirmed the authenticity of the first.
Platinum has been known in Europe only since 1748, though it was noticed by Ulloa in 1741. It was compared at first to gold; and was, in fact, brought into the market under the name of white gold. The term platinum, however, is derived from the Spanish word plata, silver, on account of its resemblance in colour to that metal.
The whole of the platinum ore from the Urals is sent to St. Petersburg, where it is treated by the following simple process:—
One part of the ore is put in open platina vessels, capable of containing from 6 to 8 lbs., along with 3 parts of muriatic acid at 25° B. and 1 part of nitric acid at 40°. Thirty of these vessels are placed upon a sand-bath covered with a glazed dome with movable panes, which is surmounted by a ventilating chimney to carry the vapours out of the laboratory. Heat is applied for 8 or 10 hours, till no more red vapours appear; a proof that the whole nitric acid is decomposed, though some of the muriatic remains. After settling, the supernatant liquid is decanted off into large cylindrical glass vessels, the residuum is washed, and the washing is also decanted off. A fresh quantity of nitro-muriatic acid is now poured upon the residuum. This treatment is repeated till the whole solid matter has eventually disappeared. The ore requires for solution from 10 to 15 times its weight of nitro-muriatic acid, according to the size of its grains.
The solutions thus made are all acid; a circumstance essential to prevent the iridium from precipitating with the platinum, by the water of ammonia, which is next added. The deposit being allowed to form, the mother waters are poured off, the precipitate is washed with cold water, dried, and calcined in crucibles of platinum.
The mother-waters and the washings are afterwards treated separately. The first being concentrated to one-twelfth of their bulk in glass retorts, on cooling they let fall the iridium in the state of an ammoniacal chloride, constituting a dark-purple powder, occasionally crystallized in regular octahedrons. The washings are evaporated to dryness in porcelain vessels; the residuum is calcined and treated like fresh ore; but the platinum it affords needs a second purification.
For agglomerating the platinum, the spongy mass is pounded in bronze mortars; the powder is passed through a fine sieve, and put into a cylinder of the intended size of the ingot. The cylinder is fitted with a rammer, which is forced in by a coining press, till the powder be much condensed. It is then turned out of the mould, and baked 36 hours in a porcelain kiln, after which it may be readily forged, if it be pure, and may receive any desired form from the hammer. It contracts in volume from 1-6th to 1-5th during the calcination. The cost of the manufacture of platinum is fixed by the administration at 32 francs the Russian pound; but so great a sum is never expended upon it.
For Dr. Wollaston’s process, see Phil. Trans. 1829, Part I.
Platinum furnishes most valuable vessels to both analytical and manufacturing chemists. It may be beat out into leaves of such thinness as to be blown about with the breath.
This metal is applied to porcelain by two different processes; sometimes in a rather coarse powder, applied by the brush, like gold, to form ornamental figures; sometimes in a state of extreme division, obtained by decomposing its muriatic solution, by means of an essential oil, such as rosemary or lavender. In this case, it must be evenly spread over the whole ground. Both modes of application give rise to a steely lustre.
The properties possessed in common by gold and platinum, have several times given occasion to fraudulent admixtures, which have deceived the assayers. M. Vauquelin having executed a series of experiments to elucidate this subject, drew the following conclusions:—
If the platinum do not exceed 30 or 40 parts in the thousand of the alloy, the gold does not retain any of it when the parting is made with nitric acid in the usual way; and when the proportion of platinum is greater, the fraud becomes manifest, 1st by the higher temperature required to pass it through the cupel, and to form a round button, 2, by the absence of the lightning, fulguration, or coruscation; 3, by the dull white colour of the button and its crystallized surface; 4, by the straw-yellow colour which platinum communicates to the aquafortis in the parting; 5, by the straw-yellow colour, bordering on white, of the cornet, after it is annealed. If the platinum amounts to one fourth of the gold, we must add to the alloy at least 3 times its weight of fine silver, laminate it very thin, anneal somewhat strongly, boil it half an hour in the first aquafortis, and at least a quarter of an hour in the second, in order that the acid may dissolve the whole of the platinum.
Were it required to determine exactly the proportions of platinum contained in an alloy of copper, silver, gold, and platinum, the amount of the copper may be found in the first place by cupellation, then the respective quantities of the three other metals may be learned by a process founded, 1, upon the property possessed by sulphuric acid of dissolving silver without affecting gold or platinum; and, 2, upon the property of platinum being soluble in the nitric acid, when it is alloyed with a certain quantity of gold and silver.
According to Boussingault, the annual product of Platinum in America does not exceed 8⁄3 cwts. At Nischne-Tagilsk, in 1824, a lump of native platinum weighing fully 10 lbs. was found; and in 1830, another lump, of nearly double size, which weighed 35⁄4 Prussian marcs; fully 18 lbs. avoirdupoise.
PRODUCTION OF PLATINUM IN THE URAL.
From 1822 to 1827 inclusively, 52 puds and 22 ⁄2 pounds.
1828 94
1829 78 31 ⁄2
1830 105 1
1831 to 1833 348 15
Analyses of the Platinum Ores of the Urals, and of that from Barbacoas on the Pacific, between the 2nd and 6th degrees of northern latitude.
From Nischne-Tagilsk. Goroblagodat. Barbacoas.
Berzelius. Osann. Berzelius.
Magnetic. Not
Magnetic
Platinum 73·58 78·94 83·07 86·50 84·30
Iridium 2·35 4·97 1·91 — 1·46
Rhodium 1·15 0·86 0·59 1·15 3·46
Palladium 0·30 0·28 0·26 1·10 1·06
Iron 12·98 11·04 10·79 8·32 5·31
Copper 5·20 0·70 1·30 0·45 0·74
Undissolved Osmium and Iridium 2·30 1·96 1·80 1·40 —
Osmium — — — — 1·03
Quartz — — — — 0·60
Lime — — — — 0·12
97·86 98·75 99·72 98·92 98·08
PLUMBAGO. See Graphite, for its mineralogical and chemical characters. The mountain at Borrowdale, in which the blacklead is mined, is 2000 feet high, and the entrance to the mine is 1000 feet below its summit. This valuable mineral became so common a subject of robbery about a century ago, as to have enriched, it was said, a great many persons living in the neighbourhood. Even the guard stationed over it by the proprietors was of little avail against men infuriated with the love of plunder; since in those days a body of miners broke into the mine by main force, and held possession of it for a considerable time.
The treasure is now protected by a strong building, consisting of four rooms upon the ground floor; and immediately under one of them is the opening, secured by a trap-door, through which alone workmen can enter the interior of the mountain. In this apartment, called the dressing-room, the miners change their ordinary clothes for their working dress, as they come in, and after their six hours’ post or journey, they again change their dress, under the superintendence of the steward, before they are suffered to go out. In the innermost of the four rooms, two men are seated at a large table, sorting and dressing the plumbago, who are locked in while at work, and watched by the steward from an adjoining room, who is armed with two loaded blunderbusses. Such formidable apparatus of security is deemed requisite to check the pilfering spirit of the Cumberland mountaineers.
The cleansed blacklead is packed up into strong casks, which hold 1 cwt. each. These are all despatched to the warehouse of the proprietors in London, where the blacklead is sold monthly by auction, at a price of from 35s. to 45s. a pound.
In some years, the net produce of the six weeks’ annual working of the mine has, it is said, amounted to 30,000l. or 40,000l.
PLUSH (Panne, Peluche, Fr.; Wollsammet, Plüsch, Germ.), is a textile fabric, having a sort of velvet nap or shag upon one side. It is composed regularly of a woof of a single woollen thread, and a two-fold warp, the one, wool of two threads twisted, the other, goat’s or camel’s hair. There are also several sorts of plush made entirely of worsted. It is manufactured, like velvet, in a loom with three treadles; two of which separate and depress the woollen warp, and the third raises the hair-warp, whereupon the weaver, throwing the shuttle, passes the woof between the woollen and hair warp; afterwards, laying a brass broach or needle under that of the hair, he cuts it with a knife (see Fustian) destined for that use, running its fine slender point along in the hollow of the guide-broach, to the end of a piece extended upon a table. Thus the surface of the plush receives its velvety appearance. This stuff is also made of cotton and silk.
POINT NET, is a style of lace formerly much in vogue, but now superseded by the bobbin-net manufacture.
PORCELAIN, is the finest kind of pottery-ware. It is considered under that title.
PORPHYRY, is a compound mineral or rock, composed essentially of a base of hornstone, interspersed with crystals of felspar. It frequently contains also quartz, mica, and hornblende. That most esteemed is the antient porphyry of Egypt, with a ground of a fine red colour passing into purple, having snow-white crystals of felspar imbedded in it. Most beautiful specimens of it are to be seen in the antique colossal statues in the British Museum.
Porphyry occurs in Arran, and in Perthshire between Dalnacardoch and Tummel bridge. It is much used for making slabs, mullers, and mortars.
PORTER, is a malt liquor, so called from being the favourite beverage of the porters and workpeople of the metropolis and other large towns of the British empire; it is characterized by its dark-brown colour, its transparency, its moderately bitter taste, and peculiar aromatic flavour, which, along with its tonic and intoxicating qualities, make it be keenly relished by thirsty palates accustomed to its use. At first the essential distinction of porter arose from its wort being made with highly-kilned brown malt, while other kinds of beer and ale were brewed from a paler article; but of late years, the taste of the public having run in favour of sweeter and lighter beverages, the actual porter is brewed with a less proportion of brown malt, is less strongly hopped, and not allowed to get hard by long keeping in huge ripening tuns. Some brewers colour the porter with burnt sugar; but in general the most respectable concentrate a quantity of their first and best wort to an extract, in an iron pan, and burn this into a colouring stuff, whereby they can lay claim to the merit of using nothing in their manufacture but malt and hops. The singular flavour of good London porter seems to proceed, in a great degree, from that of the old casks and fermenting tuns in which it is prepared. Though not much addicted to vinous potations of any kind, I feel warranted by long experience to opine, that the porter brewed by the eminent London houses, when drunk in moderation, is a far wholesomer beverage for the people than the thin acidulous wines of France and Germany. See Beer.
PORTLAND STONE, is a fine compact oolite, so named from the island where it is quarried. It is a convenient but not a durable building-stone.
POTATO (Pomme de terre, Fr.; Kartoffel, Germ.); is the well-known root of the Solanum tuberosum.
The following Table exhibits several good analyses of the potato:—
Sort. Fibrine. Starch. Veg.
album. Gum. Acids
and
Salts. Water. Analyst.
Red potatos 7 ·0 15 ·0 1 ·4 4 ·1 5 ·1 75 ·0 Einhof.
Id. germinated 6 ·8 15 ·2 1 ·3 3 ·7 — 73 ·0 —
Potato sprouts 2 ·8 0 ·4 0 ·4 3 ·3 — 93 ·0 —
Kidney potatos 8 ·8 9 ·1 0 ·8 — — 81 ·3 —
Large red do. 6 ·0 12 ·9 0 ·7 — — 78 ·0 —
Sweet do. 8 ·2 15 ·1 0 ·8 — — 74 ·3 —
Potato of Peru 5 ·2 15 ·0 1 ·9 1 ·9 76 ·0 Lampad.
Potato of England 6 ·8 12 ·9 1 ·1 1 ·7 77 ·5 —
Onion potato 8 ·4 18 ·7 0 ·9 1 ·7 70 ·3 —
Onion Voigtland 7 ·1 15 ·4 1 ·2 2 ·0 74 ·3 —
Onion cultivated in
the environs of Paris 6 ·79 13 ·3 0 ·92 3 ·3 1 ·4 73 ·12 Henry.
POTASH, or POTASSA. (Potasse, Fr.; Kali, Germ.) This substance was so named from being prepared for commercial purposes by evaporating in iron pots the lixivium of the ashes of wood fuel. In the crude state called potashes, it consists, therefore, of such constituents of burned vegetables as are very soluble in water, and fixed in the fire. The potash salts of plants which originally contained vegetable acids, will be converted into carbonates, the sulphates will become sulphites, sulphurets, or even carbonates, according to the manner of incineration; the nitrates will be changed into pure carbonates, while the muriates or chlorides will remain unaltered. Should quicklime be added to the solution of the ashes, a corresponding portion of caustic potassa will be introduced into the product, with more or less lime, according to the care taken in decanting off the clear lye for evaporation.
In America, where timber is in many places an incumbrance upon the soil, it is felled, piled up in pyramids, and burned, solely with a view to the manufacture of potashes. The ashes are put into wooden cisterns, having a plug at the bottom of one of the sides under a false bottom; a moderate quantity of water is then poured on the mass, and some quicklime is stirred in. After standing for a few hours, so as to take up the soluble matter, the clear liquor is drawn off; evaporated to dryness in iron pots, and finally fused at a red heat into compact masses, which are gray on the outside, and pink-coloured within.
Pearlash is prepared by calcining potashes upon a reverberatory hearth, till the whole carbonaceous matter, and the greater part of the sulphur, be dissipated; then lixiviating the mass, in a cistern having a false bottom covered with straw, evaporating the clear lye to dryness in flat iron pans, and stirring it towards the end into white lumpy granulations.
I find the best pink Canadian potashes, as imported in casks containing about 5 cwts., to contain pretty uniformly 60 per cent. of absolute potassa; and the best pearlashes to contain 50 per cent.; the alkali in the former being nearly in a caustic state; in the latter, carbonated.
All kinds of vegetables do not yield the same proportion of potassa. The more succulent the plant, the more does it afford; for it is only in the juices that the vegetable salts reside, which are converted by incineration into alkaline matter. Herbaceous weeds are more productive of potash than the graminiferous species, or shrubs, and these than trees; and for a like reason, twigs and leaves are more productive than timber. But plants in all cases are richest in alkaline salts when they have arrived at maturity. The soil in which they grow also influences the quantity of saline matter.
The following Table exhibits the average product in potassa of several plants, according to the researches of Vauquelin, Pertuis, Kirwan, and De Saussure:—
In 1000 parts. Potassa.
Pine or fir 0 ·45
Poplar 0 ·75
Trefoil 0 ·75
Beechwood 1 ·45
Oak 1 ·53
Boxwood 2 ·26
Willow 2 ·85
Elm and maple 3 ·90
Wheat straw 3 ·90
Barb of oak twigs 4 ·20
Thistles 5 ·00
Flax stems 5 ·00
Small rushes 5 ·08
Vine shoots 5 ·50
Barley straw 5 ·80
Dry beech bark 6 ·00
Fern 6 ·26
Large rush 7 ·22
Stalk of maize 17 ·5
Bastard chamomile (Anthemis cotula, L.) 19 ·6
Bean stalks 20 ·0
Sunflower stalks 20 ·0
Common nettle 25 ·03
Vetch plant 27 ·50
Thistles in full growth 35 ·37
Dry straw of wheat before earing 47 ·0
Wormwood 73 ·0
Fumitory 79 ·0
Stalks of tobacco, potatos, chesnuts, chesnut husks, broom, heath, furze, tansy, sorrel, vine leaves, beet leaves, orach, and many other plants, abound in potash salts. In Burgundy, the well-known cendres gravelées are made by incinerating the lees of wine pressed into cakes, and dried in the sun; the ashes contain fully 16 per cent. of potassa.
The purification of pearlash is founded upon the fact of its being more soluble in water than the neutral salts which debase it. Upon any given quantity of that substance, in an iron pot, let one and a half times its weight of water be poured, and let a gentle heat be applied for a short time. When the whole has again cooled, the bottom will be encrusted with the salts, while a solution of nearly pure carbonate of potash will be found floating above, which may be drawn off clear by a syphon. The salts may be afterwards thrown upon a filter of gravel. If this lye be diluted with 6 times its bulk of water mixed with as much slaked lime as there was pearlash employed, and the mixture be boiled for an hour, the potash will become caustic, by giving up its carbonic acid to the lime. If the clear settled lixivium be now siphoned off, and concentrated by boiling in a covered iron pan, till it assumes the appearance of oil, it will constitute the common caustic of the surgeon, the potassa fusa of the shops. But to obtain potassa chemically pure, recourse must be had to the bicarbonate, nitrate, or tartrate of potassa, salts which, when carefully crystallized, are exempt from any thing to render the potassa derived from them impure. The bicarbonate having been gently ignited in a silver basin, is to be dissolved in 6 times its weight of water, and the solution is to be boiled for an hour, along with one pound of slaked lime for every pound of the bicarbonate used. The whole must be left to settle without contact of air. The supernatant lye is to be drawn off by a syphon, and evaporated in an iron or silver vessel provided with a small orifice in its close cover for the escape of the steam, till it assumes, as above, the appearance of oil, or till it be nearly redhot. Let the fused potassa be now poured out upon a bright plate of iron, cut into pieces as soon as it concretes, and put up immediately in a bottle furnished with a well-ground stopper. It is hydrate of potassa, being composed of 1 atom of potassa 48, + 1 atom of water 9, = 57.
A pure carbonate of potassa may be also prepared by fusing pure nitre in an earthen crucible, and projecting charcoal into it by small bits at a time, till it ceases to cause deflagration. Or a mixture of 10 parts of nitre and 1 of charcoal may be deflagrated in small successive portions in a redhot deep crucible. When a mixture of 2 parts of tartrate of potassa, or crystals of tartar, and 1 of nitre, is deflagrated, pure carbonate of potassa remains mixed with charcoal, which by lixiviation, and the agency of quicklime, will afford a pure hydrate. Crystals of tartar calcined alone yield also a pure carbonate.
Caustic potassa, as I have said, after being fused in a silver crucible at a red heat, retains 1 prime equivalent of water. Hence its composition in 100 parts is, potassium 70, oxygen 14, water 16. Anhydrous potassa, or the oxide free from water, can be obtained only by the combustion of potassium in the open air. It is composed of 83⁄3 of metal, and 16⁄3 of oxygen. Berzelius’s numbers are 83·05 and 16·95.
Caustic potassa may be crystallized; but in general it occurs as a white brittle substance of spec. grav. 1·708, which melts at a red heat, evaporates at a white heat, deliquesces into a liquid in the air, and attracts carbonic acid; is soluble in water and alcohol, forms soft soaps with fat oils, and soapy-looking compounds with resins and wax; dissolves sulphur, some metallic sulphurets, as those of antimony, arsenic, &c., as also silica, alumina, and certain other bases; and decomposes animal textures, as hair, wool, silk, horn, skin, &c. It should never be touched with the tongue or the fingers.
The following Table exhibits the quantity of Fused Potassa in 100 parts of caustic lye, at the respective densities:—
Sp. gr. Pot.
in 100.
1·58 53·06
1·56 51·58
1·54 50·09
1·52 48·46
1·50 46·45
1·48 44·40
1·46 42·31
1·44 40·17
1·42 37·97
1·40 35·99
1·38 34·74
1·36 33·46
1·34 32·14
1·32 30·74
1·30 29·34
1·28 27·86
1·26 26·34
1·24 24·77
1·22 23·14
1·20 21·25
1·18 19·34
1·16 17·40
1·14 15·38
1·12 13·30
1·10 11·28
1·08 9·20
1·06 7·02
1·04 4·77
1·02 2·44
1·00 0·00
The only certain way of determining the quantity of free potassa in any solid or liquid, is from the quantity of a dilute acid of known strength which it can saturate.
The hydrate of potassa, or its lye, often contains a notable quantity of carbonate, the presence of which may be detected by lime water, and its amount be ascertained by the loss of weight which it suffers, when a weighed portion of the lye is poured into a weighed portion of dilute sulphuric acid poised in the scale of a balance.
There are two other oxides of potassium; the suboxide, which consists, according to Berzelius, of 90·74 of metal, and 9·26 oxygen; and the hyperoxide, an orange-yellow substance, which gives off oxygen in the act of dissolving in water, and becomes potassa. It consists of 62 of metal, and 38 of oxygen.
Carbonate of potassa is composed of 48 parts of base, and 22 of acid, according to most British authorities; or, in 100 parts, of 68·57 and 31·43; but according to Berzelius, of 68·09 and 31·91.
Carbonate of potassa, as it exists associated with carbon in calcined tartar, passes very readily into the Bicarbonate, on being moistened with water, and having a current of carbonic acid gas passed through it. The absorption takes place so rapidly, that the mass becomes hot, and therefore ought to be surrounded with cold water. The salt should then be dissolved in the smallest quantity of water at 120° F., filtered, and crystallized.
POTASSIUM (Eng. and Fr.; Kalium, Germ.); is a metal deeply interesting, not only from its own marvellous properties, but from its having been the first link in the chain of discovery which conducted Sir H. Davy through many of the formerly mysterious and untrodden labyrinths of chemistry.
The easiest and best mode of obtaining this elementary substance, is that contrived by Brunner, which I have often practised upon a considerable scale. Into the orifice of one of the iron bottles, as A, fig. 889., in which mercury is imported, adapt, by screwing, a piece of gun-barrel tube, 9 inches long; having brazed into its side, about 3 inches from its outer end, a similar piece of iron tube. Fill this retort two-thirds with a mixture of 10 parts of cream of tartar, previously calcined in a covered crucible, and 1 of charcoal, both in powder; and lay it horizontally in an air-furnace, so that while the screw orifice is at the inside wall, the extremity of the straight or nozzle tube may project a few inches beyond the brickwork, and the tube brazed into it at right angles may descend pretty close to the outside wall, so as to dip its lower end a quarter of an inch beneath the surface of some rectified naphtha contained in a copper bottle surrounded by ice-cold water. By bringing the condenser-vessel so near the furnace, the tubes along which the potassium vapour requires to pass, run less risk of getting obstructed. The horizontal straight end of the nozzle tube should be shut by screwing a stopcock air-tight into it. By opening the cock momentarily, and thrusting in a hot wire, this tube may be readily kept free, without permitting any considerable waste of potassium. The heat should be slowly applied at first, but eventually urged to whiteness, and continued as long as potassuretted hydrogen continues to be disengaged. The retort, and the part of the nozzle tube exposed to the fire, should be covered with a good refractory lute, as described under the article Phosphorus. The joints must be perfectly air-tight; and the vessel freed from every trace of mercury, by ignition, before it is charged with the tartar-ash.
Tartar skilfully treated in this way will afford 3 per cent. of potassium; and when it is observed to send forth green fumes, it has commenced the production of the metal. Instead of the construction above described, the following form of apparatus may be employed.
A. fig. 889., represents the iron bottle, charged with the incinerated tartar; and B is a fire-brick support. A piece of fire-tile should also be placed between the bottom of the bottle and the back wall of the furnace, to keep the apparatus steady during the operation. Whenever the moisture is expelled, and the mass faintly ignited, the tube C should be screwed into the mouth of the bottle, through a small hole left for this purpose in the side of the furnace. That tube should be no longer, and the front wall of the furnace no thicker, than what is absolutely necessary. As soon as the reduction is indicated by the emission of green vapours, the receiver must be adapted, d, a, D, E, shown in a large scale in fig. 890.
This is a condenser, in two pieces, made of thin sheet copper; D, the upper part, is a rectangular box, open at bottom, about 10 inches high, by 5 or 6 long, and 2 wide; near to the side a, it is divided inside into two equal compartments, up to two-thirds of its height, by a partition b, b, in order to make the vapours that issue from C pursue a downward and circuitous path. In each of its narrow sides, near the top, a short tube is soldered, at d and a; the former being fitted air-tight into the end of the nozzle of the retort, while the latter is closed with a cork traversed by a stiff iron probe e, which passes through a small hole in the partition b, b, under c, and is employed to keep the tube C clear, by its drill-shaped steel point. In one of the broad sides of the box D, near the top, a bit of pipe is soldered on at e, for receiving the end of a bent glass tube of safety, which dips its other and lower end into a glass containing naphtha. E, the bottom copper box, with naphtha, which receives pretty closely the upper case D, is to be immersed in a cistern of cold water containing some lumps of ice.
The chemical action by which potassa is reduced in this process, seems to be somewhat complicated, and has not been thoroughly explained. A very small proportion of pure potassium is obtained; a great deal of it is converted into a black infusible mass, which passes over with the metal, and is very apt to block up the tube. Should this resist clearing out with the probe, the fire must be immediately withdrawn from the furnace, otherwise the apparatus will probably burst or blow up. Care must be taken to prevent any moisture getting into the nozzle, for it would probably produce a violent detonation.
When the operation has proceeded regularly, accompanied to the end with a constant evolution of gas, the retort becomes nearly empty, or contains merely a little charcoal, or carbonate of potassa, and the potassium collects in the naphtha at the bottom of the receiver E, in the form of globules or rounded lumps, of greater or less size, and of a leaden hue. But the greater part of the metal escapes with the gas, in a state of combination not well understood. This gaseous compound burns with a white or reddish-white flame, and deposits potassa. Several ounces of potassium may be produced in this way at one operation; but, as thus obtained, it always contains some combined charcoal, which must be separated by distilling it in an iron retort, having its beak plunged in naphtha.
Pure potassium, as procured in Sir H. Davy’s original method, by acting upon fused potassa under a film of naphtha, with the negative wire of a powerful voltaic battery, is very like quicksilver. It is semi-fluid at 60° Fahr., nearly liquid at 92°, and entirely so at 120°. At 50° it is malleable, and has the lustre of polished silver; at 32° it is brittle, with a crystalline fracture; and at a heat approaching to redness, it begins to boil, is volatilized, and converted into a green-coloured gas, which condenses into globules upon the surface of a cold body. Its specific gravity in the purest state is 0·865 at 60°. When heated in the air, it takes fire, and burns very vividly. It has a stronger affinity for oxygen than any other known substance; and is hence very difficult to preserve in the metallic state. At a high temperature it reduces almost every oxygenated body. When thrown upon water, it kindles, and moves about violently upon the surface, burning with a red flame, till it be consumed; that is to say, converted into potassa. When thrown upon a cake of ice, it likewise kindles, and burns a hole in it. If a globule of it be laid upon wet turmeric paper, it takes fire, and runs about, marking its desultory path with red lines. The flame observed in these cases is owing chiefly to hydrogen, for it is at the expense of the water that the potassium burns.
Potassa, even in a pretty dilute solution, produces a precipitate with muriate of platinum, a phenomenon which distinguishes it from soda. It forms, moreover, with sulphuric and acetic acids, salts which crystallize very differently from the sulphates and acetates of soda.
POTTERY, PORCELAIN. (Eng. and Fr.; Steingut, Porzellan, Germ.) The French, who are fond of giving far-fetched names to the most ordinary things, have dignified the art of pottery with the title of ceramique, from the Greek noun κεραμος, an earthen pot, compounded of two words which signify, in that language, burned clay. In reference to chemical constitution, there are only two genera of baked stoneware. The first consists of a fusible earthy mixture, along with an infusible, which when combined are susceptible of becoming semi-vitrified and translucent in the kiln. This constitutes porcelain or china-ware; which is either hard and genuine, or tender and spurious, according to the quality and quantity of the fusible ingredient. The second kind consists of an infusible mixture of earths, which is refractory in the kiln, and continues opaque. This is pottery, properly so called; but it comprehends several sub-species, which graduate into each other by imperceptible shades of difference. To this head belong earthenware, stoneware, flintware, fayence, delftware, iron-stone china, &c.
The earliest attempts to make a compact stoneware, with a painted glaze, seem to have originated with the Arabians in Spain, about the 9th century, and to have passed thence into Majorca, in which island they were carried on with no little success. In the 14th century, these articles, and the art of imitating them, were highly prized by the Italians, under the name of Majolica, and porcelana, from the Portuguese word for a cup. The first fabric of stoneware possessed by them, was erected at Fayenza, in the ecclesiastical state, whence the French term fayence is derived. The body of the ware was usually a red clay, and the glaze was opaque, being formed of the oxides of lead and tin, along with potash and sand. Bernhard de Pallissy, about the middle of the 16th century, manufactured the first white fayence, at Saintes, in France; and not long afterwards the Dutch produced a similar article, of substantial make, under the name of delftware, and delft porcelain, but destitute of those graceful forms and paintings for which the ware of Fayenza was distinguished. Common fayence may be, therefore, regarded as a strong, well-burned, but rather coarse-grained kind of stoneware.
It was in the 17th century that a small work for making earthenware of a coarse description, coated with a common lead glaze, was formed at Burslem, in Staffordshire, which may be considered as the germ of the vast potteries now established in that county. The manufacture was improved about the year 1690, by two Dutchmen, the brothers Elers, who introduced the mode of glazing ware by the vapour of salt, which they threw by handfuls at a certain period among the ignited goods in the kiln. But these were rude, unscientific, and desultory efforts. It is to the late Josiah Wedgewood, Esq. that this country and the world at large are mainly indebted for the great modern advancement of the ceramic art. It was he who first erected magnificent factories, where every resource of mechanical and chemical science was made to co-operate with the arts of painting, sculpture, and statuary, in perfecting this valuable department of the industry of nations. So sound were his principles, so judicious his plans of procedure, and so ably have they been prosecuted by his successors in Staffordshire, that a population of 60,000 operatives now derives a comfortable subsistence within a district formerly bleak and barren, of 8 miles long, by 6 broad, which contains 150 kilns, and is significantly called the Potteries.
OF THE MATERIALS OF POTTERY OR PORCELAIN, AND THEIR PREPARATION.
1. Clay.—The best clay from which the Staffordshire ware is made, comes from Dorsetshire; and a second quality from Devonshire: but both are well adapted for working, being refractory in the fire, and becoming very white when burnt. The clay is cleaned as much as possible by hand, and freed from loosely adhering stones at the pits where it is dug. In the factory mounted by Mr. Wedgewood, which may be regarded as a type of excellence, the clay is cut to pieces, and then kneaded into a pulp with water, by engines; instead of being broken down with pickaxes, and worked with water by hand-paddles, in a square pit or water-tank, an old process, called blunging. The clay is now thrown into a cast-iron cylinder, 20 inches wide, and 4 feet high, or into a cone 2 feet wide at top, and 6 feet deep, in whose axis an upright shaft revolves, bearing knives as radii to the shaft. The knives are so arranged, that their flat sides lie in the plane of a spiral line; so that by the revolution of the shaft, they not only cut through every thing in their way, but constantly press the soft contents of the cylinder or cone obliquely downwards, on the principle of a screw. Another set of knives stands out motionless at right angles from the inner surface of the cylinder, and projects nearly to the central shaft, having their edges looking opposite to the line of motion of the revolving blades. Thus the two sets of slicing implements, the one active, and the other passive, operate like shears in cutting the clay into small pieces, while the active blades, by their spiral form, force the clay in its comminuted state out at an aperture at the bottom of the cylinder or cone, whence it is conveyed into a cylindrical vat, to be worked into a pap with water. This cylinder is tub-shaped, being about 4 times wider than it is deep. A perpendicular shaft turns also in the axis of this vat, bearing cross spokes one below another, of which the vertical set on each side is connected by upright staves, giving the movable arms the appearance of two or four opposite square paddle-boards revolving with the shaft. This wooden framework, or large blunger, as it is called, turns round amidst the water and clay lumps, so as to beat them into a fine pap, from which the stony and coarse sandy particles separate, and subside to the bottom. Whenever the pap has acquired a cream-consistenced uniformity, it is run off through a series of wire, lawn, and silk sieves, of different degrees of fineness, which are kept in continual agitation backwards and forward by a crank mechanism; and thus all the grosser parts are completely separated, and hindered from entering into the composition of the ware. This clay liquor is set aside in proper cisterns, and diluted with water to a standard density.
2. But clay alone cannot form a proper material for stoneware, on account of its great contractility by heat, and the consequent cracking and splitting in the kiln of the vessels made of it; for which reason, a siliceous substance incapable of contraction must enter into the body of pottery. For this purpose, ground flints, called flint-powder by the potters, is universally preferred. The nodules of flint extracted from the chalk formation, are washed, heated redhot in a kiln, like that for burning lime, and thrown in this state into water, by which treatment they lose their translucency, and become exceeding brittle. They are then reduced to a coarse powder in a stamping-mill, similar to that for stamping ores; see Metallurgy. The pieces of flint are laid on a strong grating, and pass through its meshes whenever they are reduced by the stamps to a certain state of comminution. This granular matter is now transferred to the proper flint-mill, which consists of a strong cylindrical wooden tub, bottomed with flat pieces of massive chert, or hornstone, over which are laid large flat blocks of similar chert, that are moved round over the others by strong iron or wooden arms projecting from an upright shaft made to revolve in the axis of the mill-tub. Sometimes the active blocks are fixed to these cross arms, and thus carried round over the passive blocks at the bottom. See infrà, under Porcelain, figures of the flint and felspar mill. Into this cylindrical vessel a small stream of water constantly trickles, which facilitates the grinding motion and action of the stones, and works the flint powder and water into a species of pap. Near the surface of the water there is a plughole in the side of the tub, by which the creamy-looking flint liquor is run off from time to time, to be passed through lawn or silk sieves, similar to those used for the clay liquor; while the particles that remain on the sieves are returned into the mill. This pap is also reduced to a standard density by dilution with water; whence the weight of dry siliceous earth present, may be deduced from the measure of the liquor.
The standard clay and flint liquors are now mixed together, in such proportion by measure, that the flint powder may bear to the dry clay the ratio of one to five, or occasionally one to six, according to the richness or plasticity of the clay; and the liquors are intimately incorporated in a revolving churn, similar to that employed for making the clay-pap. This mixture is next freed from its excess of water, by evaporation in oblong stone troughs, called slip-kilns, bottomed with fire-tiles, under which a furnace flue runs. The breadth of this evaporating trough varies from 2 to 6 feet; its length from 20 to 50; and its depth from 8 to 12 inches, or more.
By the dissipation of the water, and careful agitation of the pap, an uniform doughy mass is obtained; which, being taken out of the trough, is cut into cubical lumps. These are piled in heaps, and left in a damp cellar for a considerable time; that is, several months, in large manufactories. Here the dough suffers disintegration, promoted by a kind of fermentative action, due probably to some vegetable matter in the water and the clay; for it becomes black, and exhales a fetid odour. The argillaceous and siliceous particles get disintegrated also by the action of the water, in such a way that the ware made with old paste is found to be more homogeneous, finer grained, and not so apt to crack or to get disfigured in the baking, as the ware made with newer paste.
But this chemical comminution must be aided by mechanical operations; the first of which is called the potter’s sloping or wedging. It consists in seizing a mass of clay in the hands, and, with a twist of both at once, tearing it into two pieces, or cutting it with a wire. These are again slapped together with force, but in a different direction from that in which they adhered before, and then dashed down on a board. The mass is once more torn or cut asunder at right angles, again slapped together, and so worked repeatedly for 20 or 30 times, which ensures so complete an incorporation of the different parts, that if the mass had been at first half black and half white clay, it would now be of a uniform gray colour. A similar effect is produced in some large establishments by a slicing machine, like that used for cutting down the clay lumps as they come from the pit.
In the axis of a cast iron cylinder or cone, an upright shaft is made to revolve, from which the spiral-shaped blades extend, with their edges placed in the direction of rotation. The pieces of clay subjected to the action of these knives (with the reaction of fixed ones) are minced to small morsels, which are forced pell-mell by the screw-like pressure into an opening of the bottom of the cylinder or cone, from which a horizontal pipe about 6 inches square proceeds. The dough is made to issue through this outlet, and is then cut into lengths of about 12 inches. These clay pillars or prisms are thrown back into the cylinder, and subjected to the same operation again and again, till the lumps have their particles perfectly blended together. This process may advantageously precede their being set aside to ripen in a damp cellar. In France the stoneware dough is not worked in such a machine; but after being beat with wooden mallets, a practice common also in England, it is laid down on a clean floor, and a workman is set to tread upon it with naked feet for a considerable time, walking in a spiral direction from the centre to the circumference, and from the circumference to the centre. In Sweden, and also in China (to judge from the Chinese paintings which represent their manner of making porcelain), the clay is trodden to a uniform mass by oxen. It is afterwards, in all cases, kneaded like baker’s dough, by folding back the cake upon itself, and kneading it out, alternately.
The process of slapping consists in cutting through a large mass with a wire, lifting up either half in both hands, and casting it down with great violence on the other; and this violent treatment of the clay is repeated till every appearance of air-bubbles is removed, for the smallest remaining vesicle expanding in the kiln, would be apt to cause blisters or warts upon the ware.
Having thus detailed the preparation of the stoneware paste, we have next to describe the methods of forming it into articles of various forms.
Throwing is performed upon a tool called the potter’s lathe. (See fig., infrà.) This consists of an upright iron shaft, about the height of a common table, on the top of which is fixed, by its centre, a horizontal disc or circular piece of wood, of an area sufficiently great for the largest stoneware vessel to stand upon. The lower end of the shaft is pointed, and runs in a conical step, and its collar, a little below the top-board, being truly turned, is embraced in a socket attached to the wooden frame of the lathe. The shaft has a pulley fixed upon it, with grooves for 3 speeds, over which an endless band passes from a fly-wheel, by whose revolution any desired rapidity of rotation may be given to the shaft and its top-board. This wheel, when small, may be placed alongside, as in the turner’s lathe, and then it is driven by a treadle and crank; or when of larger dimensions, it is turned by the arms of a labourer. Sometimes, indeed, the wooden plate is replaced by a large thick disc of Paris plaster, which is whirled round by the hand of the potter, without the intervention of a pulley and fly-wheel, and affords sufficient centrifugal power for fashioning small vessels. The mass of dough to be thrown, is weighed out or gauged by an experienced hand. The thrower dashes down the lump on the centre of the revolving board, and dipping his hands frequently in an adjoining tub of water, he works up the clay into a tall irregular cylinder, and then down into a cake, alternately, till he has secured the final extrication of air-bubbles, and then gives the proper form to the vessel under a less speed of rotation, regulating its dimensions by wooden pegs and gauges. He now cuts it off at the base with a piece of fine brass wire, fastened to a handle at either end. The vessel thus rudely fashioned is placed in a situation where it may dry gradually to a proper point. At a certain stage of the drying, called the green state, it possesses a greater tenacity than at any other, till it is baked. It is then taken to another lathe, called the turning lathe, where it is attached by a little moisture to the vertical face of a wooden chuck, and turned nicely into its proper shape with a very sharp tool, which also smooths it. After this it is slightly burnished with a smooth steel surface.
DESCRIPTION OF THE POTTER’S LATHE.
A, fig. 891., is the profile of the English potter’s lathe, for blocking out round ware; C is the table or tray; a is the head of the lathe, with its horizontal disc; a, b, is the upright shaft of the head; d, pulleys with several grooves of different diameters, fixed upon the shaft, for receiving the driving-cord or band; k is a bench upon which the workman sits astride; e, the treadle foot-board; l, is a ledge-board, for catching the shavings of clay which fly off from the lathe; h is an instrument, with a slide-nut i, for measuring the objects in the blocking out; c is the fly-wheel with its winch-handle r, turned by an assistant; the sole-frame is secured in its place by the heavy stone p; f is the oblong guide-pulley, having also several grooves for converting the vertical movement of the fly-wheel into the horizontal movement of the head of the lathe.
D is one of the intermediate forms given by the potter to the ball of clay, as it revolves upon the head of the lathe.
In large potteries, the whole of the lathes, both for throwing and turning, are put in motion by a steam-engine. The vertical spindle of the lathe has a bevel wheel on it, which works in another bevel toothed wheel fixed to a horizontal shaft. This shaft is provided with a long conical wooden drum, from which a strap ascends to a similar conical drum on the main lying shaft. The apex of the one cone corresponds to the base of the other, which allows the strap to retain the same degree of tension (see the conical drum apparatus of the Stearine-press), while it is made to traverse horizontally, in order to vary the speed of the lathe at pleasure. When the belt is at the base of the driving-cone, it works near the vortex of the driven one, so as to give a maximum velocity to the lathe, and vice versâ.
During the throwing of any article, a separate mechanism is conducted by a boy, which makes the strap move parallel to itself along these conical drums, and nicely regulates the speed of the lathe. When the strap runs at the middle of the cones, the velocity of each shaft is equal. By this elegant contrivance of parallel cones reversed, the velocity rises gradually to its maximum, and returns to its minimum or slower motion when the workman is about finishing the article thrown. The strap is then transferred to a pair of loose pulleys, and the lathe stops. The vessel is now cut off at the base with a small wire; is dried, turned on a power lathe, and polished as above described.
The same degree of dryness which admits of the clay being turned on the lathe, also suits for fixing on the handles and other appendages to the vessels. The parts to be attached being previously prepared, are joined to the circular work by means of a thin paste which the workmen call slip, and the seams are then smoothed off with a wet sponge. They are now taken to a stove-room heated to 80° or 90° F., and fitted up with a great many shelves. When they are fully dried, they are smoothed over with a small bundle of hemp, if the articles be fine, and are then ready for the kiln, which is to convert the tender clay into the hard biscuit.
A great variety of pottery wares, however, cannot be fashioned on the lathe, as they are not of a circular form. These are made by two different methods, the one called press-work, and the other casting. The press-work is done in moulds made of Paris plaster, the one half of the pattern being formed in the one side of the mould, and the other half on the other side: these moulding-pieces fit accurately together. All vessels of an oval form, and such as have flat sides, are made in this way. Handles of tea-pots, and fluted solid rods of various shapes, are formed by pressure also; viz., by squeezing the dough contained in a pump-barrel through different shaped orifices at its bottom, by working a screw applied to the piston-rod. The worm-shaped dough, as it issues, is cut to proper lengths, and bent into the desired form. Tubes may be also made on the same pressure principle, only a tubular opening must be provided in the bottom plate of the clay-forcing pump. The other method of fashioning earthenware articles is called casting, and is, perhaps, the most elegant for such as have an irregular shape. This operation consists in pouring the clay, in the state of pap or slip, into plaster moulds, which are kept in a desiccated state. These moulds, as well as the pressure ones, are made in halves, which nicely correspond together. The slip is poured in till the cavity is quite full, and is left in the mould for a certain time, more or less, according to the intended thickness of the vessel. The absorbent power of the plaster soon abstracts the water, and makes the coat of clay in contact with it quite doughy and stiff, so that the part still liquid being poured out, a hollow shape remains, which when removed from the mould constitutes the half of the vessel, bearing externally the exact impress of the mould. The thickness of the clay varies with the time that the paste has stood upon the plaster. These cast articles are dried to the green state, like the preceding, and then joined accurately with slip. Imitations of flowers and foliage are elegantly executed in this way. This operation, which is called furnishing, requires very delicate and dexterous manipulation.
The saggers for the unglazed coloured stoneware should be covered inside with a glaze composed of 12 parts of common salt and 30 of potash, or 6 parts of potash and 14 of salt; which may be mixed with a little of the common enamel for the glazed pottery saggers. The bottom of each sagger has some bits of flints sprinkled upon it, which become so adherent after the first firing as to form a multitude of little prominences for setting the ware upon, when this does not consist of plates. It is the duty of the workmen belonging to the glaze kiln to make the saggers during the intervals of their work; or if there be a relay of hands, the man who is not firing makes the saggers.
The English kilns differ from those of France and Germany, in their construction, in the nature of their fuel, and in the high temperature required to produce a surface sufficiently hard for a perfectly fine glaze.
When the ware is sufficiently dry, and in sufficient quantity to fill a kiln, the next process is placing the various articles in the baked fire-clay vessels, which may be either of a cylindrical or oval shape; called gazettes, Fr.; kapseln, Germ. These are from 6 to 8 inches deep, and from 12 to 18 inches in diameter. When packed full of the dry ware, they are piled over each other in the kiln. The bottom of the upper sagger forms the lid of its fellow below; and the junction of the two is luted with a ring of soft clay applied between them. These dishes protect the ware from being suddenly and unequally heated, and from being soiled by the smoke and vapours of the fuel. Each pile of saggers is called a bung.
POTTERY KILN OF STAFFORDSHIRE.
Figs. 892, , , , 896., represent the kiln for baking the biscuit, and also for running the glaze, in the English potteries.
a, a, figs. 892, , and , are the furnaces which heat the kiln; of which b, in fig. 892., are the upper mouths, and b′ the lower; the former being closed more or less by the fire-tile z, shown in fig. 896.
f is one fireplace; for the manner of distributing the fuel in it, see fig. 896.
g, y, figs. 892. and 896., are the horizontal and vertical flues and chimneys for conducting the flame and smoke. l is the laboratory, or body of the kiln; having its floor k sloping slightly downwards from the centre to the circumference. x, y, is the slit of the horizontal register, leading to the chimney flue y of the furnace, being the first regulator; x, u, is the vertical register conduit, leading to the furnace or mouth f, being the second regulator; v is the register slit above the furnace, and its vertical flue leading into the body of the kiln; v′, c, slit for regulating flue at the shoulder of the kiln; i is an arch which supports the walls of the kiln, when the furnace is under repair; c, c, are small flues in the vault s of the laboratory. h, fig. 893., is the central flue, called lunette, of the laboratory.
T, T, is the conical tower or howell, strengthened with a series of iron hoops, O′ is the great chimney or lunette of the tower; p is the door of the laboratory, bound inside with an iron frame.
A, is the complete kiln and howell, with all its appurtenances.
B, fig. 893., is the plan at the level d, d, of the floor, to show the arrangement and distribution of all the horizontal flues, both circular and radiating.
C, fig. 894., is a plan at the level e, e, of the upper mouths b, of the furnaces, to show the disposition of the fireplaces of the vertical flues, and of the horizontal registers, or peep-holes.
D, fig. 894., is a bird’s-eye view of the top of the vault or dome s, to show the disposition of the vent-holes c, c.
E, fig. 895., is a detailed plan at the level c, c, of one furnace and its dependencies.
F, fig. 896., is a transverse section, in detail, of one furnace and its dependencies.
The same letters in all the figures indicate the same objects.
Charging of the kiln.—The saggers are piled up first in the space between each of the upright furnaces, till they rise to the top of the flues. These contain the smaller articles. Above this level, large fire tiles are laid, for supporting other saggers, filled with teacups, sugar-basins, &c. In the bottom part of the pile, within the preceding, the same sorts of articles are put; but in the upper part all such articles are placed as require a high heat. Four piles of small saggers, with a middle one 10 inches in height, complete the charge. As there are 6 piles between each furnace, and as the biscuit kiln has 8 furnaces, a charge consequently amounts to 48 or 50 bungs, each composed of from 18 to 19 saggers. The inclination of the bungs ought always to follow the form of the kiln, and should therefore tend towards the centre, lest the strong draught of the furnaces should make the saggers fall against the walls of the kiln, an accident apt to happen were these piles perpendicular. The last sagger of each bung is covered with an unbaked one, three inches deep, in place of a round lid. The watches are small cups, of the same biscuit as the charge, placed in saggers, four in number, above the level of the flue-tops. They are taken hastily out of the saggers, lest they should get smoked, and are thrown into cold water.
When the charging is completed, the firing is commenced, with coal of the best quality. The management of the furnaces is a matter of great consequence to the success of the process. No greater heat should be employed for some time than may be necessary to agglutinate the particles which enter into the composition of the paste, by evaporating all the humidity; and the heat should never be raised so high as to endanger the fusion of the ware, which would make it very brittle.
When ever the mouth or door of the kiln is built up, a child prepares several fires in the neighbourhood of the howell, while a labourer transports in a wheelbarrow a supply of coals, and introduces into each furnace a number of lumps. These lumps divide the furnace into two parts; those for the upper flues being placed above, and those for the ground flues below, which must be kept unobstructed.
The fire-mouths being charged, they are kindled to begin the baking, the regulator tile z, fig. 896., being now opened; an hour afterwards the bricks at the bottom of the furnace are stopped up. The fire is usually kindled at 6 o’clock in the evening, and progressively increased till 10, when it begins to gain force, and the flame rises half-way up the chimney. The second charge is put in at 8 o’clock, and the mouths of the furnaces are then covered with tiles; by which time the flame issues through the vent of the tower. An hour afterwards a fresh charge is made; the tiles z, which cover the furnaces, are slipped back; the cinders are drawn to the front, and replaced with small coal. About half-past 11 o’clock the kiln-man examines his furnaces, to see that their draught is properly regulated. An hour afterwards a new charge of coal is applied; a practice repeated hourly till 6 o’clock in the morning. At this moment he takes out his first watch, to see how the baking goes on. It should be at a very pale-red heat; but the watch of 7 o’clock should be a deeper red. He removes the tiles from those furnaces which appear to have been burning too strongly, or whose flame issues by the orifices made in the shoulder of the kiln; and puts tiles upon those which are not hot enough. The flames glide along briskly in a regular manner. At this period he draws out the watches every quarter of an hour, and compares them with those reserved from a previous standard kiln; and if he observes a similarity of appearance, he allows the furnaces to burn a little longer; then opens the mouths carefully and by slow degrees; so as to lower the heat, and finish the round.
The baking usually lasts from 40 to 42 hours; in which time the biscuit kiln may consume 14 tons of coals; of which four are put in the first day, seven the next day and following night, and the four last give the strong finishing heat.
Emptying the kiln.—The kiln is allowed to cool very slowly. On taking the ware out of the saggers, the biscuit is not subjected to friction, as in the foreign potteries, because it is smooth enough; but is immediately transported to the place where it is to be dipped in the glaze or enamel tub. A child makes the pieces ring, by striking with the handle of the brush, as he dusts them, and then immerses them into the glaze cream; from which tub they are taken out by the enameller, and shaken in the air. The tub usually contains no more than 4 or 5 inches depth of the glaze, to enable the workman to pick out the articles more readily, and to lay them upon a board, whence they are taken by a child to the glaze kiln.
Glazing.—A good enamel is an essential element of fine stoneware; it should experience the same dilatation and contraction by heat and cold as the biscuit which it covers. The English enamels contain nothing prejudicial to health, as many of the foreign glazes do; no more lead being added to the former than is absolutely necessary to convert the siliceous and aluminous matters with which it is mixed into a perfectly neutral glass.
Three kinds of glazes are used in Staffordshire; one for the common pipe-clay or cream-coloured ware; another for the finer pipe-clay ware to receive impressions, called printing body; a third for the ware which is to be ornamented by painting with the pencil.
The glaze of the first or common ware is composed of 53 parts of white lead, 16 of Cornish stone, 36 of ground flints, and 4 of flint glass; or of 40 of white lead, 36 of Cornish stone, 12 of flints, and 4 of flint or crystal glass. These compositions are not fritted; but are employed after being simply triturated with water into a thin paste.
The following is the composition of the glaze intended to cover all kinds of figures printed in metallic colours: 26 parts of white felspar are fritted with 6 parts of soda, 2 of nitre, and 1 of borax; to 20 pounds of this frit, 26 parts of felspar, 20 of white lead, 6 of ground flints, 4 of chalk, 1 of oxide of tin, and a small quantity of oxide of cobalt, to take off the brown cast, and give a faint azure tint, are added.
The following recipe may also be used. Frit together 20 parts of flint glass, 6 of flints, 2 of nitre, and 1 of borax; add to 12 parts of that frit, 40 parts of white lead, 36 of felspar, 8 of flints, and 6 of flint glass; then grind the whole together into an uniform cream-consistenced paste.
As to the stoneware which is to be painted, it is covered with a glaze composed of 13 parts of the printing-colour frit, to which are added 50 parts of red lead, 40 of white lead, and 12 of flint; the whole having been ground together.
The above compositions produce a very hard glaze, which cannot be scratched by the knife, is not acted upon by vegetable acids, and does no injury to potable or edible articles kept in the vessels covered with it. It preserves for an indefinite time the glassy lustre, and is not subject to crack and exfoliate, like most of the Continental stoneware, made from common pipe-clay.
In order that the saggers in which the articles are baked, after receiving the glaze, may not absorb some of the vitrifying matter, they are themselves coated, as above mentioned, with a glaze composed of 13 parts of common salt, and 30 parts of potash, simply dissolved in water, and brushed over them.
Glaze kiln.—This is usually smaller than the biscuit kiln, and contains no more than 40 or 45 bungs or columns, each composed of 16 or 17 saggers. Those of the first bung rest upon round tiles, and are well luted together with a finely ground fire-clay of only moderate cohesion; those of the second bung are supported by an additional tile. The lower saggers contain the cream-coloured articles, in which the glaze is softer than that which covers the blue printed ware; this being always placed in the intervals between the furnaces, and in the uppermost saggers of the columns. The bottom of the kiln, where the glazed ware is not baked, is occupied by printed biscuit ware.
Pyrometric balls of red clay, coated with a very fusible lead enamel, are employed in the English potteries to ascertain the temperature of the glaze kilns. This enamel is so rich, and the clay upon which it is spread, is so fine-grained and compact, that even when exposed for three hours to the briskest flame, it does not lose its lustre. The colour of the clay alone changes, whereby the workman is enabled to judge of the degree of heat within the kiln. At first the balls have a pale red appearance; but they become browner with the increase of the temperature. The balls, when of a slightly dark-red colour, indicate the degree of baking for the hard glaze of pipeclay ware; but if they become dark brown, the glaze will be much too hard, being that suited for ironstone ware; lastly, when they acquire an almost black hue, they show a degree of heat suited to the formation of a glaze upon porcelain.
The glazer provides himself at each round with a stock of these ball watches, reserved from the preceding baking, to serve as objects of comparison; and he never slackens the firing till he has obtained the same depth of shade, or even somewhat more; for it may be remarked, that the more rounds a glaze kiln has made, the browner the balls are apt to become. A new kiln bakes a round of enamel-ware sooner than an old one; as also with less fuel, and at a lower temperature. The watch-balls of these first rounds have generally not so deep a colour as if they were tried in a furnace three or four months old. After this period, cracks begin to appear in the furnaces; the horizontal flues get partially obstructed, the joinings of the brickwork become loose; in consequence of which there is a loss of heat and waste of fuel; the baking of the glaze takes a longer time, and the pyrometric balls assume a different shade from what they had on being taken out of the new kiln, so that the first watches are of no comparable use after two months. The baking of enamel is commenced at a low temperature, and the heat is progressively increased; when it reaches the melting point of the glaze, it must be maintained steadily, and the furnace mouths be carefully looked after, lest the heat should be suffered to fall. The firing is continued 14 hours, and then gradually lowered by slight additions of fuel; after which the kiln is allowed from 5 to 6 hours to cool.
Muffles.—The paintings and the printed figures applied to the glaze of stoneware and porcelain are baked in muffles of a peculiar form. Fig. 897. is a lateral elevation of one of these muffles; fig. 898. is a front view. The same letters denote the same parts in the two figures.
a is the furnace; b, the oblong muffle, made of fire-clay, surmounted with a dome pierced with three apertures k, k, k, for the escape of the vaporous matters of the colours and volatile oils with which they are ground up; c is the chimney; d, d, feed-holes, by which the fuel is introduced; e, the fire-grate; f, the ash-pit; channels are left in the bottom of the furnace to facilitate the passage of the flame beneath the muffle; g is a lateral hole, which makes a communication across the furnace in the muffle, enabling the kiln man to ascertain what is passing within; k, k, are the lateral chinks for observing the progress of the firing or flame; l, is an opening scooped out in the front of the chimney to modify its draught.
The articles which are printed or painted upon the glaze are placed in the muffle without saggers, upon tripods, or movable supports furnished with feet. The muffle being charged, its mouth is closed with a fire-tile well luted round its edges. The fuel is then kindled in the fireplaces d, d, and the door of the furnace is closed with bricks, in which a small opening is left for taking out samples, and for examining the interior of the muffle. These sample or trial pieces, attached to a strong iron wire, show the progress of the baking operation. The front of the fireplaces is covered with a sheet-iron plate, which slides to one side, and may be shut whenever the kiln is charged. Soon after the fire is lighted, the flame, which communicates laterally from one furnace to another, envelopes the muffle on all sides, and thence rises up the chimney.
Printing of stoneware.—The printing under the stoneware glaze is generally performed by means of cobalt, and has different shades of blue according to the quantity of colouring matter employed. After having subjected this oxide to the processes requisite for its purification, it is mixed with a certain quantity of ground flints and sulphate of baryta, proportioned to the dilution of the shade. These materials are fritted and ground; but before they are used, they must be mixed with a flux consisting of equal parts by weight of flint glass and ground flints, which serves to fix the colour upon the biscuit, so that the immersion in the glaze liquor may not displace the lines printed on, as also to aid in fluxing the cobalt.
The following are the processes usually practised in Staffordshire for printing under the glaze.
The cobalt, or whatever colour is employed, should be ground upon a porphyry slab, with a varnish prepared as follows:—A pint of linseed oil is to be boiled to the consistence of thick honey, along with 4 ounces of rosin, half a pound of tar, and half a pint of oil of amber. This is very tenacious, and can be used only when liquefied by heat; which the printer effects by spreading it upon a hot cast-iron plate.
The printing plates are made of copper, engraved with pretty deep lines in the common way. The printer, with a leather muller, spreads upon the engraved plate, previously heated, his colour, mixed up with the above oil varnish, and removes what is superfluous with a pallet knife; then cleans the plate with a dossil filled with bran, tapping and wiping as if he were removing dust from it. This operation being finished, he takes the paper intended to receive the impression, soaks it with soap-water, and lays it moist upon the copper-plate. The soap makes the paper part more readily from the copper, and the thick ink part more readily from the biscuit. The copper-plate is now passed through the engraver’s cylinder press, the proof leaf is lifted off and handed to the women, who cut it into detached pieces, which they apply to the surface of the biscuit. The paper best fitted for this purpose is made entirely of linen rags; it is very thin, of a yellow colour, and unsized, like tissue blotting-paper.
The stoneware biscuit never receives any preparation before being imprinted, the oil of the colour being of such a nature as to fix the figures firmly. The printed paper is pressed and rubbed on with a roll of flannel, about an inch and a half in diameter, and 12 or 15 inches long, bound round with twine, like a roll of tobacco. This is used as a burnisher, one end of it being rested against the shoulder, and the other end being rubbed upon the paper; by which means it transfers all the engraved traces to the biscuit. The piece of biscuit is laid aside for a little, in order that the colour may take fast hold; it is then plunged into water, and the paper is washed away with a sponge.
When the paper is detached, the piece of ware is dipped into a caustic alkaline lye to saponify the oil, after which it is immersed in the glaze liquor, with which the printed figures readily adhere. This process, which is easy to execute, and very economical, is much preferable to the old plan of passing the biscuit into the muffle after it had been printed, for the purpose of fixing and volatilizing the oils. When the paper impression is applied to pieces of porcelain, they are heated before being dipped in the water, because, being already semi-vitrified, the paper sticks more closely to them than to the biscuit, and can be removed only by a hard brush.
The impression above the glaze is done by quite a different process, which dispenses with the use of the press. A quantity of fine clean glue is melted and poured hot upon a large flat dish, so as to form a layer about a quarter of an inch thick, and of the consistence of jelly. When cold it is divided into cakes of the size of the copper-plates it is intended to cover.
The operative (a woman) rubs the engraved copper-plate gently over with linseed oil boiled thick, immediately after which she applies the cake of glue, which she presses down with a silk dossil filled with bran. The cake licks up all the oil out of the engraved lines; it is then cautiously lifted off, and transferred to the surface of the glazed ware which it is intended to print. The glue cake being removed, the enamel surface must be rubbed with a little cotton, whereby the metallic colours are attached only on the lines charged with oil; the piece is then heated under the muffle. The same cake of glue may serve for several impressions.
Ornaments and colouring.—Common stoneware is coloured by means of two kinds of apparatus; the one called the blowing-pot, the other the worming-pot. The ornaments made in relief in France, are made hollow (intaglio) in England, by means of a mould engraved in relief, which is passed over the article. The impression which it produces is filled with a thick clay paste, which the workman throws on with the blowing-pot. This is a vessel like tea-pot, having a spout, but it is hermetically sealed at top with a clay plug, after being filled with the pasty liquor. The workman, by blowing in at the spout, causes the liquor to fly out through a quill pipe which goes down through the clay plug into the liquor. The jet is made to play upon the piece while it is being turned upon the lathe; so that the hollows previously made in it by the mould or stamp are filled with a paste of a colour different from that of the body. When the piece has acquired sufficient firmness to bear working, the excess of the paste is removed by an instrument called a tournasin, till the ornamental figure produced by the stamp be laid bare; in which case merely the colour appears at the bottom of the impression. By passing in this manner several layers of clay liquor of different colours over each other with the blowing-pot, net-work and decorations of different colours and shades are very rapidly produced.
The serpentine or snake pots, established on the same principle, are made of tin plate in three compartments, each containing a different colour. These open at the top of the vessel in a common orifice, terminated by small quill tubes. On inclining the vessel, the three colours flow out at once in the same proportion at the one orifice, and are let fall upon the piece while it is being slowly turned upon the lathe; whereby curious serpent-like ornaments may be readily obtained. The clay liquor ought to be in keeping with the stoneware paste. The blues succeed best when the ornaments are made with the finer pottery mixtures given above.
Metallic lustres applied to stoneware.—The metallic lustre being applied only to the outer surface of vessels, can have no bad effect on health, whatever substances be employed for the purpose; and as the glaze intended to receive it is sufficiently fusible, from the quantity of lead it contains, there is no need of adding a flux to the metallic coating. The glaze is in this case composed of 60 parts of litharge, 36 of felspar, and 15 of flints.
The silver and platina lustres are usually laid upon a white ground, while those of gold and copper, on account of their transparency, succeed only upon a coloured ground. The dark-coloured stoneware is, however, preferable, as it shows off the colours to most advantage; and thus the shades may be varied by varying the colours of the ornamental figures applied by the blowing-pot.
The gold and platina lustre is almost always applied to a paste body made on purpose, and coated with the above-described lead glaze. This paste is brown, and consists of 4 parts of clay, 4 parts of flints, an equal quantity of kaolin (china clay), and 6 parts of felspar. To make brown figures in relief upon a body of white paste, a liquor is mixed up with this paste, which ought to weigh 26 ounces per pint, in order to unite well with the other paste, and not to exfoliate after it is baked.
Preparation of gold lustre.—Dissolve first in the cold, and then with heat, 48 grains of fine gold in 288 grains of an aqua regia, composed of 1 ounce of nitric acid and 3 ounces of muriatic acid; add to that solution 4⁄2 grains of grain tin, bit by bit; and then pour some of that compound solution into 20 grains of balsam of sulphur diluted with 10 grains of oil of turpentine. The balsam of sulphur is prepared by heating a pint of linseed oil, and 2 ounces of flowers of sulphur, stirring them continually till the mixture begins to boil; it is then cooled, by setting the vessel in cold water; after which it is stirred afresh, and strained-through linen. The above ingredients, after being well mixed, are to be allowed to settle for a few minutes; then the remainder of the solution of gold is to be poured in, and the whole is to be triturated till the mass has assumed such a consistence that the pestle will stand upright in it; lastly, there must be added to the mixture 30 grains of oil of turpentine, which being ground in, the gold lustre is ready to be applied. If the lustre is too light or pale, more gold must be added, and if it have not a sufficiently violet or purple tint, more tin must be used.
Platina lustre.—Of this there are two kinds; one similar to polished steel, another lighter and of a silver-white hue. To give stoneware the steel colour with platina, this metal must be dissolved in an aqua regia composed of 2 parts of muriatic acid, and 1 part of nitric. The solution being cooled, and poured into a capsule, there must be added to it, drop by drop, with continual stirring with a glass rod, a spirit of tar, composed of equal parts of tar and sulphur boiled in linseed oil and filtered. If the platina solution be too strong, more spirit of tar must be added to it; but if too weak, it must be concentrated by boiling. Thus being brought to the proper pitch, the mixture may be spread ever the piece, which being put into the muffle, will take the aspect of steel.
The oxide of platina, by means of which the silver lustre is given to stoneware, is prepared as follows:—After having dissolved to saturation the metal in an aqua regia composed of equal parts of nitric and muriatic acid, the solution is to be poured into a quantity of boiling water. At the same time, a capsule, containing solution of sal-ammoniac is placed upon a sand-bath, and the platina solution being poured into it, the metal will fall down in the form of the well-known yellow precipitate, which is to be washed with cold water till it is perfectly edulcorated, then dried, and put up for use.
This metallic lustre is applied very smoothly by means of a flat camel’s hair brush. It is then to be passed through the muffle kiln; but it requires a second application of the platinum to have a sufficient body of lustre. The articles sometimes come black out of the kiln, but they get their proper appearance by being rubbed with cotton.
Platina and gold lustre; by other recipes.
Platina lustre.—Dissolve 1 ounce of platinum in aqua regia formed of 2 parts of muriatic acid and 1 part of nitric acid, with heat upon a sand-bath, till the liquid is reduced to two-thirds of its volume; let it cool; decant into a clean vessel, and pour into it, drop by drop, with constant stirring, some distilled tar, until such a mixture is produced as will give a good result in a trial upon the ware in the kiln. If the lustre be too intense, more tar must be added; if it be too weak, the mixture must be concentrated by further evaporation.
Gold lustre.—Dissolve four shillings’ worth of gold in aqua regia with a gentle heat. To the solution, when cool, add 2 grains of grain tin, which will immediately dissolve. Prepare a mixture of half an ounce of balsam of sulphur with a little essence of turpentine, beating them together till they assume the appearance of milk. Pour this mixture into the solution of gold and tin, drop by drop, with continual stirring; and place the whole in a warm situation for some time.
It is absolutely necessary to apply this lustre only upon an enamel or glaze which has already passed through the fire, otherwise the sulphur would tarnish the composition.
These lustres are applied with most advantage upon chocolate and other dark grounds. Much skill is required in their firing, and a perfect acquaintance with the quality of the glaze on which they are applied.
An iron lustre, is obtained by dissolving a bit of steel or iron in muriatic acid, mixing this solution with the spirit of tar, and applying it to the surface of the ware.
Aventurine glaze.—Mix a certain quantity of silver leaf with the above-described soft glaze, grind the mixture along with some honey and boiling water, till the metal assume the appearance of fine particles of sand. The glaze being naturally of a yellowish hue, gives a golden tint to the small fragments of silver disseminated through it. Molybdena may also be applied to produce the aventurine aspect.
The granite-like gold lustre, is produced by throwing lightly with a brush a few drops of oil of turpentine upon the goods already covered with the preparation for gold lustre. These cause it to separate and appear in particles resembling the surface of granite. When marbling is to be given to stoneware, the lustres of gold, platina, and iron are used at once, which blending in the fusion, form veins like those of marble.
Pottery and stoneware of the Wedgewood colour.—This is a kind of semi-vitrified ware, called dry bodies, which is not susceptible of receiving a superficial glaze. This pottery is composed in two ways: the first is with barytic earths, which act as fluxes upon the clays, and form enamels: thus the Wedgewood jasper ware is made.
The white vitrifying pastes, fit for receiving all sorts of metallic colours, are composed of 47 parts of sulphate of barytes, 15 of felspar, 26 of Devonshire clay, 6 of sulphate of lime, 15 of flints, and 10 of sulphate of strontites. This composition is capable of receiving the tints of the metallic oxides and of the ochrous metallic earths. Manganese produces the dark purple colour; gold precipitated by tin, a rose colour; antimony, orange; cobalt, different shades of blue; copper is employed for the browns and the dead-leaf greens; nickel gives, with potash, greenish colours.
One per cent. of oxide of cobalt is added; but one half, or even one quarter, of a per cent. would be sufficient, to produce the fine Wedgewood blue, when the nickel and manganese constitute 3 per cent. as well as the carbonate of iron. For the blacks of this kind, some English manufacturers mix black oxide of manganese with the black oxide of iron, or with ochre. Nickel and umber afford a fine brown. Carbonate of iron, mixed with bole or terra di Sienna, gives a beautiful tint to the paste; as also manganese with cobalt, or cobalt with nickel. Antimony produces a very fine colour when combined with the carbonate of iron in the proportion of 2 per cent., along with the ingredients necessary to form the above-described vitrifying paste.
The following is another vitrifying paste, of a much softer nature than the preceding. Felspar, 30 parts; sulphate of lime, 23; silex, 17; potter’s clay, 15; kaolin of Cornwall (china clay), 15; sulphate of baryta, 10.
These vitrifying pastes are very plastic, and may be worked with as much facility as English pipe-clay. The round ware is usually turned upon the lathe. It may, however, be moulded, as the oval pieces always are. The more delicate ornaments are cast in hollow moulds of baked clay, by women and children, and applied with remarkable dexterity upon the turned and moulded articles. The coloured pastes have such an affinity for each other, that the detached ornaments may be applied not only with a little gum water upon the convex and concave forms, but they may be made to adhere without experiencing the least cracking or chinks. The coloured pastes receive only one fire, unless the inner surface is to be glazed; but a gloss is given to the outer surface. The enamel for the interior of the black Wedgewood ware, is composed of 6 parts of red lead, 1 of silex, and 2 ounces of manganese, when the mixture is made in pounds’ weight.
The operation called smearing, consists in giving an external lustre to the unglazed semi-vitrified ware. The articles do not in this way receive any immersion, nor even the aid of the brush or pencil of the artist; but they require a second fire. The saggers are coated with the salt glaze already described. These cases, or saggers, communicate by reverberation the lustre so remarkable on the surface of the English stoneware; which one might suppose to be the result of the glaze tub, or of the brush. Occasionally also a very fusible composition is thrown upon the inner surface of the muffle, and 5 or 6 pieces called refractories are set in the middle of it, coated with the same composition. The intensity of the heat converts the flux into vapour; a part of this is condensed upon the surfaces of the contiguous articles, so as to give them the desired brilliancy.
Mortar body, is a paste composed of 6 parts of clay, 3 of felspar, 2 of silex, and 1 of china clay.
White and yellow figures upon dark-coloured grounds are a good deal employed. To produce yellow impressions upon brown stoneware, ochre is ground up with a small quantity of antimony. The flux consists of flint glass and flints in equal weights. The composition for white designs is made by grinding silex up with that flux, and printing it on, as for blue colours, upon brown or other coloured stoneware, which shows off the light hues.
English porcelain or china.—Most of this belongs to the class called tender or soft porcelain by the French and German manufacturers. It is not, therefore, composed simply of kaolin and petuntse. The English china is generally baked at a much lower heat than that of Sèvres, Dresden, and Berlin; and it is covered with a mere glass. Being manufactured upon a prodigious scale, with great economy and certainty, and little expenditure of fuel, it is sold at a very moderate price compared with the foreign porcelain, and in external appearance is now not much inferior.
Some of the English porcelain has been called ironstone china. This is composed usually of 60 parts of Cornish stone, 40 of china clay, and 2 of flint glass; or of 42 of the felspar, the same quantity of clay, 10 parts of flints ground, and 8 of flint glass.
The glaze for the first composition is made with 20 parts of felspar, 15 of flints, 6 of red lead, and 5 of soda, which are fritted together; with 44 parts of the frit, 22 parts of flint glass, and 15 parts of white lead, are ground.
The glaze for the second composition is formed of 8 parts of flint glass, 36 of felspar, 40 of white lead, and 20 of silex (ground flints).
The English manufacturers employ three sorts of compositions for the porcelain biscuit; namely, two compositions not fritted; one of them for the ordinary table service; another for the dessert service and tea dishes; the third, which is fritted, corresponds to the paste used in France for sculpture; and with it all delicate kinds of ornaments are made.
First
composition. Second
composition. Third
composition.
Ground flints 75 66 Lynn sand 150
Calcined bones 180 100 300
China clay 40 96 100
Clay 70 Granite 80 Potash 10
The glaze for the first two of the preceding compositions consists of, felspar 45, flints 9, borax 21, flint glass 20, nickel 4. After fritting that mixture, add 12 parts of red lead. For the third composition, which is the most fusible, the glaze must receive 12 parts of ground flints, instead of 9; and there should be only 15 parts of borax, instead of 21.
PLAN OF AN ENGLISH POTTERY.
A stoneware manufactory should be placed by the side of a canal or navigable river, because the articles manufactured do not well bear land carriage.
A Staffordshire pottery is usually built as a quadrangle, each side being about 100 feet long, the walls 10 feet high, and the ridge of the roof 5 feet more. The base of the edifice consists of a bed of bricks, 18 inches high, and 16 inches thick; upon which a mud wall in a wooden frame, called pisé, is raised. Cellars are formed in front of the buildings, as depôts for the pastes prepared in the establishment. The wall of the yard or court is 9 feet high, and 18 inches thick.
Fig. 899. A, is the entrance door; B, the porter’s lodge; C, a particular warehouse; D, workshop of the plaster-moulder; E, the clay depôt; F, F, large gates, 6 feet 8 inches high; G, the winter evaporation stove; H, the shop for sifting the paste liquors; I, sheds for the paste liquor tubs; J, paste liquor pits; K, workshop for the moulder of hollow ware; L, ditto of the dish or plate moulder; M, the plate drying-stove; N, workshop of the biscuit-printers; O, ditto of the biscuit, with o′, a long window; P, passage leading to the paste liquor pits; Q, biscuit warehouse; R, place where the biscuit is cleaned as it comes out of the biscuit kilns, S S; T, T, enamel or glaze kilns; U, long passage; V, space left for supplementary workshops; X, space appointed as a depôt for the sagger fire-clay, as also for making the saggers; Z, the workshop for applying the glaze liquor to the biscuits; a, apartment for cleaning the glazed ware; b, b, pumps; c, basin; d, muffles; e, warehouse for the finished stoneware; f, that of the glazed goods; g, g, another warehouse; h, a large space for the smith’s forge, carpenter’s shop, packing room, depôt of clays, saggers, &c. The packing and loading of the goods are performed in front of the warehouse, which has two outlets, in order to facilitate the work; i, a passage to the court or yard; l, a space for the wooden sheds for keeping hay, clay, and other miscellaneous articles, m, room for putting the biscuit into the saggers; m′, a long window; n, workshop with lathes and fly-wheels; o, drying-room; p, room for mounting or furnishing the pieces; q, repairing room; r, drying room of the goods roughly turned; s, rough turning or blocking-out room; t, room for beating the paste or dough; u, counting-house.
The declared value of the earthenware exported in 1836, was 837,774l.; in 1837, 558,682l.
There are from 33,000 to 35,000 tons of clay exported annually from Poole, in Dorsetshire, to the English and Scotch potteries. A good deal of clay is also sent from Devonshire and Cornwall.
The Spanish alcarazzas, or cooling vessels, are made porous, to favour the exudation of water through them, and maintain a constantly moist evaporating surface. Lasteyrie says, that granular sea salt is an ingredient of the paste of the Spanish alcarazzas; which being expelled partly by the heat of the baking, and partly by the subsequent watery percolation, leaves the body very open. The biscuit should be charged with a considerable proportion of sand, and very moderately fired.
OF PORCELAIN.
Porcelain is a kind of pottery ware whose paste is fine grained, compact, very hard, and faintly translucid; and whose biscuit softens slightly in the kiln. Its ordinary whiteness cannot form a definite character, since there are porcelain pastes variously coloured. There are two species of porcelain, very different in their nature, the essential properties of which it is of consequence to establish; the one is called hard, and the other tender; important distinctions, the neglect of which has introduced great confusion into many treatises on this elegant manufacture.
Hard porcelain is essentially composed, first, of a natural clay containing some silica, infusible, and preserving its whiteness in a strong heat; this is almost always a true kaolin; secondly, of a flux, consisting of silica and lime, composing a quartzose felspar rock, called pe-tun-tse. The glaze of this porcelain, likewise earthy, admits of no metallic substance or alkali.
Tender porcelain, styled also vitreous porcelain, has no relation with the preceding in its composition; it always consists of a vitreous frit, rendered opaque and less fusible by the addition of a calcareous or marly clay. Its glaze is an artificial glass or crystal, into which silica, alkalis, and lead enter.
This porcelain has a more vitreous biscuit, more transparent, a little less hard, and less fragile, but much more fusible than that of the hard porcelain. Its glaze is more glossy, more transparent, a little less white, much tenderer, and more fusible.
The biscuit of the hard porcelain made at the French national manufactory of Sèvres is generally composed of a kaolin clay, and of a decomposed felspar rock; analogous to the china clay of Cornwall, and Cornish stone. Both of the above French materials come from Saint Yriex-la-perche, near Limoges.
After many experiments, the following composition has been adopted for the service paste of the royal manufactory of Sèvres; that is, for all the ware which is to be glazed: silica, 59; alumina, 35·2; potash, 2·2; lime, 3·3. The conditions of such a compound are pretty nearly fulfilled by taking from 63 to 70 of the washed kaolin or china clay, 22 to 15 of the felspar; nearly 10 of flint powder, and about 5 of chalk. The glaze is composed solely of solid felspar, calcined, crushed, and then ground fine at the mill. This rock pretty uniformly consists of silica 73, alumina 16·2, potash 8·4, and water 0·6.
The kaolin is washed at the pit, and sent in this state to Sèvres, under the name of decanted earth. At the manufactory it is washed and elutriated with care; and its slip is passed through fine sieves. This forms the plastic, infusible, and opaque ingredient to which the substance must be added which gives it a certain degree of fusibility and semi-transparency. The felspar rock used for this purpose, should contain neither dark mica nor iron, either as an oxide or sulphuret. It is calcined to make it crushable, under stamp-pestles driven by machinery, then ground fine in hornstone mills, as represented in figs. 897, , , and 900. This pulverulent matter being diffused through water, is mixed in certain proportions, regulated by its quality, with the argillaceous slip. The mixture is deprived of the chief part of its water in shallow plaster pans without heat; and the resulting paste is set aside to ripen, in damp cellars, for many months.
When wanted for use, it is placed in hemispherical pans of plaster, which absorb the redundant moisture; after which it is divided into small lumps, and completely dried. It is next pulverized, moistened a little, and laid on a floor, and trodden upon by a workman marching over it with bare feet in every direction; the parings and fragments of soft moulded articles being intermixed, which improve the plasticity of the whole. When sufficiently tramped, it is made up into masses of the size of a man’s head, and kept damp till required.
The dough is now in a state fit for the potter’s lathe; but it is much less plastic than stoneware paste, and is more difficult to fashion into the various articles; and hence one cause of the higher price of porcelain.
The round plates and dishes are shaped on plaster moulds; but sometimes the paste is laid on as a crust, and at others it is turned into shape on the lathe. When a crust is to be made, a moistened sheep-skin is spread on a marble table; and over this the dough is extended with a rolling pin, supported on two guide-rules. The crust is then transferred over the plaster mould, by lifting it upon the skin; for it wants tenacity to bear raising by itself. When the piece is to be fashioned on the lathe, a lump of the dough is thrown on the centre of the horizontal wooden disc, and turned into form as directed in treating of stoneware, only it must be left much thicker than in its finished state. After it dries to a certain degree on the plaster mould, the workman replaces it on the lathe, by moistening it on its base with a wet sponge, and finishes its form with an iron tool. A good workman at Sèvres makes no more than from 15 to 20 porcelain plates in a day; whereas an English potter, with two boys, makes from 1000 to 1200 plates of stoneware in the same time. The pieces which are not round, are shaped in plaster moulds, and finished by hand. When the articles are very large, as wash-hand basins, salads, &c., a flat cake is spread above a skin on the marble slab, which is then applied to the mould with the sponge, as for plates; and they are finished by hand.
The projecting pieces, such as handles, beaks, spouts, and ornaments, are moulded and adjusted separately; and are cemented to the bodies of china-ware with slip, or porcelain dough thinned with water. In fact, the mechanical processes with porcelain and the finer stoneware are substantially the same; only they require more time and greater nicety. The least defect in the fabrication, the smallest bit added, an unequal pressure, the cracks of the moulds, although well repaired, and seemingly effaced in the clay shape, re-appear after it is baked. The articles should be allowed to dry very slowly; if hurried but a little, they are liable to be spoiled. When quite dry, they are taken to the kiln.
The kiln for hard porcelain at Sèvres, is a kind of tower in two flats, constructed of fire-bricks; and resembles, in other respects, the stoneware kiln already figured and described. The fuel is young aspin wood, very dry, and cleft very small; it is put into the apertures of the four outside furnaces or fire-mouths, which discharge their flame into the inside of the kiln; each floor being closed in above, by a dome pierced with holes. The whole is covered in by a roof with an open passage, placed at a proper distance from the uppermost dome. There is, therefore, no chimney proper so called. See Stone, artificial.
The raw pieces are put into the upper floor of the kiln; where they receive a heat of about the 60th degree of Wedgewood’s pyrometer, and a commencement of baking, which, without altering their shape, or causing a perceptible shrinking of their bulk, makes them completely dry, and gives them sufficient solidity to bear handling. By this preliminary baking, the clay loses its property of forming a paste with water; and the pieces become fit for receiving the glazing coat, as they may be dipped in water without risk of breakage.
The glaze of hard porcelain is a felspar rock: this being ground to a very fine powder, is worked into a paste with water mingled with a little vinegar. All the articles are dipped into this milky liquid for an instant; and as they are very porous, they absorb the water greedily, whereby a layer of the felspar glaze is deposited on their surface, in a nearly dry state, as soon as they are lifted out. Glaze-pap is afterwards applied with a hair brush to the projecting edges, or any points where it had not taken; and the powder is then removed from the part on which the article is to stand, lest it should get fixed to its support in the fire. After these operations it is replaced in the kiln, to be completely baked.
The articles are put into saggers, like those of fine stoneware; and this operation is one of the most delicate and expensive in the manufacture of porcelain. The saggers are made of the plastic or potter’s clay of Abondant, to which about a third part of cement of broken saggers has been added.
As the porcelain pieces soften somewhat in the fire, they cannot be set above each other, even were they free from glaze; for the same reason, they cannot be baked on tripods, several of them being in one case, as is done with stoneware. Every piece of porcelain requires a sagger for itself. They must, moreover, be placed on a perfectly flat surface, because in softening they would be apt to conform to the irregularities of a rough one. When therefore any piece, a soup plate for example, is to be saggered, there is laid on the bottom of the case a perfectly true disc or round cake of stoneware, made of the sagger material, and it is secured in its place on three small props of a clay-lute, consisting of potter’s clay mixed with a great deal of sand. When the cake is carefully levelled, it is moistened, and dusted over with sand, or coated with a film of fire-clay slip, and the porcelain is carefully set on it. The sand or fire-clay hinders it from sticking to the cake. Several small articles may be set on the same cake, provided they do not touch one another.
The saggers containing the pieces thus arranged, are piled up in the kiln over each other, in the columnar form, till the whole space be occupied; leaving very moderate intervals between the columns to favour the draught of the fires. The whole being arranged with these precautions, and several others, too minute to be specified here, the door of the kiln is built up with 3 rows of bricks, leaving merely an opening 8 inches square, through which there is access to a sagger with the nearest side cut off. In this sagger are put fragments of porcelain intended to be withdrawn from time to time, in order to judge of the progress of the baking. These are called time-pieces or watches (montres). This opening into the watches is closed by a stopper of stoneware.
The firing begins by throwing into the furnace-mouths some pretty large pieces of white wood, and the heat is maintained for about 15 hours, gradually raising it by the addition of a larger quantity of the wood, till at the end of that period the kiln has a cherry-red colour within. The heat is now greatly increased by the operation termed covering the fire. Instead of throwing billets vertically into the four furnaces, there is placed horizontally on the openings of these furnaces, aspin wood of a sound texture, cleft small, laid in a sloping position. The brisk and long flame which it yields dips into the tunnels, penetrates the kiln, and circulates round the sagger-piles. The heat augments rapidly, and, at the end of 13 or 15 hours of this firing, the interior of the kiln is so white, that the watches can hardly be distinguished. The draught, indeed, is so rapid at this time, that one may place his hand on the slope of the wood without feeling incommoded by the heat. Every thing is consumed, no small charcoal remains, smoke is no longer produced, and even the wood-ash is dissipated. It is obvious that the kiln and the saggers must be composed of a very refractory clay, in order to resist such a fire. The heat in the Sèvres kilns mounts so high as the 134th degree of Wedgewood.
At the end of 15 or 20 hours of the great fire; that is, after from 30 to 36 hours’ firing, the porcelain is baked; as is ascertained by taking out and examining the watches. The kiln is suffered to cool during 3 or 4 days, and is then opened and discharged. The sand strewed on the cakes to prevent the adhesion of the articles to them, gets attached to their sole, and is removed by friction with a hard sandstone; an operation which one woman can perform for a whole kiln in less than 10 days; and is the last applied to hard porcelain, unless it needs to be returned into the hot kiln to have some defects repaired.
The materials of fine porcelain are very rare; and there would be no advantage in making a gray-white porcelain with coarser and somewhat cheaper materials, for the other sources of expense above detailed, and which are of most consequence, would still exist; while the porcelain, losing much of its brightness, would lose the main part of its value.
Its pap or dough, which requires tedious grinding and manipulation, is also more difficult to work into shapes, in the ratio of 80 to 1, compared to fine stoneware. Each porcelain plate requires a separate sagger; so that 12 occupy in the kiln a space sufficient for at least 38 stoneware plates. The temperature of a hard porcelain kiln being very high, involves a proportionate consumption of fuel and waste of saggers. With 40 steres (cubic metres) of wood, 12,000 stoneware plates may be completely fired, both in the biscuit and glaze kilns; while the same quantity of wood would bake at most only 1000 plates of porcelain.
To these causes of high price, which are constant and essential, we ought to add the numerous accidents to which porcelain is exposed at every step of its preparation, and particularly in the kiln; these accidents damage upwards of one-third of the pieces, and frequently more, when articles of singular form and large dimensions are adventured.
The best English porcelain is made from a mixture of the Cornish kaolin (called china clay), ground flints, ground Cornish stone, and calcined bones in powder, or bone-ash, besides some other materials, according to the fancy of the manufacturers. A liquid pap is made with these materials, compounded in certain proportions, and diluted with water. The fluid part is then withdrawn by the absorbent action of dry stucco basins or pans. The dough, brought to a proper stiffness, and perfectly worked and kneaded on the principles detailed above, is fashioned on the lathe, by the hands of modellers, or by pressure in moulds. The pieces are then baked to the state of biscuit in a kiln, being enclosed, of course, in saggers.
This biscuit has the aspect of white sugar, and being very porous, must receive a vitreous coating. The glaze consists of ground felspar or Cornish stone. Into this, diffused in water, along with a little flint-powder and potash, the biscuit ware is dipped, as already described, under stoneware. The pieces are then fired in the glaze-kiln, care being taken, before putting them into their saggers, to remove the glaze powder from their bottom parts, to prevent their adhesion to the fire-clay vessel.
TENDER PORCELAIN.
Tender porcelain, or soft china-ware, is made with a vitreous frit, rendered less fusible and opaque by an addition of white marl or bone-ash. The frit is, therefore, first prepared. This, at Sèvres, is a composition, made with some nitre, a little sea salt, Alicant barilla, alum, gypsum, and much siliceous sand or ground flints. That mixture is subjected to an incipient pasty fusion in a furnace, where it is stirred about to blend the materials well; and thus a very white spongy frit is obtained. It is pulverized, and to every three parts of it, one of the white marl of Argenteuil is added; and when the whole are well ground, and intimately mixed, the paste of tender porcelain is formed.
As this paste has no tenacity, it cannot bear working till a mucilage of gum or black soap be added, which gives it a kind of plasticity, though even then it will not bear the lathe. Hence it must be fashioned in the press, between two moulds of plaster. The pieces are left thicker than they should be; and when dried, are finished on the lathe with iron tools.
In this state they are baked, without any glaze being applied; but as this porcelain softens far more during the baking than the hard porcelain, it needs to be supported on every side. This is done by baking on earthen moulds all such pieces as can be treated in this way, namely plates, saucers, &c. The pieces are reversed on these moulds, and undergo their shrinkage without losing their form. Beneath other articles, supports of a like paste are laid, which suffer in baking the same contraction as the articles, and of course can serve only once. In this operation saggers are used, in which the pieces and their supports are fired.
The kiln for the tender porcelain at Sèvres is absolutely similar to that for the common stoneware; but it has two floors; and while the biscuit is baked in the lower story, the glaze is fused in the upper one; which causes considerable economy of fuel. The glaze of soft porcelain is a species of glass or crystal prepared on purpose. It is composed of flint, siliceous sand, a little potash or soda, and about two-fifth parts of lead oxide. This mixture is melted in crucibles or pots beneath the kiln. The resulting glass is ground fine, and diffused through water mixed with a little vinegar to the consistence of cream. All the pieces of biscuit are covered with this glazy matter, by pouring this slip over them, since their substance is not absorbent enough to take it on by immersion.
The pieces are encased once more each in a separate sagger, but without any supports; for the heat of the upper floor of the kiln, though adequate to melt the glaze, is not strong enough to soften the biscuit. But as this first vitreous coat is not very equal, a second one is applied, and the pieces are returned to the kiln for the third time. See Stone, artificial, for a view of this kiln.
The manufacture of soft porcelain is longer and more difficult than that of hard; its biscuit is dearer, although the raw materials may be found every where; and it furnishes also more refuse. Many of the pieces split asunder, receive fissures, or become deformed in the biscuit-kiln, in spite of the supports; and this vitreous porcelain, moreover, is always yellower, more transparent, and incapable of bearing rapid transitions of temperature, so that even the heat of boiling water frequently cracks it. It possesses some advantages as to painting, and may be made so gaudy and brilliant in its decorations, as to captivate the vulgar eye.
DESCRIPTION OF THE PORCELAIN MILL.
1. The following figures of a felspar and flint mill are taken from plans of apparatus lately constructed by Mr. Hall of Dartford, and erected by him in the royal manufactory of Sèvres. There are two similar sets of apparatus, fig. 900., which may be employed together or in succession; composed each of an elevated tub A, and of three successive vats of reception A′, and two behind it, whose top edges are upon a lower level than the bottom of the casks A, A, to allow of the liquid running out of them with a sufficient slope. A proper charge of kaolin is first put into the cask A, then water is gradually run into it by the gutter adapted to the stopcock a, after which the mixture is agitated powerfully in every direction by hand with the stirring-bar, which is hung within a hole in the ceiling, and has at its upper end a small tin-plate funnel to prevent dirt or rust from dropping down into the clay. The stirrer may be raised or lowered so as to touch any part of the cask. The semi-fluid mass is left to settle for a few minutes, and then the finer argillaceous pap is run off by the stopcock a′, placed a little above the gritty deposit, into the zinc pipe which conveys it into one of the tubs A′; but as this semi-liquid matter may still contain some granular substances, it must be passed through a sieve before it is admitted into the tub. There is, therefore, at the spot upon the tub where the zinc pipe terminates, a wire-cloth sieve, of an extremely close texture, to receive the liquid paste. This sieve is shaken upon its support, in order to make it discharge the washed argillaceous kaolin. After the clay has subsided, the water is drawn off from its surface by a zinc syphon. The vats A′ have covers, to protect their contents from dust. In the pottery factories of England, the agitation is produced by machinery, instead of the hand. A vertical shaft, with horizontal or oblique paddles, is made to revolve in the vats for this purpose.
The small triturating mill is represented in fig. 901. There are three similar grinding-tubs on the same line. The details of the construction are shown in figs. 902, , where it is seen to consist principally of a revolving millstone B (fig. 902.), of a fast or sleeper millstone B′, and of a vat C, hooped with iron, with its top raised above the upper millstone. The lower block of hornstone rests upon a very firm basis, b′; it is surrounded immediately by the strong wooden circle c, which slopes out funnel-wise above, in order to throw back the earthy matters as they are pushed up by the attrition of the stones. That piece is hollowed out, partially to admit the key C, opposite to which is the faucet and spigot c′, for emptying the tub. When one operation is completed, the key C is lifted out by means of a peg put into the holes at its top; the spigot is then drawn, and the thin paste is run out into vats. The upper grindstone, B d, like the lower one, is about two feet in diameter, and must be cut in a peculiar manner. At first there is scooped out a hollowing in the form of a sector, denoted by d e f, fig. 903.; the arc d f is about one-sixth of the circumference, so that the vacuity of the turning grindstone is one-sixth of its surface; moreover, the stone must be channelled, in order to grind or crush the hard gritty substances. For this purpose, a wedge-shaped groove d e g, about an inch and a quarter deep, is made on its under face, whereby the stone, as it turns in the direction indicated by the arrow, acts with this inclined plane upon all the particles in its course, crushing them and forcing them in between the stones, till they be triturated to an impalpable powder. When the grindstone wears unequally on its lower surface, it is useful to trace upon it little furrows, proceeding from the centre to the circumference, like those shown by the dotted lines e′ e′′. It must, moreover, be indented with rough points by the hammer.
The turning hornstone-block is set in motion by the vertical shaft H, which is fixed by the clamp-iron cross I to the top of the stone. When the stone is new, its thickness is about 14 inches, and it is made to answer for grinding till it be reduced to about 8 inches, by lowering the clamp I upon the shaft, so that it may continue to keep its hold of the stone. The manner in which the grindstones are turned, is obvious from inspection of fig. 901., where the horizontal axis L, which receives its impulsion from the great water-wheel, turns the prolonged shaft L′, or leaves it at rest, according as the clutch l, l′, is locked or opened. This second shaft bears the three bevel wheels M, M, M. These work in three corresponding bevel wheels M′ M′ M′, made fast respectively to the three vertical shafts of the millstones, which pass through the cast-iron guide tubes M′′ M′′. These are fixed in a truly vertical position by the collar-bar m′′, m′, fig. 902. In this figure we see at m how the strong cross-bar of cast iron is made fast to the wooden beams which support all the upper mechanism of the mill-work. The bearing m′ is disposed in an analogous manner; but it is supported against two cast-iron columns, shown at L′′ L′′, in fig. 901. The guide tubes M′′ are bored smooth for a small distance from each of their extremities, and their interjacent calibre is wider, so that the vertical shafts touch only at two places. It is obvious, that whenever the shaft L′ is set a-going, it necessarily turns the wheels M and M′, and their guide tubes M′′; but the vertical shaft may remain either at rest, or revolve, according to the position of the lever click or catch K, at the top, which is made to slide upon the shaft, and can let fall a finger into a vertical groove cut in the surface of that shaft. The clamp-fork of the click is thus made to catch upon the horizontal bevel-wheel M′, or to release it, according as the lever K is lowered or lifted up. Thus each millstone may be thrown out of or into geer at pleasure.
These stones make upon an average 11 or 12 turns in a minute, corresponding to 3 revolutions of the water-wheel, which moves through a space of 3 feet 4 inches in the second, its outer circumference being 66 feet. The weight of the upper stone, with its iron mountings, is about 6 cwt., when new. The charge of each mill in dry material is 2 cwt.; and the water may be estimated at from one-half to the whole of this weight; whence the total load may be reckoned to be at least 3 cwt.; the stone, by displacement of the magma, loses fully 400 pounds of its weight, and weighs therefore in reality only 2 cwt. It is charged in successive portions, but it is discharged all at once. When the grinding of the siliceous or felspar matters is nearly complete, a remarkable phenomenon occurs; the substance precipitates to the bottom, and assumes in a few seconds so strong a degree of cohesion, that it is hardly possible to restore it again to the pasty or magma state; hence if a millstone turns too slowly, or if it be accidentally stopped for a few minutes, the upper stone gets so firmly cemented to the under one, that it is difficult to separate them. It has been discovered, but without knowing why, that a little vinegar added to the water of the magma almost infallibly prevents that sudden stiffening of the deposit and stoppage of the stones. If the mills come to be set fast in this way, the shafts or geering would be certainly broken, were not some safety provision to be made in the machinery against such accidents. Mr. Hall’s contrivance to obviate the above danger is highly ingenious. The clutch l, l′, fig. 901., is not a locking crab, fixed in the common way, upon the shaft L; but it is composed, as shown in figs. 904, , , , of a hoop u, fixed upon the shaft by means of a key, of a collar v, and of a flat ring or washer x, with four projections, which are fitted to the collar v, by four bolts y. Fig. 905. represents the collar v seen in front; that is, by the face which carries the clutch teeth; and fig. 906. represents its other face, which receives the flat ring x, fig. 907., in four notches corresponding to the four projections of the washer-ring. Since the ring u is fixed upon the shaft L, and necessarily turns with it, it has the two other pieces at its disposal, namely the collar v, and the washer x, because they are always connected with it by the four bolts y, so as to turn with the ring u, when the resistance they encounter upon the shaft L′ is not too great, and to remain at rest, letting the ring u turn by itself, when that resistance increases to a certain pitch. To give this degree of friction, we need only interpose the leather washers z, z′, fig. 904.; and now as the collar coupling-box, v, slides pretty freely upon the ring u, it is obvious that by tightening more or less the screw bolts y, these washers will become as it were a lateral brake, to tighten more or less the bearing of the ring u, to which they are applied: by regulating this pressure, every thing may be easily adjusted. When the resistance becomes too great, the leather washers, pressed upon one side by the collar v, of the washer x, and rubbed upon the other side by the prominence of the ring u, get heated to such a degree, that they are apt to become carbonized, and require replacement.
This safety clutch may be recommended to the notice of mechanicians, as susceptible of beneficial application in a variety of circumstances.
GREAT PORCELAIN MILL.
The large felspar and kaolin mill, made by Mr. Hall, for Sèvres, has a flat bed of hornstone, in one block, laid at the bottom of a great tub, hooped strongly with iron. In most of the English potteries, however, that bed consists of several flat pieces of chert or hornstone, laid level with each other. There is, as usual, a spigot and faucet at the side, for drawing off the liquid paste. The whole system of the mechanism is very substantial, and is supported by wooden beams.
The following is the manner of turning the upper blocks. In fig. 900. the main horizontal shaft P bears at one of its extremities a toothed wheel, usually mounted upon the periphery of the great water-wheel (fig. 908. shows this toothed wheel by a dotted line) at its other end; P carries the fixed portion p of a coupling-box, similar to the one just described as belonging to the little mill. On the prolongation of P, there is a second shaft P′, which bears the movable portion of that box, and an upright bevel wheel P′′. Lastly, in figs. 900. and 908. there is shown the vertical shaft Q, which carries at its upper end a large horizontal cast-iron wheel Q′, not seen in this view, because it is sunk within the upper surface of the turning hornstone, like the clamp d, f, in fig. 902. At the lower end of the shaft Q, there is the bevel wheel Q′′, which receives motion from the wheel P′′, fig. 900.
The shaft P always revolves with the water-wheel; but transmits its motion to the shaft P′ only when the latter is thrown into geer with the coupling-box p′, by means of its forked lever. Then the bevel wheel P′ turns round with the shaft P′, and communicates its rotation to the bevel wheel Q′′, which transmits it to the shaft Q, and to the large cast-iron wheel, which is sunk into the upper surface of the revolving hornstone.
The shaft Q is supported and centred by a simple and solid adjustment; at its lower part, it rests in a step R, which is supported upon a cast-iron arch Q′, seen in profile in fig. 900.; its base is solidly fixed by four strong bolts. Four set screws above R, fig. 900., serve to set the shaft Q truly perpendicular: thus supported, and held securely at its lower end, in the step at R, figs. 900. and 908., it is embraced near the upper end by a brass bush or collar, composed of two pieces, which may be drawn closer together by means of a screw. This collar is set into the summit of a great truncated cone of cast-iron, which rises within the tub through two-thirds of the thickness of the hornstone bed; having its base firmly fixed by bolts to the bottom of the tub, and having a brass collet to secure its top. The iron cone is cased in wood. When all these pieces are well adjusted and properly screwed up, the shaft Q revolves without the least vacillation, and carries round with it the large iron wheel Q′, cast in one piece, and which consists of an outer rim, three arms or radii, and a strong central nave, made fast by a key to the top of the shaft Q, and resting upon a shoulder nicely turned to receive it. Upon each of the three arms, there are adjusted, with bolts, three upright substantial bars of oak, which descend vertically through the body of the revolving mill to within a small distance of the bed-stone; and upon each of the three arcs of that wheel-ring, comprised between its three strong arms, there are adjusted, in like manner, five similar uprights, which fit into hollows cut in the periphery of the moving stone. They ought to be cut to a level at their lower part, to suit the slope of the bottom of the tub o, figs. 900. and 908., so as to glide past it pretty closely, without touching.
The speed of this large mill is eight revolutions in the minute. The turning hornstone describes a mean circumference of 141⁄3 inches (its diameter being 45 inches), and of course moves through about 100 feet per second. The tub O, is 52 inches wide at bottom, 56 at the surface of the sleeper block (which is 16 inches thick), and 64 at top, inside measure. It sometimes happens that the millstone throws the pasty mixture out of the vessel, though its top is 6 inches under the lip of the tub o; an inconvenience which can be obviated only by making the pap a little thicker; that, is by allowing only from 25 to 30 per cent. of water; then its density becomes nearly equal to 2·00, while that of the millstones themselves is only 2·7; whence, supposing them to weigh only 2 cwt., there would remain an effective weight of less than ⁄2 cwt. for pressing upon the bottom and grinding the granular particles. This weight appears to be somewhat too small to do much work in a short time; and therefore it would be better to increase the quantity of water, and put covers of some convenient form over the tubs. It is estimated that this mill will grind nearly 5 cwt. of hard kaolin or felspar gravel, in 24 hours, into a proper pap.
To the preceding methodical account of the porcelain manufacture, I shall now subjoin some practical details relative to certain styles of work, with comparisons between the methods pursued in this country and upon the Continent, but chiefly by our jealous rivals the French.
The blue printed ware of England has been hitherto a hopeless object of emulation in France. M. Alexandre Brongniart, membre de l’Institut, and director of the Manufacture Royal de Sèvres, characterizes the French imitations of the Fayence fine, ou Anglaise, in the following terms: “Les défauts de cette poterie, qui tiennent à sa nature, sont de ne pouvoir aller sur le feu pour les usages domestiques, et d’avoir un vernis tendre, qui se laisse aisément entamer par les instruments d’acier et de fer. Mais lorsque cette poterie est mal fabriquée, ou fabriquée avec une économie mal entendue, ses défauts deviennent bien plus graves; son vernis jaunâtre et tendre tressaille souvent; il se laisse entamer ou user avec la plus grande facilité par les instruments de fer, ou par l’usage ordinaire. Les fissures que ce tressaillement ou ces rayures ouvrent dans le vernis permettent aux matières grasses de pénétrer dans le biscuit, que dans les poteries affectées de ce défaut, a presque toujours une texture lâche; les pièces se salissent, s’empuantissent, et se brisent même avec la plus grande facilité.”
What a glaze, to be scratched or grooved with soft iron; to fly off in scales, so as to let grease soak into the biscuit or body of the ware; to become foul, stink, and break with the utmost ease! The refuse crockery of the coarsest pottery works in the United Kingdom would hardly deserve such censure.
In the minutes of evidence of the Enquête Ministérielle, published in 1835, MM. de Saint Cricq and Lebeuf, large manufacturers of pottery-ware at Creil and Montereau, give a very gratifying account of the English stoneware manufacture. They declare that the English possess magnificent mines of potter’s clay, many leagues in extent; while those of the French are mere patches or pots. Besides, England, they say, having upwards of 200 potteries, can constantly employ a great many public flint-mills, and thereby obtain that indispensable material of the best quality, and at the lowest rate. “The mill erected by M. Brongniart, at Sèvres, does its work at twice the price of the English mills. The fuel costs in England one-fourth of what it does in France. The expense of a kiln-round, in the latter country, is 200 francs; while in the former it is not more than 60.” After a two-months tour among the English potteries, these gentlemen made the following additional observations to their first official statement:—
“The clay, which goes by water carriage from the counties of Devon and Dorset, into Staffordshire, to supply more than 200 potteries, clustered together, is delivered to them at a cost of 4 francs (3s. 2d.) the 100 kilogrammes (2 cwt.); at Creil, it costs 4f. 50c., and at Montereau, only 2f. 40c. There appears, therefore, to be no essential difference in the price of the clay; but the quality of the English is much superior, being incontestably whiter, purer, more homogeneous, and not turning red at a high heat, like the French.” The grinding of the flints costs the English potter 4⁄2d. per 100 kilos., and the French 6d.; but as that of the latter is in general ground dry, it is a coarser article. The kaolin, or china clay, is imported from Cornwall for the use of many French potteries; but the transport of merchandise is so ill managed in France, that while 2 cwts. cost in Staffordshire only 8f. 75c. (about 7s. 1d.), they cost 12f. at Creil, and 13f. 50c. at Montereau. The white lead and massicot, so much employed for glazes, are 62 per cent. dearer to the French potters than the English. As no French mill has succeeded in making unsized paper fit for printing upon stoneware, our potters are under the necessity of fetching it from England; and, under favour of our own custom-house, are allowed to import it at a duty of 165f. per 100 kilogrammes, or about 8d. per pound English. No large stock of materials need be kept by the English, because every article may be had when wanted from its appropriate wholesale dealers; but the case is quite different with the French, whose stocks, even in small works, can never safely be less in value than 150,000f. or 200,000f.; constituting a loss to them, in interest upon their capital, of from 7,500f. to 10,000f. per annum. The capital sunk in buildings is far less in England than in France, in consequence of the different styles of erecting stoneware factories in the two countries. M. de Saint Cricq informs us, that Mr. Clewes, of Shelton, rents his works for 10,000f. (380l.) per annum; while the similar ones of Creil and Montereau, in France, have cost each a capital outlay of from 500,000f. to 600,000f., and in which the products are not more than one half of Mr. Clewes’. “This forms a balance against us,” says M. St. C., “of about 20,000f. per annum; or nearly 800l. sterling. Finally, we have the most formidable rival to our potteries in the extreme dexterity of the English artisans. An enormous fabrication permits the manufacturers to employ the same workmen during the whole year upon the same piece; thus I have seen at Shelton a furnisher, for sixpence, turn off 100 pieces, which cost at Creil and Montereau 30 sous (1s. 2⁄2d.); yet the English workman earns 18f. 75c. a week, while the French never earns more than 15f. I have likewise seen an English moulder expert enough to make 25 waterpots a day, which, at the rate of 2d. a piece, bring him 4s. 2d. of daily wages; while the French moulder, at daily wages also of 4s. 2d., turns out of his hands only 7, or at most 8 pots. In regard to hollow wares, the English may be fairly allowed to have an advantage over us, in the cost of labour, of 100 per cent.; which they derive from the circumstance, that there are in Staffordshire 60,000 operatives, men, women, and children, entirely dedicated to the stoneware manufacture; concentrating all their energies within a space of 10 square leagues. Hence a most auspicious choice of good practical potters, which cannot be found in France.”
M. Saint Amans, a French gentleman, who spent some years in Staffordshire, and has lately erected a large pottery in France, says the English surpass all other nations in manufacturing a peculiar stoneware, remarkable for its lightness, strength, and elegance; as also in printing blue figures upon it of every tint, equal to that of the Chinese, by processes of singular facility and promptitude. After the biscuit is taken out of the kiln, the fresh impression of the engraving is transferred to it from thin unsized paper, previously immersed in strong soap water; the ink for this purpose being a compound of arseniate of cobalt with a flux, ground up with properly boiled linseed oil. The copper-plates are formed by the graving tool with deeper or shallower lines according to the variable depth of shades in the design. The cobalt pigment, on melting, spreads so as to give the soft effect of water-colour drawing. The paper being still moist, is readily applied to the slightly rough and adhesive surface of the biscuit, and may be rubbed on more closely by a dossil of flannel. The piece is then dipped in a tub of water, whereby the paper gets soft, and may be easily removed, leaving upon the pottery the pigment of the engraved impression. After being gently dried, the piece is dipped into the glaze mixture, and put into the enamel oven.
Composition of the Earthy Mixtures.
The basis of the English stoneware is, as formerly stated, a bluish clay, brought from Dorsetshire and Devonshire, which lies at the depth of from 25 to 30 feet beneath the surface. It is composed of about 24 parts of alumina, and 76 of silica, with some other ingredients in very small proportions. This clay is very refractory in high heats, a property which, joined to its whiteness when burned, renders it peculiarly valuable for pottery. It is also the basis of all the yellow biscuit-ware called cream colour, and in general of what is called the printing body; as also for the semi-vitrified porcelain of Wedgewood’s invention, and of the tender porcelain.
The constituents of the stoneware are, that clay, the powder of calcined flints, and of the decomposed felspar called Cornish stone. The proportions are varied by the different manufacturers. The following are those generally adopted in one of the principal establishments of Staffordshire:—
For cream colour, Silex or ground flints 20 parts.
Clay 100
Cornish stone 2
Composition of the Paste for receiving the Printing Body under the Glaze.
For this purpose the proportions of the flint and the felspar must be increased. The substances are mixed separately with water into the consistence of a thick cream, which weighs per pint, for the flints 32 ounces, and for the Cornish stone 28. The china clay of Cornwall is added to the same mixture of flint and felspar, when a finer pottery or porcelain is required. That clay cream weighs 24 ounces per pint. These 24 ounces in weight are reduced to one-third of their bulk by evaporation. The pint of dry Cornish clay weighs 17 ounces, and in its first pasty state 24, as just stated. The dry flint powder weighs 14⁄2 ounces per pint; which when made into a cream weighs 32 ounces. To 40 measures of Devonshire clay-cream there are added,
13 measures of flint liquor.
12 — Cornish clay ditto.
1 — Cornish stone ditto.
The whole are well mixed by proper agitation, half dried in the troughs of the slip-kiln, and then subjected to the machine for cutting up the clay into junks. The above paste, when baked, is very white, hard, sonorous, and susceptible of receiving all sorts of impressions from the paper engravings. When the silica is mixed with the alumina in the above proportions, it forms a compact ware, and the impression remains fixed between the biscuit and the glaze, without communicating to either any portion of the tint of the metallic colour employed in the engraver’s press. The felspar gives strength to the biscuit, and renders it sonorous after being baked; while the china clay has the double advantage of imparting an agreeable whiteness and great closeness of grain.
PRECIPITATE, is any matter separated in minute particles from the bosom of a fluid, which subsides to the bottom of the vessel in a pulverulent form.
PRECIPITATION, is the actual subsidence of a precipitate.
PRESS, HYDRAULIC. Though the explanation of the principles of this powerful machine belongs to a work upon mechanical engineering, rather than to one upon manufactures, yet as it is often referred to in this volume, a brief description of it cannot be unacceptable to many of my readers.
The framing consists of two stout cast-iron plates a, b, which are strengthened by projecting ribs, not seen in the section, fig. 909. The top or crown plate b, and the base-plate a, a, are bound most firmly together by 4 cylinders of the best wrought iron, c, c, which pass up through holes near the ends of the said plates, and are fast wedged in them. The flat pieces e, e, are screwed to the ends of the crown and base plates, so as to bind the columns laterally. f, is the hollow cylinder of the press, which, as well as the ram g, is made of cast iron. The upper part of the cavity of the cylinder is cast narrow, but is truly and smoothly rounded at the boring-mill, so as to fit pretty closely round a well-turned ram or piston; the under part of it is left somewhat wider in the casting. A stout cup of leather, perforated in the middle, is put upon the ram, and serves as a valve to render the neck of the cylinder perfectly water-tight, by filling up the space between it and the ram; and since the mouth of the cup is turned downwards, the greater the pressure of water upwards, the more forcibly are the edges of the leather valve pressed against the inside of the cylinder, and the tighter does the joint become. This was Bramah’s beautiful invention.
Upon the top of the ram, the press-plate or table, strengthened with projecting ridges, rests, which is commonly called the follower, because it follows the ram closely in its descent. This plate has a half-round hole at each of its four corners, corresponding to the shape of the four iron columns along which it glides in its up-and-down motions of compression and relaxation.
k, k, figs. 909. and 910., is the framing of a force pump with a narrow barrel; i is the well for containing water to supply the pump. To spare room in the engraving, the pump is set close to the press, but it may be removed to any convenient distance by lengthening the water-pipe u, which connects the discharge of the force pump with the inside of the cylinder of the press. Fig. 911. is a section of the pump and its valves. The pump m, is of bronze; the suction-pipe n, has a conical valve with a long tail; the solid piston or plunger p, is smaller than the barrel in which it plays, and passes at its top through a stuffing-box q; r is the pressure-valve, s is the safety-valve, which, in fig. 910., is seen to be loaded with a weighted lever; t is the discharge-valve, for letting the water escape, from the cylinder beneath the ram, back into the well. See the winding passages in fig. 912. u is the tube which conveys the water from the pump into the press-cylinder. In fig. 910. two centres of motion for the pump-lever are shown. By shifting the bolt into the centre nearest the pump-rod, the mechanical advantage of the workman may be doubled. Two pumps are generally mounted in one frame for one hydraulic press; the larger to give a rapid motion to the ram at the beginning, when the resistance is small; the smaller to give a slower but more powerful impulsion, when the resistance is much increased. A pressure of 500 tons may be obtained from a well-made hydraulic press with a ten-inch ram, and a two and a one inch set of pumps. See Stearine Press.
PRINCE’S METAL, or Prince Rupert’s metal, is a modification of brass.
PRINTING INK. (Encre d’imprimerie, Fr.; Buchdruckerfarbe, Germ.) After reviewing the different prescriptions given by Moxon, Breton, Papillon, Lewis, those in Nicholson’s and the Messrs. Aikins’ Dictionaries, in Rees’ Cyclopædia, and in the French Printer’s Manual, Mr. Savage says, that the Encyclopædia Britannica is the only work, to his knowledge, which has given a recipe by which a printing ink might be made, that could be used, though it would be of inferior quality, as acknowledged by the editor; for it specifies neither the qualities of the materials, nor their due proportions. The fine black ink made by Mr. Savage, has, he informs us, been pronounced by some of our first printers to be unrivalled; and has procured for him the large medal from the Society for the Encouragement of Arts.
1. Linseed oil.—Mr. S. says, that the linseed oil, however long boiled, unless set fire to, cannot be brought into a proper state for forming printing ink; and that the flame may be most readily extinguished by the application of a pretty tight tin cover to the top of the boiler, which should never be more than half full. The French prefer nut oil to linseed; but if the latter be old, it is fully as good, and much cheaper, in this country at least.
2. Black rosin is an important article in the composition of good ink; as by melting it in the oil, when that ingredient is sufficiently boiled and burnt, the two combine, and form a compound approximating to a natural balsam, like that of Canada, which is itself one of the best varnishes that can be used for printing ink.
3. Soap.—This is a most important ingredient in printer’s ink, which is not even mentioned in any of the recipes prior to that in the Encyclopædia Britannica. For want of soap, ink accumulates upon the face of the types, so as completely to clog them up after comparatively few impressions have been taken; it will not wash off without alkaline lyes, and it skins over very soon in the pot. Yellow rosin soap is the best for black inks; for those of light and delicate shades, white curd soap is preferable. Too much soap is apt to render the impression irregular, and to prevent the ink from drying quickly. The proper proportion has been hit, when the ink works clean, without clogging the surface of the types.
4. Lamp black.—The vegetable lamp black, sold in firkins, takes by far the most varnish, and answers for making the best ink. See Black.
5. Ivory black is too heavy to be used alone as a pigment for printing ink; but it may be added with advantage by grinding a little of it upon a muller with the lamp black, for certain purposes; for instance, if an engraving on wood is required to be printed so as to produce the best possible effect.
6. Indigo alone, or with an equal weight of prussian blue, added in small proportion, takes off the brown tone of certain lamp-black inks. Mr. Savage recommends a little Indian red to be ground in with the indigo and prussian blue, to give a rich tone to the black ink.
7. Balsam of capivi, as sold by Mr. Allen, Plough-court, Lombard-street, mixed, by a stone and a muller, with a due proportion of soap and pigment, forms an extemporaneous ink, which the printer may employ very advantageously when he wishes to execute a job in a peculiarly neat manner. Canada balsam does not answer quite so well.
After the smoke begins to rise from the boiling oil, a bit of burning paper stuck in the cleft end of a long stick, should be applied to the surface, to set it on fire, as soon as the vapour will burn; and the flame should be allowed to continue (the pot being meanwhile removed from over the fire, or the fire taken from under the pot,) till a sample of the varnish, cooled upon a pallet-knife, draws out into strings of about half an inch long between the fingers. To six quarts of linseed oil thus treated, six pounds of rosin should be gradually added, as soon as the froth of the ebullition has subsided. Whenever the rosin is dissolved, one pound and three quarters of dry brown soap, of the best quality, cut into slices, is to be introduced cautiously, for its water of combination causes a violent intumescence. Both the rosin and soap should be well stirred with the spatula. The pot is to be now set upon the fire, in order to complete the combination of all the constituents.
Put next of well ground indigo and prussian blue, each 2⁄2 ounces, into an earthen pan, sufficiently large to hold all the ink, along with 4 pounds of the best mineral lamp black, and 3⁄2 pounds of good vegetable lamp black; then add the warm varnish by slow degrees, carefully stirring, to produce a perfect incorporation of all the ingredients. This mixture is next to be subjected to a mill, or slab and muller, till it be levigated into a smooth uniform paste.
One pound of a superfine printing ink may be made by the following recipe of Mr. Savage:—Balsam of capivi, 9 oz.; lamp black, 3 oz.; indigo and prussian blue, together, p. æq. 1⁄4 oz.; Indian red, ⁄4 oz.; turpentine (yellow) soap, dry, 3 oz. This mixture is to be ground upon a slab, with a muller, to an impalpable smoothness. The pigments used for coloured printing inks are, carmine, lakes, vermillion, red lead, Indian red, Venetian red, chrome yellow, chrome red or orange, burnt terra di Sienna, gall-stone, Roman ochre, yellow ochre, verdigris, blues and yellows mixed for greens, indigo, prussian blue, Antwerp blue, lustre, umber, sepia, browns mixed with Venetian red, &c.
PRINTING MACHINE. (Typographie mécanique, Fr.; Druckmaschine, Germ.) In reviewing those great eras of national industry, when the productive arts, after a long period of irksome vassalage, have suddenly achieved some new conquest over the inertia of matter, the contemplative mind cannot fail to be struck with the insignificant part which the academical philosopher has generally played in such memorable events.
Engrossed with barren syllogisms, or equational theorems, often little better than truisms in disguise, he nevertheless believes in the perfection of his attainments, and disdains to soil his hands with those handicraft operations at which all improvements in the arts must necessarily begin. He does not deem manufacture worthy of his regard, till it has worked out its own grandeur and independence with patient labour and consummate skill. In this spirit the men of speculative science neglected for 60 years the steam engine of Newcomen, till the artisan Watt transformed it into an automatic prodigy; they have never deigned to illustrate by dynamical investigations the factory mechanisms of Arkwright, yet nothing in the whole compass of art deserves it so well; and though perfectly aware that revolvency is the leading law in the system of the universe, they have never thought of showing the workman that this was also the true principle of every automatic machine.
These remarks seem to be peculiarly applicable to book-printing, an art invented for the honour of learning and the glory of the learned, though they have done nothing for its advancement; yet by the overruling bounty of Providence it has eventually served as the great teacher and guardian of the whole family of man.
It has been justly observed by Mr. Cowper, in his ingenious lecture, that no improvement had been introduced in this important art, from its invention till the year 1798, a period of nearly 350 years. In Dr. Dibdin’s interesting account of printing, in the Bibliographical Decameron, may be seen representations of the early printing-presses, which exactly resemble the wooden presses in use at the present day. A new era has, however, now arrived, when the demands for prompt circulation of political intelligence require powers of printing newspapers beyond the reach of the most expeditious hand presswork.
For the first essential modification of the old press, the world is indebted to the late Earl Stanhope. His press is formed of iron, without any wood; the table upon which the form of types is laid, as well as the platen or surface which immediately gives the impression, is of cast iron, made perfectly level; the platen being large enough to print a whole sheet at one pull. The compression is applied by a beautiful combination of levers, which give motion to the screw, cause the platen to descend with progressively increasing force till it reaches the type, when the power approaches the maximum; upon the infinite lever principle, the power being applied to straighten an obtuse-angled jointed lever. This press, however, like all its flat-faced predecessors, does not act by a continuous, but a reciprocating motion, and can hardly be made automatic; nor does it much exceed the old presses in productiveness, since it can turn off only 250 impressions per hour.
The first person who publicly projected a self-acting printing-press, was Mr. William Nicholson, the able editor of the Philosophical Journal, who obtained a patent in 1790-1, for imposing types upon a cylindrical surface; this disposition of types, plates, and blocks, being a new invention (see fig. 913.); 2, for applying the ink upon the surface of the types, &c., by causing the surface of a cylinder smeared with the colouring-matter to roll over them; or else causing the types to apply themselves to the said cylinder. For the purpose of spreading the ink evenly over this cylinder, he proposed to apply three or more distributing rollers longitudinally against the inking cylinder, so that they might be turned by the motion of the latter. 3. “I perform,” he says, “all my impressions by the action of a cylinder, or cylindrical surface; that is, I cause the paper to pass between two cylinders, one of which has the form of types attached to it, and forming part of its surface; and the other is faced with cloth, and serves to press the paper so as to take off an impression of the colour previously applied; or otherwise I cause the form of types, previously coloured, to pass in close and successive contact with the paper wrapped round a cylinder with woollen.” (See figs. 913. and 914.)
In this description Mr. Nicholson indicates pretty plainly the principal parts of modern printing machines; and had he paid the same attention to any one part of his invention which he fruitlessly bestowed upon attempts to attach types to a cylinder, or had he bethought himself of curving stereotype plates, which were then beginning to be talked of, he would in all probability have realized a working apparatus, instead of scheming merely ideal plans.
The first operative printing machine was undoubtedly contrived by, and constructed under the direction of, M. König, a clockmaker from Saxony, who, so early as the year 1804, was occupied in improving printing-presses. Having failed to interest the continental printers in his views, he came to London soon after that period, and submitted his plans to Mr. T. Bensley, our celebrated printer, and to Mr. R. Taylor, now one of the editors of the Philosophical Magazine.
These gentlemen afforded Mr. König and his assistant Bauer, a German mechanic, liberal pecuniary support. In 1811, he obtained a patent for a method of working a common hand-press by power; but after much expense and labour he was glad to renounce the scheme. He then turned his mind to the use of a cylinder for communicating the pressure, instead of a flat plate; and he finally succeeded, sometime before the 28th November 1814, in completing his printing automaton; for on that day the editors of the Times informed their readers that they were perusing for the first time a newspaper printed by steam-impelled machinery; it is a day, therefore, which will be ever memorable in the annals of typography.
In that machine the form of type was made to traverse horizontally under the pressure cylinder, with which the sheet of paper was held in close embrace by means of a series of endless tapes. The ink was placed in a cylindrical box, from which it was extruded by means of a powerful screw, depressing a well-fitted piston; it then fell between two iron rollers, and was by their rotation transferred to several other subjacent rollers, which had not only a motion round their axes, but an alternating traverse motion (endwise). This system of equalizing rollers terminated in two which applied the ink to the types. (See fig. 915). This plan of inking evidently involved a rather complex mechanism, was hence difficult to manage, and sometimes required two hours to get into good working trim. It has been superseded by a happy invention of Mr. Cowper, to be presently described.
In order to obtain a great many impressions rapidly from the same form, a paper-conducting cylinder (one embraced by the paper) was mounted upon each side of the inking apparatus, the form being made to traverse under both of them. This double-action machine threw off 1100 impressions per hour when first finished; and by a subsequent improvement, no less than 1800.
Mr. König’s next feat was the construction of a machine for printing both sides of the newspaper at each complete traverse of the forms. This resembled two single machines, placed with their cylinders towards each other, at a distance of two or three feet; the sheet was conveyed from one paper cylinder to another, as before, by means of tapes; the track of the sheet exactly resembled the letter S laid horizontally, thus, ; and the sheet was turned over or reversed in the course of its passage. At the first paper cylinder it received the impression from the first form, and at the second it received it from the second form; whereby the machine could print 750 sheets of book letter-press on both sides in an hour. This new register apparatus was erected for Mr. T. Bensley, in the year 1815, being the only machine made by Mr. König for printing upon both sides. See fig. 916.
Messrs. Donkin and Bacon had for some years previous to this date been busily engaged with printing machines, and had indeed, in 1813, obtained a patent for an apparatus, in which the types were placed upon the sides of a revolving prism; the ink was applied by a roller, which rose and fell with the eccentricities of the prismatic surface, and the sheet was wrapped upon another prism fashioned so as to coincide with the eccentricities of the type prism. One such machine was erected for the University of Cambridge. (See fig. 917.) It was a beautiful specimen of ingenious contrivance and good workmanship. Though it was found to be too complicated for common operatives, and defective in the mechanism of the inking process; yet it exhibited for the first time the elastic inking rollers, composed of glue combined with treacle, which alone constitute one of the finest inventions of modern typography. In König’s machine the rollers were of metal covered with leather, and never answered their purpose very well.
Before proceeding further, I may state that the above elastic composition, which resembles caoutchouc not a little, but is not so firm, is made by dissolving with heat, in two pounds of ordinary treacle, one pound of good glue, previously soaked during a night in cold water.
In the year 1815, Mr. Cowper turned his scientific and inventive mind to the subject of printing machines, and has since, in co-operation with his partner, Mr. Applegath, carried them to an unlooked-for degree of perfection. In 1815 Mr. Cowper obtained a patent for curving stereotype plates, for the purpose of fixing them on a cylinder Several machines so mounted, capable of printing 1000 sheets per hour upon both sides, are at work at the present day; twelve machines on this principle having been made for the Directors of the Bank of England a short time previous to their re-issuing gold. See figs. 918. and 919.
It deserves to be remarked here, that the same object seems to have occupied the attention of Nicholson, Donkin, Bacon, and Cowper; viz., the revolution, of the form of types. Nicholson sought to effect this by giving to the shank of a type a shape like the stone of an arch; Donkin and Bacon by attaching types to the sides of a revolving prism; and Cowper, more successfully, by curving a stereotype plate. (See fig. 918.) In these machines Mr. Cowper places two paper cylinders side by side, and against each of them a cylinder for holding the plates; each of these four cylinders is about two feet in diameter. Upon the surface of the stereotype-plate cylinder, four or five inking rollers of about three inches in diameter are placed; they are kept in their position by a frame at each end of the said cylinder, and the axles of the rollers rest in vertical slots of the frame, whereby having perfect freedom of motion, they act by their gravity alone, and require no adjustment.
The frame which supports the inking rollers, called the waving-frame, is attached by hinges to the general framework of the machine; the edge of the stereotype-plate cylinder is indented, and rubs against the waving-frame, causing it to vibrate to and fro, and consequently to carry the inking rollers with it, so as to give them an unceasing traverse movement. These rollers distribute the ink over three-fourths of the surface of the cylinder, the other quarter being occupied by the curved stereotype plates. The ink is contained in a trough, which stands parallel to the said cylinder, and is formed by a metal roller revolving against the edge of a plate of iron; in its revolution it gets covered with a thin film of ink, which is conveyed to the plate-cylinder by a distributing roller vibrating between both. The ink is diffused upon the plate cylinder as before described; the plates in passing under the inking rollers become charged with the coloured varnish; and as the cylinder continues to revolve, the plates come into contact with a sheet of paper on the first paper cylinder, which is then carried by means of tapes to the second paper cylinder, where it receives an impression upon its opposite side from the plates upon the second cylinder.
Thus the printing of the sheet is completed. Though the above machine be applicable only to stereotype plates, it has been of general importance, because it formed the foundation of the future success of Messrs. Cowper and Applegath’s printing machinery, by showing them the best method of serving out, distributing, and applying the coloured varnish to the types.
In order to adapt this method of inking to a flat type-form machine, it was merely requisite to do the same thing upon an extended flat surface or table, which had been performed upon an extended cylindrical surface. Accordingly, Messrs. Cowper and Applegath constructed a machine for printing both sides of the sheet from type, including the inking apparatus, and the mode of conveying the sheet from the one paper cylinder to the other, by means of drums and tapes. It is highly creditable to the scientific judgment of these patentees, that in new modelling the printing machine, they dispensed with forty wheels, which existed in Mr. König’s apparatus, when Mr. Bensley requested them to apply their improvements to it.
The distinctive advantages of these machines, and which have not hitherto been equalled, are the uniform distribution of the ink, the equality as well as delicacy with which it is laid upon the types, the diminution in its expenditure, amounting to one half upon a given quantity of letter-press, and the facility with which the whole mechanism is managed. The band inking-roller, and distributing-table, now so common in every printing-office in Europe and America, is the invention of Mr. Cowper, and was specified in his patent. The vast superiority of the inking apparatus in his machines, over the balls used of old, induced him to apply it forthwith to the common press, and most successfully for the public; but with little or no profit to the inventor, as the plan was unceremoniously infringed throughout the kingdom, by such a multitude of printers, whether rich or poor, as to render all attempts at reclaiming his rights by prosecution hopeless. See fig. 920.
To construct a printing machine which shall throw off two sides at a time with exact register, that is, with the second side placed precisely upon the back of the first, is a very difficult problem, which was first practically solved by Messrs. Applegath and Cowper. It is comparatively easy to make a machine which shall print the one side of a sheet of paper first, and then the other side, by the removal of one form, and the introduction of another; and thus far did Mr. König advance. A correct register requires the sheet, after it has received its first impression from one cylinder, to travel round the peripheries of the cylinders and drums, at such a rate as to meet the types of the second side at the exact point which will ensure this side falling with geometrical nicety upon the back of the first. For this purpose, the cylinders and drums must revolve at the very same speed as the carriage underneath; hence the least incorrectness in the workmanship will produce such defective typography as will not be endured in book-printing at the present day, though it may be tolerated in newspapers. An equable distribution of the ink is of no less importance to beautiful letter-press. See figs. 921. 922.
The machines represented in figs. 923, , , are different forms of those which have been patented by Messrs. Applegath and Cowper. That shown in figs. 923. and 925. prints both sides of the sheet during its passage, and is capable of throwing off nearly 1000 finished sheets per hour. The moistened quires of blank paper being piled upon a table A, the boy, who stands on the adjoining platform, takes up one sheet after another, and lays them upon the feeder B, which has several linen girths passing across its surface, and round a pulley at each end of the feeder; so that whenever the pulleys begin to revolve, the motion of the girths carries forward the sheet, and delivers it over the entering roller E, where it is embraced between two series of endless tapes, that pass round a series of tension rollers. These tapes are so placed as to fall partly between, and partly exterior to, the pages of the printing; whereby they remain in close contact with the sheet of paper on both of its sides during its progress through the machine. The paper is thus conducted from the first printing cylinder F, to the second cylinder G, without having the truth of its register impaired, so that the coincidence of the two pages is perfect. These two great cylinders, or drums, are made of cast iron, turned perfectly true upon a self-acting lathe; they are clothed in these parts, corresponding to the typographic impression, with fine woollen cloth, called blankets by the pressmen, and revolve upon powerful shafts which rest in brass bearings of the strong framing of the machine. These bearings, or plummer blocks, are susceptible of any degree of adjustment, by set screws. The drums H and I are made of wood; they serve to conduct the sheet evenly from the one printing cylinder to the other.
One series of tapes commences at the upper part of the entering drum E, proceeds in contact with the right-hand side and under surface of the printing cylinder F, passes next over the carrier-drum H, and under the carrier-drum I; then encompassing the left-hand side and under portion of the printing drum G, it passes in contact with the small tension rollers a, b, c, d, fig. 925., and finally arrives at the roller E, which may be called the commencement of the one series of endless tapes. The other series may be supposed to commence at the roller h; it has an equal number of tapes, and corresponds with the former in being placed upon the cylinders so that the sheets of paper may be held securely between them. This second series descends from the roller h, fig. 925., to the entering drum E, where it meets and coincides with the first series in such a way that both sets of tapes proceed together under the printing cylinder F, over H, under I, and round G, until they arrive at the roller i, fig. 923., where they separate, after having continued in contact, except at the places where the sheets of paper are held between them. The tapes descend from the roller i, to a roller at k, and, after passing in contact with rollers at l, m, n, they finally arrive at the roller h, where they were supposed to commence. Hence two series of tapes act invariably in contact, without the least mutual interference, as may be seen by inspection of the figs. 923, , 925.
The various cylinders and drums revolve very truly by means of a system of toothed wheels and pinions mounted at their ends. Two horizontal forms of types are laid at a certain distance apart upon the long carriage M, adjoining to each of which there is a flat metallic plate, or inking table, in the same plane. The common carriage, bearing its two forms of type and two inking tables, is moved backwards and forwards, from one end of the printing machine to the other, upon rollers attached to the frame-work, and in its traverse brings the types into contact with the sheet of paper clasped by the tapes round the surfaces of the printing cylinders. This alternate movement of the carriage is produced by a pinion working alternately into the opposite sides of a rack under the table. The pinion is driven by the bevel wheels K.
The mechanism for supplying the ink, and distributing it over the forms, is one of the most ingenious and valuable inventions belonging to this incomparable machine, and is so nicely adjusted, that a single grain of the pigment may suffice for printing one side of a sheet. Two similar sets of inking apparatus are provided; one at each end of the machine, adapted to ink its own form of type. The metal roller L, called the ductor roller, as it draws out the supply of ink, has a slow rotatory motion communicated to it by a catgut cord, which passes round a small pulley upon the end of the shaft of the printing cylinder G. A horizontal plate of metal, with a straight-ground edge, is adjusted by set screws, so as to stand nearly in contact with the ductor roller. This plate has an upright ledge behind, converting it into a sort of trough or magazine, ready to impart a coating of ink to the roller, as it revolves over the table. Another roller, covered with elastic composition (see suprà), called the vibrating roller, is made to travel between the ductor roller and the inking table; the vibrating roller, as it rises, touches the ductor roller for an instant, abstracts a film of ink from it, and then descends to transfer it to the table. There are 3 or 4 small rollers of distribution, placed somewhat diagonally across the table at M, (inclined only 2 inches from a parallel to the end of the frame,) furnished with long slender axles, resting in vertical slots, whereby they are left at liberty to revolve and to traverse at the same time; by which compound movement they are enabled to efface all inequality in the surface of the varnish, or to effect a perfect distribution of the ink along the table. The table thus evenly smeared, being made to pass under the 3 or 4 proper inking rollers N, fig. 924., imparts to them an uniform film of ink, to be immediately transferred by them to the types. Hence each time that the forms make a complete traverse to and fro, which is requisite for the printing of every sheet, they are touched no less than eight times by the inking rollers. Both the distributing and inking rollers turn in slots, which permit them to rise and fall so as to bear with their whole weight upon the inking table and the form, whereby they never stand in need of any adjustment by screws, but are always ready for work when dropped into their respective places.
Motion is given to the whole system of apparatus by a strap from a steam engine going round a pulley placed at the end of the axle at the back of the frame; one steam-horse power being adequate to drive two double printing machines; while a single machine may be driven by the power of two men acting upon a fly-wheel. In Messrs. Clowes’ establishment, in Stamford-street, two five-horse engines actuate nineteen of the above described machines.
The operation of printing is performed as follows:—See fig. 926.
The sheets being carefully laid, one by one, upon the linen girths, at the feeder B, the rollers C and D are made to move, by means of a segment wheel, through a portion of a revolution. This movement carries on the sheet of paper sufficiently to introduce it between the two series of endless tapes at the point where they meet each other upon the entering drum E. As soon as the sheet is fairly embraced between the tapes, the rollers C and D are drawn back, by the operation of a weight, to their original position, so as to be ready to introduce another sheet into the machine. The sheet, advancing between the endless tapes, applies itself to the blanket upon the printing cylinder F, and as it revolves meets the first form of types, and receives their impression; after being thus printed on one side, it is carried, over H and under I, to the blanket upon the printing cylinder G, where it is placed in an inverted position; the printed side being now in contact with the blanket, and the white side being outwards, meets the second form of types at the proper instant, so as to receive the second impression, and get completely printed. The perfect sheet, on arriving at the point i, where the two series of tapes separate, is tossed out by centrifugal force into the hands of a boy.
The diagram, fig. 926. shows the arrangement of the tapes, agreeably to the preceding description; the feeder B, with the rollers C and D, is seen to have an independent endless girth.
The diagram, fig. 927. explains the structure of the great machine contrived by Messrs. Applegath and Cowper for printing the Times newspaper. Here there are four places to lay on the sheets, and four to take them off; consequently, the assistance of eight lads is required. P, P, P, P, are the four piles of paper; F, F, F, F, are the four feeding-boards; E, E, E, E, are the four entering drums, upon which the sheets are introduced between the tapes t, t, t, t, whence they are conducted to the four printing cylinders 1, 2, 3, 4; T is the form of type; I, I, are two inking tables, of which one is placed at each end of the form. The inking apparatus is similar to that above described, with the addition of two central inking rollers R, which likewise receive their ink from the inking tables. The printing cylinders 1, 2, 3, 4, are made to rise and fall about half an inch; the first and third simultaneously, as also the second and fourth. The form of type, in passing from A to B, prints sheets at 1 and 3; in returning from B to A, it prints sheets at 4 and 2; while the cylinder alternately falls to give the impression, and rises to permit the form to pass untouched.
Each of the lines marked t, consists of two endless tapes, which run in contact at the parts shown, but separate at the entering drums E, and at the taking off parts o, o, o, o. The return of the tapes to the entering drum is omitted in the diagram, to avoid confusion of the lines.